059
Second-order templation: Ordered deposition of supramolecular squares on a chloride-covered Cu(100) surface

C. Safarowsky, L. Merz, A. Rang, P. Broekmann, B. A. Hermann, C. A. Schalley – 2004

Beneath the surface lies the answer: Metallosupramolecular cations are deposited in an ordered manner on a copper surface, which had previously been covered with chloride ions. The anion layer acts as a second-order template, whose interactions with the cation determine the adsorption process.

Title
059
Second-order templation: Ordered deposition of supramolecular squares on a chloride-covered Cu(100) surface
Author
C. Safarowsky, L. Merz, A. Rang, P. Broekmann, B. A. Hermann, C. A. Schalley
Date
2004-02-27
Identifier
DOI 10.1002/anie.200352968; 10.1002/ange.200352968
Citation
Angew. Chem. Int. Ed. 2004, 43, 1291-1294; Angew. Chem. 2004, 116, 1311-1314
Type
Text