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153
A neutral Pt3 stack unsupported by any bridging ligand

L. Holland, W.-Z. Shen, P. von Grebe, D. Gupta, P. J. Sanz Miguel, Y. Huang, F. Pichierri, A. Springer, C. A. Schalley, B. Lippert – 2011

Pt...Pt...Pt interactions via their d8 orbitals, combined with π–π stacking of deprotonated, chelating 2-(3′-pyrazolyl)pyridine (pyzpy) ligands, are responsible for trans-Pt(pyzpy)2 (2) crystallization in a stack of three molecules unsupported by any bridging ligand.

Title
153
A neutral Pt3 stack unsupported by any bridging ligand
Author
L. Holland, W.-Z. Shen, P. von Grebe, D. Gupta, P. J. Sanz Miguel, Y. Huang, F. Pichierri, A. Springer, C. A. Schalley, B. Lippert
Date
2011-04-05
Identifier
DOI 10.1039/C0DT01408G
Citation
Dalton Trans. 2011, 40, 5159-5161