613. One-pot Covalent Functionalization of Two-Dimensional Black Phosphorus by Anionic Ring Opening Polymerization
O. Bawadkji, M. Cherri, A. Schäfer, S. Herziger, P. Nickl, K. Achazi, I. S. Donskyi, M. Adeli, R. Haag – 2022
In this work, a one-pot approach for the covalent functionalization of few-layer black phosphorus (BP) by anionic ring opening polymerization of glycidol to obtain multifunctional BP-polyglycerol (BP-PG) with high amphiphilicity for near-infrared-responsive drug delivery and biocompatibility is reported. Straightforward synthesis in combination with exceptional biological and physicochemical properties designates functionalized BP-PG as a promising candidate for a broad range of biomedical applications.