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11. New Developments in the Asymmetric Stetter Reaction

M. Christmann

Highly active carbene catalysts have revitalized the interest in the asymmetric Stetter reaction as a method for the construction of 1,4-dicarbonyl compounds. With the latest generation of a catalyst developed by Rovis and co-workers (1, for example), products with quaternary stereocenters such as 2 can be generated in 85 % yield and 99 % ee.

Title
11. New Developments in the Asymmetric Stetter Reaction
Author
M. Christmann
Identifier
DOI: 10.1002/anie.200500761
Source(s)
Citation
Angew. Chem. Int. Ed. 2005, 44, 2632–2634.