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Residues and Dissipation Kinetics of Two Imidacloprid Nanoformulations on Bean (Phaseolus vulgaris L.) under Field Conditions

N. Memarizadeh*, M. Ghadamyari, K. Talebi, E. Torabi, M. Adeli, R. Jalalipour – 2019

The current study investigates the dissipation kinetics of two imidacloprid (IMI) nanoformulations (entitled: Nano-IMI and Nano-IMI/TiO2) on common bean (Phaseolus vulgaris) seeds under field conditions and compares them with 35% Suspension Concentrate (SC) commercial formulation. To do so, it sprays P. vulgaris plants at 30 and 60 g/ha within green bean stage, sampling them during the 14-day period after the treatment. Following extraction and quantification of IMI residues, dissipation data have been fitted to simple-first order kinetic model (SFOK) and to first-order double-exponential decay (FODED) models, with 50% and 90% dissipation times (DT50 and DT90, respectively) assessed along the pre-harvest interval (PHI). With the exception of Nano-IMI at 60 g/ha, other decline curves are best fitted to the FODED model. In general, dissipation is faster for Nano-IMI (at 30 g/ha: DT50 = 1.09 days, DT90 = 4.30 days, PHI = 1.23 days; at 60 g/ha: DT50 = 1.29 days, DT90 = 4.29 days, PHI = 2.95 days) and Nano-IMI/TiO2 (at 30 g/ha: DT50 = 1.15 days, DT90 = 4.40 days, PHI = 1.08 days; at 60 g/ha: DT50 = 0.86 days, DT90 = 4.92 days, PHI = 3.02 days), compared to 35% SC (at 30 g/ha: DT50 = 1.58, DT90 = 6.45, PHI = 1.93; at 60 g/ha: DT50 = 1.58 days, DT90 = 14.50 days, PHI = 5.37 days). These results suggest the suitability of Nano-IMI and Nano-IMI/TiO2 application at both rates in terms of their residues on P. vulgaris seeds.

Title
Residues and Dissipation Kinetics of Two Imidacloprid Nanoformulations on Bean (Phaseolus vulgaris L.) under Field Conditions
Author
N. Memarizadeh*, M. Ghadamyari, K. Talebi, E. Torabi, M. Adeli, R. Jalalipour
Date
2019
Identifier
10.22059/POLL.2019.275929.582
Citation
Pollution, 2019, 5, 871-878
Type
Text