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Functionalization of fullerene at room temperature: toward new carbon vectors with improved physicochemical properties

Z. Beiranvand, A. Kakanejadifard, I. S. Donskyi, A. Faghani, Z. Tu, A. Lippitz,, P. Sasanpour, F. Maschietto, B. Paulus, W. E. S. Unger, R. Haag, M. Adeli – 2016

In this work, fullerene has been functionalized with cyanuric chloride at room temperature by a nitrene mediated [2 + 1] cycloaddition reaction. The adduct after functionalization is inherently in the form of azafulleroid and shows broad UV absorption in the wavelength range of 200–800 nm, as well as photothermal conversion and fluorescence with a high quantum yield.

Title
Functionalization of fullerene at room temperature: toward new carbon vectors with improved physicochemical properties
Author
Z. Beiranvand, A. Kakanejadifard, I. S. Donskyi, A. Faghani, Z. Tu, A. Lippitz,, P. Sasanpour, F. Maschietto, B. Paulus, W. E. S. Unger, R. Haag, M. Adeli
Date
2016
Identifier
10.1039/C6RA23419D
Citation
RSC Adv., 2016, 6, 112771-112775
Type
Text