Fluorine-Rich Fluorides: New Insights into the Chemistry of Polyfluoride Anions
059
Thomas Vent-Schmidt, Felix Brosi, Jens Metzger, Tobias Schlöder, Xuefeng Wang, Lester Andrews, Carsten Müller, Helmut Beckers, Sebastian Riedel – 2015
Polyfluoride anions have been investigated by matrix‐isolation spectroscopy and quantum‐chemical methods. For the first time the higher polyfluoride anion [F₅]⁻ has been observed under cryogenic conditions in neon matrices at 850 cm⁻¹. In addition, a new band for the Cs⁺[F₃]⁻ complex in neon is reported.
Title
Fluorine-Rich Fluorides: New Insights into the Chemistry of Polyfluoride Anions
Author
Thomas Vent-Schmidt, Felix Brosi, Jens Metzger, Tobias Schlöder, Xuefeng Wang, Lester Andrews, Carsten Müller, Helmut Beckers, Sebastian Riedel
Date
2015
Source(s)
Appeared in
Angew. Chem. Int. Ed. 2015, 54, 28, 8279–8283
Angew. Chem. 2015, 127, 28, 8397-8401 VIP Paper
Citation
DOI: 10.1002/anie.201502624
DOI: 10.1002/ange.201502624
Language
eng