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Spectroscopic Observation of a Group 12 Oxyfluoride: A Matrix-Isolation and Quantum-Chemical Investigation of Mercury Oxyfluorides

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Lester Andrews, Xuefeng Wang, Yu Gong, Tobias Schlöder, Sebastian Riedel, Marvin J. Franger – 2012

Experiments with amalgams as a source for laser‐ablated Hg atoms as reaction partners with OF₂ gave strong HgF₂ IR absorptions and new bands in the Hg-F stretching region for OHgF and FOHgF molecules trapped in solid neon and argon. Assignment of these new bands to the first oxyfluoride of mercury, OHgF, and to the FOHgF insertion product is supported by quantum‐chemical methods.

Title
Spectroscopic Observation of a Group 12 Oxyfluoride: A Matrix-Isolation and Quantum-Chemical Investigation of Mercury Oxyfluorides
Author
Lester Andrews, Xuefeng Wang, Yu Gong, Tobias Schlöder, Sebastian Riedel, Marvin J. Franger
Date
2012
Appeared in
Angew. Chem. Int. Ed. 2012, 51, 33, 8235–8238 Angew. Chem. 2012, 124, 33, 8359–8363
Citation
DOI: 10.1002/anie.201204331 DOI: 10.1002/ange.201204331
Language
eng