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Synthesis of the Smallest Axially Chiral Molecule by Asymmetric Carbon–Fluorine Bond Activation

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031

Moritz F. Kuehnel, Tobias Schlöder, Sebastian Riedel, Belén Nieto-Ortega, Francisco J. Ramírez, Juan T. López Navarrete, Juan Casado, Dieter Lentz – 2012

Enantioselect‐DeFluor: Carbon–fluorine bond cleavage by a chiral zirconium complex allows the synthesis of optically active 1,3‐difluoroallene for the first time. Its absolute configuration was established by gas‐phase vibrational circular dichroism spectroscopy.

Title
Synthesis of the Smallest Axially Chiral Molecule by Asymmetric Carbon–Fluorine Bond Activation
Author
Moritz F. Kuehnel, Tobias Schlöder, Sebastian Riedel, Belén Nieto-Ortega, Francisco J. Ramírez, Juan T. López Navarrete, Juan Casado, Dieter Lentz
Date
2012
Appeared in
Angew. Chem. Int. Ed. 2012, 51, 9, 2218–2220 Angew. Chem. 2012, 124, 9, 2261–2263
Citation
DOI: 10.1002/anie.201108105 DOI: 10.1002/ange.201108105
Language
eng