The Reaction of White Phosphorus with NO+/NO2+[Al(ORF)4]−: The [P4NO]+ Cluster Formed by an Unexpected Nitrosonium Insertion
023
Tobias Koechner, Sebastian Riedel, Anna J. Lehner, Harald Scherer, Ines Raabe, Tobias A. Engesser, Franziska W. Scholz, Urs Gellrich, Philipp Eiden, Roberto A. Paz Schmidt, Dietmar A. Plattner, Ingo Krossing – 2010
An appealing couple: The unprecedented insertion of the nitrosonium cation into a tetrahedral edge of white phosphorus forms the highly reactive [P₄NO]⁺ cation (see picture). The synthesis, characterization, and applications are discussed, and NO₂[Al(OC(CF₃)₃)₄] is presented as an easily synthesized oxidant.
Title
The Reaction of White Phosphorus with NO+/NO2+[Al(ORF)4]−: The [P4NO]+ Cluster Formed by an Unexpected Nitrosonium Insertion
Author
Tobias Koechner, Sebastian Riedel, Anna J. Lehner, Harald Scherer, Ines Raabe, Tobias A. Engesser, Franziska W. Scholz, Urs Gellrich, Philipp Eiden, Roberto A. Paz Schmidt, Dietmar A. Plattner, Ingo Krossing
Date
2010
Source(s)
Appeared in
Angew. Chem. Int. Ed. 2010, 49, 44, 8139-8143
Angew. Chem. 2010, 122, 44, 8316–8320
Citation
DOI: 10.1002/anie.201003031
DOI: 10.1002/ange.201003031
Language
eng