Springe direkt zu Inhalt

New publication in Chemical Communications

News from Oct 18, 2024

Moritz Ernst’s publication on “A Polychloride-enabled Synthesis of [NEt3Me][PCl6] Serving as a Potential PCl3-Storage and PCl5-Reagent” is now published in Chemical Communications. We show that the reaction of the ionic liquid [NEt3Me][Cl3] with white phosphorus (P4) gives quantitatively hexachlorophosphate [NEt3Me][PCl6]. This compound shows similar reactivity as PCl5, as confirmed for the reaction with phenol, carboxylic acids and ammonium chloride. At elevated temperature, [NEt3Me][PCl6] releases PCl3 and can therefore be used as a potential PCl3-storage material.

Congratulations!

DOI: 10.1039/D4CC04319G

2 / 34