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Archive of Paper Highlights

October 2022

GROMACS Stochastic Dynamics and BAOAB Are Equivalent Configurational Sampling Algorithms

St. Kieninger and B.G. Keller, JCTC 2022, nn, nn, 10.1021/acs.jctc.2c00585.

September 2022

Introducing the Perfluorinated Cp* Ligand into Coordination Chemistry

R. Sievers, M. Sellin, S.M. Rupf, J. Parche, M. Malischewski, Angew. Chem. Int. Ed. 2022,nn, nn, 10.1002/anie.202211147.

August 2022

  • A new access to diazaphospholes via cycloaddition–cycloreversion reactions on triazaphospholes

    L. Dettling, M. Papke, J.A.W. Sklorz, D. Buzsaki, Z. Kelemen, M. Weber, L. Nyulazi, C. Müller., Chem. Comm. 2022, 58, 7745-7748.

July 2022

  • Rational Design of Amphiphilic Fluorinated Peptides: Evaluation of Self-Assembly Properties and Hydrogel Formation

    S. Chowdhary, R.F. Schmidt, A.K. Sahoo, T. Dieck, T. Hohmann, B. Schade, K. Brademann-Jock, A.F. Thünemann, R.R. Netz, M. Gradzielski, B. Koksch., Nanoscale. 2022, 14, 10176-10189.

May 2022

  • Heterogeneity of oxygen reactivity: key for selectivity of partial methanol oxidation on gold surfaces

    Feldt, C. D.; Albrecht, P. A.; Eltayeb, S.; Riedel, W.; Risse, T., Chem. Comm. 2022, 58, 4336-4339.

March 2022

  • Sequence-sorted redox-switchable hetero[3]rotaxanes

    M. Gaedke, H. Hupatz, F. Witte, S. M. Rupf, C. Douglas, H. V. Schröder, L. Fischer, M. Malischewski, B. Paulus, C. A. Schalley, Org. Chem. Front. 2022, 9, 64-74.

January 2022

  • A light-fueled nanoratchet shifts a coupled chemical equilibrium

    M. Kathan, S. Crespi, N. O. Thiel, D. L. Stares, D. Morsa, J. de Boer, G. Pacella, T. van den Enk, P. Kobauri, G. Portale, C. A. Schalley, B. L. Feringa, Nat. Nanotechnol. 2021, 7, 1, 81-92.

December 2021

  • Photochemical C(sp)–C(sp2) Bond Activation in Phosphaalkynes: A New Route to Reactive Terminal Cyaphido Complexes LnM–C≡P

    Tim Görlich, Daniel S. Frost, Nico Boback, Nathan T. Coles, Birger Dittrich, Peter Müller, William D. Jones*, and Christian Müller*, J. Am. Chem. Soc. 2021, 143, 46, 19365 - 19373.

October 2021

  • Systematic Evaluation of Fluorination as Modification for Peptide-Based Fusion Inhibitors against HIV-1 Infection

    Susanne Huhmann, Elisabeth K. Nyakatura, Anette Rohrhofer, Johann Moschner, Barbara Schmidt, Jutta Eichler, Christian Roth, Beate Koksch, Chem Bio Chem 2021, 22, 1 - 10.

September 2021

  • Structural proof of a [C–F–C]+ fluoronium cation

    Kurt F. Hoffmann, Anja Wiesner, Carsten Müller, Simon Steinhauer, Helmut Beckers, Muhammad Kazim, Cody Ross Pitts, Thomas Lectka, Sebastian Riedel , Nat Commun 2021, 12, 5275.

July/August 2021

June 2021

April 2021

  • Electron Symmetry Breaking during Attosecond Charge Migration Induced by Laser Pulses: Point Group Analyses for Quantum Dynamics

    D.Haase, G.Hermann, J.Manz, V.Pohl, J.C.Tremblay, Symmetry 2021, 13, 205.

February 2021

  • Searching for Monomeric Nickel Tetrafluoride: Unravelling Infrared Matrix Isolation Spectra of Higher Nickel Fluorides

    Lin Li, Ahmed K. Sakr, Tobias Schlöder, Siri Klein, Helmut Beckers, Marios-Petros Kitsaras, Howard V. Snelling, Nigel A. Young, Dirk Andrae, Sebastian Riedel, Angew. Chem. 2020, Early View.

January 2021

  • Multiomics Analysis Provides Insight into the Laboratory Evolution of Escherichia coli toward the Metabolic Usage of Fluorinated Indoles

    F. Agostini, L. Sinn, D. Petras, V. Kubyshkin, A.A. Berger, C. J. Schipp, P.C. Dorrestein, J. Rappsilber, N. Budisa, B. Koksch, ACS Cent. Sci. 2020, 7, 1, 81-92.

December 2020

  • 2-(Dimethylamino)phosphinine: A Phosphorus Containing Aniline Derivative

    Steven Giese, Katrin Klimov, Antal Mikeházi, Zsolt Kelemen, Daniel Frost, Simon Steinhauer, Peter Müller, László Nyulászi, and Christian Müller, Angew. Chem. Int. Ed. 2020, accepted article

November 2020

  • Mucin-Inspired, High Molecular Weight Virus Binding Inhibitors Show Biphasic Binding Behavior to Influenza A Viruses

    Wallert, M.; Nie, C.; Anilkumar, P.; Abbina, S.; Bhatia, S.; Ludwig, K.; Kizhakkedathu, J.N.; Haag, R.; Block, S., Small 2020, 16(47), 2004635

September 2020

July/August 2020

June 2020

  • Adaptive flexible sialylated nanogels as highly potent influenza A virus inhibitors

    Sumati Bhatia, Malte Hilsch, Jose Luis Cuellar Camacho, Kai Ludwig, Chuanxiong Nie, Badri Parshad, Matthias Wallert, Stephan Block, Daniel Lauster, Christoph Böttcher, Andreas Herrmann, Rainer Haag, Angew. Chem. Int. Ed. 2020, accepted article

May 2020

  • Identification of Semiconductive Patches in Thermally Processed Monolayer Oxo-Functionalized Graphene

    Zhenping Wang, Qirong Yao, Cristof Neumann, Felix Börrnert, Julian Renner, Ute Kaiser, Andrey Turchanin, Harold J. W. Zandvliet, Siegfried Eigler, Angew. Chem. Int. Ed. 2020, accepted article

  • Modular detergents tailor the purification and structural analysis of membrane proteins including G-protein coupled receptors

    Leonhard H. Urner, Idlir Liko, Hsin-Yung Yen, Kin-Kuan Hoi, Jani Reddy Bolla, Joseph Gault, Fernando Gonçalves Almeida, Marc-Philip Schweder, Denis Shutin, Svenja Ehrmann, Rainer Haag, Carol V. Robinson and Kevin Pagel, Nat. Commun. 2020, 11, 564.

April 2020

  • Isolation and structural characterization of eight‐fold protonated octacyanometallates [M(CNH)8]4+ (M=MoIV,WIV) from Superacids

    Malte Sellin, Valérie Marvaud, Moritz Malischewski, Angew. Chem. Int. Ed. 2020, published online

March 2020

  • Semisynthesis of Plant-Derived Englerin A Enabled by Microbe Engineering of Guaia-6,10(14)-diene as Building Block

    Thomas Siemon, Zhangqian Wang, Guangkai Bian, Tobias Seitz, Ziling Ye, Yan Lu, Shu Cheng, Yunkun Ding, Yanglei Huang, Zixin Deng, Tiangang Liu and Mathias Christmann, J. Am. Chem. Soc. 2020, 142(6), 2760-2765

  • A Conserved Kinase-Based Body-Temperature Sensor Globally Controls Alternative Splicing and Gene Expression

    Tom Haltenhof, Ana Kotte, Francesca De Bortoli, Samira Schiefer, Stefan Meinke, Ann-Kathrin Emmerichs, Kristina Katrin Petermann, Bernd Timmermann, Petra Imhof, Andreas Franz, Bernhard Loll, Markus C. Wahl, Marco Preußner, Florian Heyd, Mol. Cell 2020, published online

February 2020

  • Synthesis of Swinhoeisterol A, Dankasterone A and B, and Periconiastone A by Radical Framework Reconstruction

    Fenja L. Duecker, Robert C. Heinze and Philipp Heretsch, J. Am. Chem. Soc. 2020, 142(1), 104-108

January 2020

December 2019

  • Ultrathin nanosheets of oxo-functionalized graphene inhibit the ion migration in perovskite solar cells

    M. Li, W.-W. Zuo, Q. Wang, K.-L. Wang, M.-P. Zhuo, H. Köbler, C. E. Halbig, S. Eigler, Y.-G. Yang, X.-Y. Gao, Z.-K. Wang, Y. Li, A. Abate, Advanced Energy Materials 2019, Accepted manuscript online

November 2019

  • Facile C=O Bond Splitting of Carbon Dioxide Induced by Metal–Ligand Cooperativity in a Phosphinine Iron(0) Complex

    Julia Leitl, Michael Marquardt, Peter Coburger, Daniel J. Scott, Verena Streitferdt, Ruth M. Gschwind, Christian Müller, Robert Wolf, Angew. Chem. Int. Ed. 2019, 58(43), 15407-15411

October 2019

  • Competition for Membrane Receptors: Norovirus Detachment via Lectin Attachment

    Nagma Parveen, Gustaf E. Rydell, Göran Larson, Vesa P. Hytönen, Vladimir P. Zhdanov, Fredrik Höök and Stephan Block, J. Am. Chem. Soc. 2019, published online

August/September 2019

  • Adsorption of Mono- and Divalent 4-(Dimethylamino)pyridines on Gold Surfaces: Studies by Surface-Enhanced Raman Scattering and Density Functional Theory

    Xin Gong, Maurice Taszarek, Luise Schefzig, Hans-Ulrich Reissig, Steffen Thierbach, Bernhard Wassermann, Christina Graf, Doreen Mollenhauer, Eckart Rühl, Langmuir 2019, 35(26), 8667-8680

  • Dendronized fluorosurfactant for highly stable water-in-fluorinated oil emulsions with minimal inter-droplet transfer of small molecules

    Mohammad Suman Chowdhury, Wenshan Zheng, Shalini Kumari, John Heyman, Xingcai Zhang, Pradip Dey, David Weitz, and Rainer Haag, Nature Communications 2019, 10, Article no. 4546

July 2019

  • Strong Exchange Couplings Drastically Slow Down Magnetization Relaxation in an Air-Stable Cobalt(II)-Radical Single-Molecule Magnet (SMM)

    Uta Albold, Heiko Bamberger, Philipp P. Hallmen, Joris van Slageren, and Biprajit Sarkar, Angew. Chem. Int. Ed. 2019, 58, Early View

June 2019

  • Phosphinine-Based Ligands in Gold-Catalyzed Reactions

    M. Rigo, E. R. M. Habraken, K. Bhattacharyya, M. Weber, A. W. Ehlers, N. Mézailles, J. C. Slootweg, and C. Müller, Chem. Eur. J. 2019, 28, Early View

May 2019

  • An Intrinsic Hydrophobicity Scale for Amino Acids and Its Application to Fluorinated Compounds

    Waldemar Hoffmann, Jennifer Langenhan, Susanne Huhmann, Johann Moschner, Rayoon Chang, Matteo Accorsi, Jongcheol Seo, Jörg Rademann, Gerard Meijer, Beate Koksch, Michael T. Bowers, Gert von Helden, and Kevin Pagel, Angew. Chem. Int. Ed. 2019, Accepted Article

  • Diaminodicyanoquinones: Fluorescent Dyes with High Dipole Moments and Electron‐Acceptor Properties

    Philipp Rietsch, Felix Witte, Sebastian Sobottka, Gregor Germer, Alexander Becker, Arne Güttler, Biprajit Sarkar, Beate Paulus, Ute Resch-Genger, and Siegfried Eigler, Angew. Chem. Int. Ed. 2019, Early View

April 2019

  • Theory of cyclic voltammetry in random arrays of cylindrical microelectrodes applied to carbon felt electrodes for vanadium redox flow batteries

    Tim Tichter, Dirk Andrae, Jacob Mayer, Jonathan Schneider, Marcus Gebhard and Christina Roth, Phys. Chem. Chem. Phys. 2019, Advance Article

March 2019

  • Mobility-Based Quantification of Multivalent Virus-Receptor Interactions: New Insights Into Influenza A Virus Binding Mode

    Müller, M., Lauster, D., Wildenauer, H. H., Herrmann, A., and Block, S., Nano Lett. 2019, Article ASAP

    This letter as Highlight in c&en (Chemical & Engineering News)

February 2019

January 2019

  • Exploring Rigid and Flexible Core Trivalent Sialosides for Influenza Virus Inhibition

    P. Kiran, S. Bhatia, D. Lauster, S. Aleksić, C. Fleck, N. Peric, W. Maison, S. Liese, B. G. Keller, A. Herrmann, and R. Haag, Chem. Eur. J. 2018, 24(72), 19373-19385

December 2018

November 2018

October 2018

  • [P4H]+[Al(OTeF5)4].: protonation of white phosphorus with the Brønsted superacid H[Al(OTeF5)4](solv)

    Anja Wiesner, Simon Steinhauer, Helmut Beckers, Christian Müller and Sebastian Riedel, Chem. Sci. 2018, 9(36), 7169-7173

September 2018

  • Synthesis of Enantioenriched Bromohydrins via Divergent Reactions of Racemic Intermediates from Anchimeric Oxygen Borrowing

    Y.-M. Cao, D. Lentz, M. Christmann, J. Am. Chem. Soc. 2018, 140(34), 10677-10681

  • γ-Iron Phase Stabilized at Room Temperature by Thermally Processed Graphene Oxide

    Artur Khannanov, Airat Kiiamov, Alina Valimukhametova, Dmitrii A. Tayurskii, Felix Börrnert, Ute Kaiser, Siegfried Eigler, Farit G. Vagizov and Ayrat M. Dimiev, J. Am. Chem. Soc. 2018, 140(29), 9051-9055

July/August 2018

  • Selective Synthesis of Perfluoroalkylated Corannulenes and Investigation of their Structural, Dynamic and Electrochemical Behavior

    Axel Haupt, Lisa.Marie Keller, Maximilian Kutter, Dieter Lentz, Chemistry 2018, Early View

  • Controlled self-assembly of stomatosomes by use of single-component fluorinated dendritic amphiphiles

    H. v. Berlepsch, B. N. S. Thota, M. Wyszogrodzka, S. de Carlo, R. Haag and C. Böttcher, Soft Matter 2018, 14, 5256-5269

June 2018

  • Stabilization of Lewis Acidic AuF3 as an N‐Heterocyclic Carbene Complex: Preparation and Characterization of [AuF3(SIMes)]

    Mathias A. Ellwanger, Simon Steinhauer, Paul Golz, Thomas Braun, Sebastian Riedel, Angew. Chem. Int. Ed. 2018, Early View

May 2018

  • Multiply Intercalator-Substituted Cu(II) Cyclen Complexes as DNA Condensers and DNA/RNA Synthesis Inhibitors

    Jan Hormann, Jaroslav Malina, Oliver Lemke, Max J. Hülsey, Stefanie Wedepohl, Jan Potthoff, Claudia Schmidt, Ingo Ott, Bettina G. Keller, Viktor Brabec, and Nora Kulak, Inorg. Chem. 2018, Article ASAP

March/April 2018

  • Oxygen Radical Character in Group 11 Oxygen Fluorides

    Lin Li, Tony Stüker, Stefanie Kieninger, Dirk Andrae, Tobias Schlöder, Yu Gong, Lester Andrews, Helmut Beckers, and Sebastian Riedel, Nat. Comm. 2018, article no. 1267

  • Effect of friction on oxidative graphite intercalation and high-quality graphene formation

    S. Seiler, C. E. Halbig, F. Grote, P. Rietsch, F. Börrnert, U. Kaiser, B. Meyer, S. Eigler, Nat. Comm. 2018, article no. 836

February 2018

January 2018

  • Salt-templated porous carbon-carbon composite electrodes for application in vanadium redox flow batteries

    M. Schnucklake, S. Kuecken, A. Fetyan, J. Schmidt, A. Thomas, C. Roth, J. Mater. Chem. A 2017, 5, 25193-25199

December 2017

  • Triazaphospholenium Tetrafluoroborate: The First Phosphorus Analog of a 1,2,3-Triazole-Derived Carbene

    Martin Papke, Lea Dettling, Julian A. W. Sklorz, Dénes Szieberth, László Nyulaszi, Christian Müller, Angew. Chem. Int. Ed. 2017, Early View Article

November 2017

  • Bioinspired synthesis of pentacyclic onocerane triterpenoids

    Florian Bartels, Young J. Hong, Daijiro Ueda, Manuela Weber, Tsutomu Sato, Dean J. Tantillo and Mathias Christmann, Chem. Sci. 2017, Advance Article

October 2017

  • Combination of Surface Charge and Size Controls the Cellular Uptake of Functionalized Graphene Sheets

    Zhaoxu Tu, Katharina Achazi, Andrea Schulz, Rolf Mülhaupt, Steffen Thierbach, Eckart Rühl, Mohsen Adeli, and Rainer Haag, Adv. Funct. Mater. 2017, 27, 1701837

September 2017

  • Unexpected Chiro-Thermoresponsive Behavior of Helical Poly(phenylacetylene)s Bearing Elastin-Based Side-Chains

    S. Arias, F. Freire, M. Calderón, J. Bergueiro, Angew. Chem. Int. Ed. 2017, online

July 2017

  • Broad substrate tolerance of tubulin tyrosine ligase enables one-step site-specific enzymatic protein labeling

    D. Schumacher, O. Lemke, J. Helma, L. Gerszonowicz, V. Waller, T. Stoschek, P. Durkin, N. Budisa, H. Leonhardt, B.G. Keller, C. Hackenberger, Chem. Sci. 2017, 8, 3471-3478 (DOI: 10.1039/C7SC00574A)

  • Thermal disproportionation of oxo-functionalized graphene

    Fabian Grote, Christoph Gruber, Felix Börrnert, Ute Kaiser, Siegfried Eigler, Angew. Chem. Int. Ed. 2017, Online Version

  • Illuminating Iron: Mesoionic Carbenes as Privileged Ligands in Photochemistry

    B. Sarkar, L. Suntrup, Angew. Chem. Int. Ed. 2017, Online Version

  • Tricyanomethane and Its Ketenimine Tautomer: Generation from Different Precursors and Analysis in Solution, Argon Matrix, and as a Single Crystal

    Klaus Banert, Madhu Chityala, Manfred Hagedorn, Helmut Beckers, Tony Stüker, Sebastian Riedel, Tobias Rüffer, and Heinrich Lang, Angew. Chem. Int. Ed. 2017, Online Version

June 2017

  • Palladium-Catalyzed Directed Halogenation of Bipyridine N-Oxides

    Sina P. Zucker, Friedrich Wossidlo, Manuela Weber, Dieter Lentz, and C. Christoph Tzschucke, J. Org. Chem. 2017, Article ASAP

  • Superacids Based on Pentafluoroorthotellurate Derivatives of Aluminum

    A. Wiesner, T. W. Gries, S. Steinhauer, H. Beckers, S. Riedel, Angew. Chem. Int. Ed. 2017, Online

May 2017

  • Data-based modeling of drug penetration relates human skin barrier function to the interplay of diffusivity and free-energy profiles

    Robert Schulz, Kenji Yamamoto, André Klossek, Roman Flesch, Stefan Hönzke, Fiorenza Rancan, Annika Vogt, Ulrike Blume-Peytavi, Sarah Hedtrich, Monika Schäfer-Korting, Eckart Rühl, and Roland R. Netz, Proc. Natl. Acad. Sci. USA 2017, 114(14), 3631-3636

April 2017

  • Internal Dynamics of the 3-Pyrroline-N-Oxide Ring in Spin-Labeled Proteins

    P. Consentius, B. Loll , U. Gohlke, C. Alings, C. Müller, R. Müller, C. Teutloff, U. Heinemann, M. Kaupp, M. C. Wahl, and T. Risse, J. Phys. Chem. Lett. 2017, 8(6), 1113-1117

March 2017

  • PolyWhips: Directional particle transport by gradient-directed growth and stiffening of supramolecular assemblies

    L. Cera, L. Chiappisi, C. Böttcher, A. Schulz, S. Schoder, M. Gradzielski, C.A. Schalley, Adv. Mater. 2017, 29(8), 1604430

February 2017

January 2017

  • Discovery and Investigation of Natural Editing Function against Artificial Amino Acids in Protein Translation

    J. Völler, M. Dulic, U. Gerling-Driessen, H. Biava, T. Baumann, N. Budisa, I. Gruic-Sovulj, B. Koksch, ACS Cent. Sci. 2016, advance publication on the web

December 2016

  • Core-multishell nanocarriers: Transport and release of dexamethasone probed by soft X-ray spectromicroscopy

    K. Yamamoto, A. Klossek, R. Flesch, T. Ohigashi, E. Fleige, F. Rancan, J. Frombach, A. Vogt, U. Blume-Peytavi, P. Schrade, S. Bachmann, R. Haag, S. Hedtrich, M. Schäfer-Korting, N. Kosugi, E. Rühl, J. Control. Release 2016, 242, 64-70

November 2016

  • Tracking Transient Conformational States of T4 Lysozyme at Room Temperature Combining X-ray Crystallography and Site-Directed Spin Labeling

    P. Consentius, U. Gohlke, B. Loll, C. Alings, R. Müller, U. Heinemann, M. Kaupp, M. Wahl, and T. Risse, J. Am. Chem. Soc. 2016, 138(39), 12868.12875

October 2016

  • Intradomain Allosteric Network Modulates Calcium Affinity of the C-Type Lectin Receptor Langerin

    Jonas Hanske, Stevan Aleksic, Martin Ballaschk, Marcel Jurk, Elena Shanina, Monika Beerbaum, Peter Schmieder, Bettina G. Keller, Christoph Rademacher, J. Am. Chem. Soc. 2016, 138(37), 12176-12186

August/September 2016

  • Structural Proof for the First Dianion of a Polychloride: Investigation of [Cl8]2−

    Robin Brückner, Patrick Pröhm, Anja Wiesner, Simon Steinhauer, Carsten Müller, Sebastian Riedel, Angew. Chem. Int. Ed. 2016, 55(36), 10904-10908

  • Clicking the Arsenic–Carbon Triple Bond: An Entry into a New Class of Arsenic Heterocycles

    Gregor Pfeifer, Martin Papke, Daniel Frost, Julian A. W. Sklorz, Marija Habicht, Christian Müller, Angew. Chem. Int. Ed. 2016, Early View

  • Retention of Native Protein Structures in the Absence of Solvent: A Coupled Ion Mobility and Spectroscopic Study

    J. Seo, J., W. Hoffmann, S. Warnke, M. T. Bowers, K. Pagel, G. von Helden, Angew. Chem. Int. Ed. 2016, Early View

  • Synthesis of Strophasterol A Guided by a Proposed Biosynthesis and Innate Reactivity

    R. C. Heinze, D. Lentz, P. Heretsch, Angew. Chem. Int. Ed. 2016, Early View

July 2016

  • Significantly enhanced proteolytic activity of cyclen complexes by monoalkylation

    Chrischani Perera-Bobusch, Jan Hormann, Christoph Weise, Stefanie Wedepohl, Jens Dernedde and Nora Kulak, Dalton Trans. 2016, 45, 10500-10504

June 2016

  • A combined in-situ XAS-DRIFTS study unraveling adsorbate induced changes on the Pt nanoparticle structure

    C. Brieger, J. Melke, N. van der Bosch, U. Reinholz, H. Riesemeier, A. Guilherme Buzanich, M. Krishna Kayarkatte, I. Derr, A. Schökel, C. Roth, J. Catal. 2016, 339, 57-67

May 2016

  • Introducing Chirality into Nonionic Dendritic Amphiphiles and Studying Their Supramolecular Assembly

    Sumit Kumar, Kai Ludwig, Boris Schade, Hans von Berlepsch, Ilona Papp, Rahul Tyagi, Monika Gulia, Rainer Haag, and Christoph Böttcher, Chem. Eur. J. 2016, 22(16), 5629-5636

  • Expanding the phosphorus–carbon analogy: formation of an unprecedented 5-phosphasemibullvalene derivative

    Massimo Rigo, Manuela Weber and Christian Müller, Chem. Comm. 2016, Advance Article

April 2016

  • Catalysis of “outer-phase” oxygen atom exchange reactions by encapsulated “inner-phase” water in {V15Sb6}-type polyoxovanadates

    M. Wendt, U. Warzok, C. Näther, J. van Leusen, P. Kögerler, C.A. Schalley, W. Bensch, Chem. Sci. 2016, 7, 2684-2694

  • Polymeric near-infrared absorbing dendritic nanogels for efficient in vivo photothermal cancer therapy

    Maria Molina, Stefanie Wedepohl and Marcelo Calderón, Nanoscale 2016, 8, 5852-5856

March 2016

  • A four-coordinate cobalt(II) single-ion magnet with coercivity and a very high energy barrier

    Y. Rechkemmer, F. D. Breitgoff, M. van der Meer, M. Atanasov, M. Hakl, M. Orlita, P. Neugebauer, F. Neese, B. Sarkar, J. van Slageren, Nature Commun. 2016, 7, #10467

  • Controlling the Interaction and Non-Close-Packed Arrangement of Nanoparticles on Large Areas

    Madlen Schmudde, Christian Grunewald, Christian Goroncy, Christelle N. Noufele, Benjamin Stein, Thomas Risse, and Christina Graf, ACS Nano 2016, Article ASAP

  • Charge-Induced Unzipping of Isolated Proteins to a Defined Secondary Structure

    A. I. González Flórez, E. Mucha, D.-S. Ahn, S. Gewinner, W. Schöllkopf, K. Pagel, G. von Helden, Angew. Chem. Int. Ed. 2016, 55(10), 3295-3299

February 2016

January 2016

  • Quantitative study of ruthenium cross-over in direct methanol fuel cells during early operation hours

    A. Schoekel, J. Melke, M. Bruns, K. Wippermann, F. Kuppler, C. Roth, J. Power Sources 2016, 301, 210-218

  • A 2D Polychloride Network Held Together by Halogen–Halogen Interactions

    Robin Brückner, Heike Haller, Simon Steinhauer, Carsten Müller und Sebastian Riedel, Angew. Chem. Int. Ed. 2015, 54(51), 15579-15583

December 2015

  • Quantum theory of concerted electronic and nuclear fluxes associated with adiabatic intramolecular processes

    Timm Bredtmann, Dennis J. Diestler, Si-Dian Li, Jörn Manz, Jhon Fredy Pérez-Torres, Wen-Juan Tian, Yan-Bo Wu, Yonggang Yang and Hua-Jin Zhai, Phys. Chem. Chem. Phys. 2015 17(44), 29421-29464

November 2015

  • Structural Insights into the Incorporation of the Mo Cofactor into Sulfite Oxidase from Site-Directed Spin Labeling

    Aaron Hahn, Christopher Engelhard, Stefan Reschke, Christian Teutloff, Robert Bittl, Silke Leimkühler, Thomas Risse, Angew. Chem. Int. Ed. 2015 54(40), 11865-11869

  • Experimental and Theoretical Investigations of the Existence of CuII, CuIII, and CuIV in Copper Corrolato Complexes

    Woormileela Sinha, Michael G. Sommer, Naina Deibel, Fabian Ehret, Matthias Bauer, Biprajit Sarkar, Sanjib Kar, Angew. Chem. Int. Ed. 2015 54(46), 13769-13774

October 2015

September 2015

  • Field propagation-induced directionality of carrier-envelope phase-controlled photoemission from nanospheres

    F. Süßmann, L. Seiffert, S. Zherebtsov, V. Mondes, J. Stierle, M. Arbeiter, J. Plenge, P. Rupp, C. Peltz, A. Kessel, S.A. Trushin, B. Ahn, D. Kim, C. Graf, E. Rühl, M. F. Kling, T. Fennel, Nature Communications 2015, 6, article no. 7944

  • [Fe19] "Super-Lindqvist" Aggregate and Large 3D Interpenetrating  Coordination Polymer from Solvothermal Reactions of [Fe2(OtBu)6] with Ethanol

    Olaf Nachtigall, Matthias Kusserow, Rodolphe Clérac, Wolfgang Wernsdorfer, Michael Menzel, Franz Renz, Jerzy Mrozinski and Johann Spandl, Angew. Chem. Int. Ed. 2015, 54(35), 10361-10364

  • Fluorine teams up with water to restore inhibitor activity to mutant BPTI

    S. Ye, B. Loll, A.A. Berger, U. Mülow, C. Alings, M. Wahl, B. Koksch, Chem. Sci. 2015, 6(X), 5246-5254

August 2015

  • Fluorine-Rich Fluorides: New Insights into the Chemistry of Polyfluoride Anions

    Thomas Vent-Schmidt, Felix Brosi, Jens Metzger, Tobias Schlöder, Xuefeng Wang, Lester Andrews, Carsten Müller, Helmut Beckers and Sebastian Riedel, Angew. Chem. Int. Ed. 2015, 54(28), 8279-8283

July 2015

  • Selective Probing of the Penetration of Dexamethasone into Human Skin by Soft X-ray Spectromicroscopy

    K. Yamamoto, R. Flesch, T. Ohigashi, S. Hedtrich, A. Klossek, P. Patoka, G. Ulrich, S. Ahlberg, F. Rancan, A. Vogt, U. Blume-Peytavi, P. Schrade, S. Bachmann, M. Schäfer-Korting, N. Kosugi, and E. Rühl, Anal. Chem. 2015, 87(12), 6173-6179

June 2015

May 2015

April 2015

  • (-)-Englerin A is a Potent and Selective Activator of TRPC4 and TRPC5 Calcium Channels

    Y. Akbulut, H. J. Gaunt, K. Muraki, M. J. Ludlow, M. S. Amer, A. Bruns, N. S. Vasudev, L. Radtke, M. Willot, S. Hahn, T. Seitz, S. Ziegler, M. Christmann, D. J. Beech, H. Waldmann, Angew. Chem. Int. Ed. 2015, 54(12), 3787-3791

  • Dendritic polymer imaging systems for the evaluation of conjugate uptake and cleavage

    H. R. Krüger, G. Nagel, S. Wedepohl, M. Calderón, Nanoscale 2015, 7(9), 3838-3844

  • The Ligand Field of the Azido Ligand: Insights into Bonding Parameters and Magnetic Anisotropy in a Co(II)-Azido Complex

    D. Schweinfurth, M. G. Sommer, M. Atanasov, S. Demeshko, S. Hohloch, F. Meyer, F. Neese, B. Sarkar, J. Am. Chem. Soc. 2015, 137(5), 1993-2005

  • Amphiphilic Perylene–Calix[4]arene Hybrids: Synthesis and Tunable Self-Assembly

    Fabian Rodler, Boris Schade, Christof M. Jäger, Susanne Backes, Frank Hampel, Christoph Böttcher, Timothy Clark, and Andreas Hirsch, J. Am. Chem. Soc. 2015, 137(9), 3308-3317

March 2015

  • Synthesis of Polycyclic Tertiary Carbinamines by Samarium Diiodide Mediated Cyclizations of Indolyl Sulfinyl Imines

    Chintada Nageswara Rao, Dieter Lentz, Hans-Ulrich Reissig, Angew. Chem. Int. Ed. 2015, 54(9), 2750-2753

  • Chemical Assembly Systems: Layered Control for Divergent, Continuous, Multistep Syntheses of Active Pharmaceutical Ingredients

    Diego Ghislieri, Kerry Gilmore, Peter H. Seeberger, Angew. Chem. Int. Ed. 2015, 54(2), 678-682

February 2015

  • Photoionization of the 3s2 3p4 3P and the 3s2 3p4 1D, 1S states of sulfur: Experiment and theory

    Mathias Barthel, Roman Flesch, Eckart Rühl, and Brendan M. McLaughlin, Phys. Rev. A 2015, 91, 013406

January 2015

December 2014

  • Supramolecular Polymers as Surface Coatings: Rapid Fabrication of Healable Superhydrophobic and Slippery Surfaces

    Qiang Wei, Christoph Schlaich, Sylvain Prévost, Andrea Schulz, Christoph Böttcher, Michael Gradzielski, Zhenhui Qi, Rainer Haag and Christoph A. Schalley, Adv. Mater. 2014, 26(43), 7358-7364

November 2014 - Month of Publications

  • Sebastian Riedel in Nature:

    Identification of an iridium-containing compound with a formal oxidation state of IX

    G. Wang, M. Zhou, J.T. Goettel, J. Schrobilgen, J. Su, J. Li, T. Schlöder, S. Riedel, Nature 2014, 514(7523), 475-477

  • Rainer Haag in Angewandte Chemie:

    Mussel-Inspired Dendritic Polymers as Universal Multifunctional Coatings

    Q. Wei, K. Achazi, H. Liebe, A. Schulz, P.-L.M. Noeske, I. Grunwald, R. Haag, Angew. Chem. Int. Ed. 2014, 53(43), 11650–11655

  • again Rainer Haag in Angewandte Chemie:

    Photoresponsive Switches at Surfaces Based on Supramolecular Functionalization with Azobenzene–Oligoglycerol Conjugates

    O. Nachtigall, C. Kördel, L.H. Urner, R. Haag, Angew. Chem. Int. Ed. 2014, 53(36), 9669–9673

  • Eugen Illenberger in Angewandte Chemie:

    Reactions in Nitroimidazole Triggered by Low-Energy (0–2 eV) Electrons: Methylation at N1-H Completely Blocks Reactivity

    K. Tanzer, L. Feketeova, B. Puschnigg, P. Scheier, E. Illenberger, S. Denifl, Angew. Chem. Int. Ed. 2014, 53(45), 12240–12243

October 2014

September 2014

  • Oxygen Transfer from an Intramolecularly Coordinated Diaryltellurium Oxide to Acetonitrile. Formation and Combined AIM and ELI-D Analysis of a Novel Diaryltellurium Acetimidate

    Ole Mallow, Jens Bolsinger, Pamela Finke, Malte Hesse, Yu-Sheng Chen, Andrew Duthie, Simon Grabowsky, Peter Luger, Stefan Mebs, and Jens Beckmann, J. Am. Chem. Soc. 2014, 136(31), 10870-10873

  • Tuning the electronic effects of aromatic phosphorus heterocycles: an unprecedented phosphinine with significant P(π)-donor properties

    Antonia Loibl, Iris de Krom, Evgeny A. Pidko, Manuela Weber, Jelena Wiecko and Christian Müller, Chem. Commun. 2014, 50, 8842-8844

  • Cyclometalated Mono- and Dinuclear IrIII Complexes with “Click”-Derived Triazoles and Mesoionic Carbenes

    Ramananda Maity, Stephan Hohloch, Cheng-Yong Su, Margarethe van der Meer and Biprajit Sarkar, Chem. Eur. J. 2014, 20(32), 9952-9961

August 2014

  • Unprecedented Strong Lewis Bases - Synthesis and Methyl Cation Affinities of Dimethylamino-Substituted Terpyridines

    Paul Hommes, Christina Fischer, Christoph Lindner, Hendrik Zipse and Hans-Ulrich Reissig, Angew. Chem. 2014, 53(29), 7647-7651

  • Iron oxide nanoparticles stabilized with dendritic polyglycerols as selective MRI contrast agents

    Daniel Nordmeyer, Patrick Stumpf, Dominic Gröger, Andreas Hofmann, Sven Enders, Sebastian B. Riese, Jens Dernedde, Matthias Taupitz, Ursula Rauch, Rainer Haag, Eckart Rühl and Christina Graf, Nanoscale 2014, 6, 9646-9654

July 2014

  • Hierarchically Ordered Self-Assembly of Amphiphilic Bifullerenes

    L. Wasserthal, B. Schade, K. Ludwig, C. Böttcher, A. Hirsch, Chem. Eur. J. 2014, 20(20), 5961-5966

  • Following ORR intermediates adsorbed on a Pt cathode catalyst during break-in of a PEM fuel cell by in operando X-ray absorption spectroscopy

    D. E. Ramaker, A. Korovina, V. Croze, J. Melke, C. Roth, Phys. Chem. Chem. Phys. 2014, 16, 13645-13653

June 2014

  • A Universal Approach to Crosslinked Hierarchical Polymer Multilayers as Stable and Highly Effective Antifouling Coatings

    Q. Wei, T. Becherer, P.-L. M. Noeske, I. Grunwald, R. Haag, Adv. Mater. 2014, 26(17), 2688-2693

  • Stimuli-induced folding cascade of a linear oligomeric guest chain programmed through cucurbit[n]uril self-sorting (n = 6, 7, 8)

    L. Cera, C.A. Schalley, Chem. Sci. 2014, 5(6), 2560-2567

May 2014

April 2014

  • Redox-Induced Spin-State Switching and Mixed Valency in Quinonoid-Bridged Dicobalt Complexes

    David Schweinfurth, Yvonne Rechkemmer, Stephan Hohloch, Naina Deibel, Irina Peremykin, Jan Fiedler, Raphael Marx, Petr Neugebauer, Joris van Slageren, and Biprajit Sarkar, Chem. Eur. J. 2014, 20(12), 3475-3486

March 2014

  • Carbohydrate-Lectin Recognition of Sequence-Defined Heteromultivalent Glycooligomers

    D. Ponader, P. Maffre, J. Aretz, D. Pussak, N. M. Ninnemann, S. Schmidt, P. H.
    Seeberger, C. Rademacher, G. U. Nienhaus, L. Hartmann, J. Am. Chem. Soc. 2014, 136(5), 2008-2016

  • Ruthenium Complexes of Tripodal Ligands with Pyridine and Triazole Arms: Subtle Tuning of Thermal, Electrochemical, and Photochemical Reactivity

    F. Weisser, S. Hohloch, S. Plebst, D. Schweinfurth, B. Sarkar, Chem. Eur. J. 2014, 20(3), 781-793

February 2014

  • Porphyrin Assemblies and Their Scaffolds

    J.-H. Fuhrhop, Langmuir 2014, 30(1), 1-12

  • Partial side chain fluorination influencing amyloid formation: a symphony of size, hydrophobicity, and alpha-helix propensity

    U.I.M. Gerling, M. Salwiczek, C.D. Cadicamo, H. Erdbrink, S. Grage, P. Wadhwani, A. Ulrich, M. Behrens, G. Haufe, C. Czekelius, B. Koksch, Chem. Sci. 2014, 5(2), 819-830

January 2014

  • A Microgel Construction Kit for Bioorthogonal Encapsulation and pH-Controlled Release of Living Cells

    D. Steinhilber, T. Rossow, S. Wedepohl, F. Paulus, S. Seiffert, R. Haag, Angew. Chem. Int. Ed. 2013, 52(51), 13538-13543

  • NMR Studies of Protonation and Hydrogen Bond States of Internal Aldimines of Pyridoxal 5'-Phosphate Acid-Base in Alanine Racemase, Aspartate Aminotransferase and Poly-L-lysine

    Monique Chan-Huot, Alexandra Dos, Reinhard Zander, Shasad Sharif, Peter M. Tolstoy, Shara Compton, Emily Fogle, Michael D. Toney, Ilya Shenderovich, Gleb S. Denisov, and Hans-Heinrich Limbach, J. Am. Chem. Soc. 2013, 135(48), 18160-18175

December 2013

November 2013

  • The role of statistics and microenvironment for the photoresponse in multi-switch architectures: The case of photo switchable oligoazobenzene foldamers

    Z. Yu, S. Weidner, T. Risse, S. Hecht, Chemical Science 2013, 4(11), 4156-4167

  • Nuclear Fluxes in Diatomic Molecules Deduced from Pump-Probe Spectra with Spatiotemporal Resolutions down to 5 pm and 200 asec

    J. Manz, J.F. Perez-Torres, Y. Yang, Phys. Rev. Lett. 2013, 111, 153004

  • Cyclometalation of Aryl-Substituted Phosphinines through C-H-Bond Activation: A Mechanistic Investigation

    L. E. E. Broeckx, S. Güven, F. J. L. Heutz, M. Lutz, D. Vogt, C. Müller, Chem. Eur. J. 2013, 19(39), 13087-13098

October 2013

  • Synthesis and Biological Evaluation of Radio and Dye Labeled Amino Functionalized Dendritic Polyglycerol Sulfates as Multivalent Anti-Inflammatory Compounds

    D. Gröger, F. Paulus, K. Licha, P. Welker, M. Weinhart, C. Holzhausen, L. Mundhenk, U. Abram, A. D. Gruber, and R. Haag, Bioconjugate Chemistry 2013, 24, 1507-1514

  • Structural motifs of pre-nucleation clusters

    Y. Zhang, I. R. Türkmen, B. Wassermann, A. Erko, and E. Rühl, J. Chem. Phys. 2013, 139, 134506

September 2013

August 2013 and Archive of Paper Highlights