Paper Highlights of 2017

December 2017

Triazaphospholenium Tetrafluoroborate: The First Phosphorus Analog of a 1,2,3-Triazole-Derived Carbene

Martin Papke, Lea Dettling, Julian A. W. Sklorz, Dénes Szieberth, László Nyulaszi, Christian Müller, Angew. Chem. Int. Ed. 2017, Early View Article

Bioinspired synthesis of pentacyclic onocerane triterpenoids

Florian Bartels, Young J. Hong, Daijiro Ueda, Manuela Weber, Tsutomu Sato, Dean J. Tantillo and Mathias Christmann, Chem. Sci. 2017, Advance Article

Combination of Surface Charge and Size Controls the Cellular Uptake of Functionalized Graphene Sheets

Zhaoxu Tu, Katharina Achazi, Andrea Schulz, Rolf Mülhaupt, Steffen Thierbach, Eckart Rühl, Mohsen Adeli, and Rainer Haag, Adv. Funct. Mater. 2017, 27, 1701837

Unexpected Chiro-Thermoresponsive Behavior of Helical Poly(phenylacetylene)s Bearing Elastin-Based Side-Chains

S. Arias, F. Freire, M. Calderón, J. Bergueiro, Angew. Chem. Int. Ed. 2017, online

Broad substrate tolerance of tubulin tyrosine ligase enables one-step site-specific enzymatic protein labeling

D. Schumacher, O. Lemke, J. Helma, L. Gerszonowicz, V. Waller, T. Stoschek, P. Durkin, N. Budisa, H. Leonhardt, B.G. Keller, C. Hackenberger, Chem. Sci. 2017, 8, 3471-3478 (DOI: 10.1039/C7SC00574A)
Thermal disproportionation of oxo-functionalized graphene

Fabian Grote, Christoph Gruber, Felix Börrnert, Ute Kaiser, Siegfried Eigler, Angew. Chem. Int. Ed. 2017, Online Version
Illuminating Iron: Mesoionic Carbenes as Privileged Ligands in Photochemistry

B. Sarkar, L. Suntrup, Angew. Chem. Int. Ed. 2017, Online Version
Tricyanomethane and Its Ketenimine Tautomer: Generation from Different Precursors and Analysis in Solution, Argon Matrix, and as a Single Crystal

Klaus Banert, Madhu Chityala, Manfred Hagedorn, Helmut Beckers, Tony Stüker, Sebastian Riedel, Tobias Rüffer, and Heinrich Lang, Angew. Chem. Int. Ed. 2017, Online Version

Palladium-Catalyzed Directed Halogenation of Bipyridine N-Oxides

Sina P. Zucker, Friedrich Wossidlo, Manuela Weber, Dieter Lentz, and C. Christoph Tzschucke, J. Org. Chem. 2017, Article ASAP
Superacids Based on Pentafluoroorthotellurate Derivatives of Aluminum

A. Wiesner, T. W. Gries, S. Steinhauer, H. Beckers, S. Riedel, Angew. Chem. Int. Ed. 2017, Online

Data-based modeling of drug penetration relates human skin barrier function to the interplay of diffusivity and free-energy profiles

Robert Schulz, Kenji Yamamoto, André Klossek, Roman Flesch, Stefan Hönzke, Fiorenza Rancan, Annika Vogt, Ulrike Blume-Peytavi, Sarah Hedtrich, Monika Schäfer-Korting, Eckart Rühl, and Roland R. Netz, Proc. Natl. Acad. Sci. USA 2017, 114(14), 3631-3636

Internal Dynamics of the 3-Pyrroline-N-Oxide Ring in Spin-Labeled Proteins

P. Consentius, B. Loll , U. Gohlke, C. Alings, C. Müller, R. Müller, C. Teutloff, U. Heinemann, M. Kaupp, M. C. Wahl, and T. Risse, J. Phys. Chem. Lett. 2017, 8(6), 1113-1117

PolyWhips: Directional particle transport by gradient-directed growth and stiffening of supramolecular assemblies

L. Cera, L. Chiappisi, C. Böttcher, A. Schulz, S. Schoder, M. Gradzielski, C.A. Schalley, Adv. Mater. 2017, 29(8), 1604430

Crystal Structure Determination of the Pentagonal-Pyramidal Hexamethylbenzene Dication C₆(CH₃)₆²⁺

M. Malischewski, K. Seppelt, Angew. Chem. Int. Ed. 2017, 56(1), 368-370

Discovery and Investigation of Natural Editing Function against Artificial Amino Acids in Protein Translation

J. Völler, M. Dulic, U. Gerling-Driessen, H. Biava, T. Baumann, N. Budisa, I. Gruic-Sovulj, B. Koksch, ACS Cent. Sci. 2016, advance publication on the web