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Bismuth⋅⋅⋅π arene interaction in [Bi{OC6H4(CH2C6H5)-2}3]2

mgmc19

mgmc19

F. Roschke, G. Thiele, S. Dehnen, M. Mehring – 2019

We report on the synthesis of a new bismuth aryloxide molecule Bi[OC6H4(CH2C6H5)-2]3 (1), which was characterized by NMR and IR spectroscopy as well as single-crystal X-ray diffraction analysis. A characteristic structural feature is the dimeric unit with a central Bi2O2 core resulting from μ-binding phenolates. In addition, both bismuth atoms show a Bi⋅⋅⋅π arene interaction with a quite short Bi⋅⋅⋅πcentroid distance of 3.11 Å in the solid state.

Titel
Bismuth⋅⋅⋅π arene interaction in [Bi{OC6H4(CH2C6H5)-2}3]2
Verfasser
F. Roschke, G. Thiele, S. Dehnen, M. Mehring
Datum
2019
Zitierweise
Main Group Met. Chem. 2019, 42, 46.
Art
Text