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Nitrile functionalized organogermane chalcogenide clusters with hetero-(nor-)adamantane cores

JOMC16

S. Heimann, G. Thiele, S. Dehnen – 2016

By the synthesis of Cl3Ge(CH2)2CN (1) and subsequent reaction with sodium monochalcogenides, adamantane-type [(NC(CH2)2Ge)4Ch6] (Ch = S (2), Se) and noradamantane-type [(NC(CH2)2Ge)4Te5] (3) were obtained. The compounds represent the first nitrile-functionalized tetrel chalcogenide clusters and the first nitrile-functionalized clusters of the named architectures, and are thus potential precursor for novel reaction pathways to multifunctional core-shell compounds.

Titel
Nitrile functionalized organogermane chalcogenide clusters with hetero-(nor-)adamantane cores
Verfasser
S. Heimann, G. Thiele, S. Dehnen
Datum
2016
Zitierweise
J. Organomet. Chem. 2016, 813, 36-40.
Art
Text