Hot Article in Chemical Communications
News vom 26.07.2023
Lea Dettling’s publication on “Phosphorus Derivatives of Mesoionic Carbenes: Synthesis and Characterization of Triazaphosphole-5-ylidene→BF3 Adducts” is now published in Chemical Communications as part of the themed collection: Chemical Communications HOT Articles 2023. We show that BF4− -salts of Si(CH3)3- substituted triazaphospholenium cations undergo elimination of FSi(CH3)3 to form selectively BF3 adducts of unprecedented triazaphosphol-5-ylidenes. These heterocycles are the phosphorus congeners of tetrazol-5-ylidene carbenes.
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