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Stable Alkali-Metal Complexes of Hybrid Disila-Crown Ethers

IC16_2

K. Reuter, M. R. Buchner, G. Thiele, C. v. Hänisch – 2016

Contrary to cyclosiloxanes, the herein presented disilane groups bearing crown ethers act as excellent ligands for alkali-metal ions. Via proton NMR spectroscopy and quantum chemical methods, the binding affinity of these hybrid ligands was determined to be in the range of their organic analogues.

Title
Stable Alkali-Metal Complexes of Hybrid Disila-Crown Ethers
Author
K. Reuter, M. R. Buchner, G. Thiele, C. v. Hänisch
Date
2016
Citation
Inorg. Chem. 2016, 55, 4441.
Type
Text