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Heterobimetallic Chalcogenidometallate Strands: Synthesis, Structure, Magnetism, and Conductivity

IC12

G. Thiele, S. Peter, M. Schwarzer, E. Ruzin, R. Clérac, H. Staesche, C. Rößler, B. Roling, S. Dehnen – 2012

The reactions of [SnTe]4− anions with Hg2+ or Mn2+ ions in protic solution yielded two solvent-free salts with one-dimensional, SiS2-type telluridostannate chain anions {[MSnTe4]2−}n: Rb2[HgSnTe4] (2) and (NMe4)2[MnSnTe4] (3). Besides their crystal structures, we present the physical properties of the previously reported Cs+ analogue Cs2[MnSnTe4] (1), indicating antiferromagnetic coupling of the Mn ions and charge transport due to polaron hopping.

Title
Heterobimetallic Chalcogenidometallate Strands: Synthesis, Structure, Magnetism, and Conductivity
Author
G. Thiele, S. Peter, M. Schwarzer, E. Ruzin, R. Clérac, H. Staesche, C. Rößler, B. Roling, S. Dehnen
Date
2012
Citation
Inorg. Chem. 2012, 51, 3349.
Type
Text