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Smallest molecular chalcogenidometalate anions of the heaviest metals: syntheses, structures, and their interconversion

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DT16

G. Thiele, C. Donsbach, R. Riedel, M. Marsch, K. Harms, S. Dehnen – 2016

The syntheses of the first molecular meta-selenidomercurate(II), ortho-telluridothallate(III) and a hydrate of an ortho-selenidoplubate(IV) are presented alongside an improved and facile synthesis of the selenidobismuthate(III) with almost quantitative yields. By means of quantum chemical calculations, the energetics of the interconversions of small metalate anions is discussed and the existence of the heaviest homologues of [NO2]−, [NO3]−, [PO4]2− and [CO3]2− are predicted.

Title
Smallest molecular chalcogenidometalate anions of the heaviest metals: syntheses, structures, and their interconversion
Author
G. Thiele, C. Donsbach, R. Riedel, M. Marsch, K. Harms, S. Dehnen
Date
2016
Citation
Dalton Trans. 2016, 45, 5958.
Type
Text