Optical and Electrical Properties of A3[VS4] (A = Na, K) Synthesized via a Straightforward and Scalable Solid-State Method
M. J. Ernst, M. Kleoff, P. Voßnacker, G. Thiele, C. Müller, S. Riedel – 2024
Reaction of the ionic liquid [NEt3 Me][Cl3] with white phosphorus (P4 ) gives, quantitatively, hexachlorophosphate [NEt3Me][PCl6 ]. This compound shows similar reactivity as PCl 5, as confirmed for the reaction with phenol, carboxylic acids and ammonium chloride. At elevated temperature, [NEt3 Me][PCl 6] releases PCl 3 and can therefore be used as a potential PCl3-storage material.
Title
Optical and Electrical Properties of A3[VS4] (A = Na, K) Synthesized via a Straightforward and Scalable Solid-State Method
Author
M. J. Ernst, M. Kleoff, P. Voßnacker, G. Thiele, C. Müller, S. Riedel
Date
2024
Source(s)
Citation
Chem. Commun. 2024<\b>, Advance Article