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K4[PbSe4]⋅en⋅NH3: A Non‐Oxide, Non‐Halide Inorganic Lead(IV) Compound

AC14

G. Thiele, T. Krüger, S. Dehnen – 2014

The first inorganic lead(IV) compound without oxygen, nitrogen or halogen ligands attached to the lead atom was obtained as the potassium salt of the tetraselenidoplumbate(IV) anion [PbIVSe4]4−. It is stable under inert conditions which may enable the transfer of the chemistry of chalcogenidogermanate(IV) or chalcogenidostannate(IV) materials, to the lead homologues.

Title
K4[PbSe4]⋅en⋅NH3: A Non‐Oxide, Non‐Halide Inorganic Lead(IV) Compound
Author
G. Thiele, T. Krüger, S. Dehnen
Date
2014
Citation
Angew. Chem. 2014, 53, 4699; Angew. Chem. Int. Ed. 2014, 126, 4787.
Type
Text