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M. Sc. Samantha Frank


PhD Candidate

Phosphinine based Lewis pairs

Freie Universität Berlin
Institut für Chemie und Biochemie
Anorganische Chemie
Fabeckstraße 34/36
Room F208
14195 Berlin
samantha.frank (at) fu-berlin.de

Synthesis of trimethylsilyl-substituted phosphinines and their application as Lewis bases in classical or frustrated Lewis pairs for activation of small molecules such as terminal dienophiles, CO2 or H2. Photochemical di-π-methane rearrangement of phosphabarrelenes to phosphasemibullvalenes.