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Investigation of Alkali Metal Polyfluorides by Matrix-Isolation Spectroscopy

Frenio A. Redeker, Helmut Beckers, Sebastian Riedel – 2015

IR laser ablation was used for the systematic matrix-isolation investigation of reaction products of alkali metal fluorides and fluorine. New insights about periodic trends in the reaction behaviour of alkali metals and the formation as well as the photochemistry of alkali metal trifluorides are presented. New bands were found for the antisymmetric stretches of CsF₃ and [F₃]⁻ in solid krypton and nitrogen, and for the combination bands (νₐₛ + νₛ) of CsF₃ and [F₃]⁻ in solid krypton and argon.

Titel
Investigation of Alkali Metal Polyfluorides by Matrix-Isolation Spectroscopy
Verfasser
Frenio A. Redeker, Helmut Beckers, Sebastian Riedel
Schlagwörter
Polyfluorides, Alkalimetals, Matrix-Isolation Spectroscopy, Fluorine
Datum
2015
Quelle/n
Erschienen in
RSC Adv. 2015,5, 106568-106573.
Zitierweise
DOI 10.1039/c5ra24227d
Sprache
eng