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Fluorine Rich Fluorides – New insights into the chemistry of polyfluoride anions

Thomas Vent-Schmidt, Felix Brosi, Jens Metzger, Tobias Schlöder, Xuefeng Wang, Lester Andrews, Carsten Müller, Helmut Beckers, Sebastian Riedel – 2015

Polyfluoride anions have been investigated by matrix‐isolation spectroscopy and quantum‐chemical methods. For the first time the higher polyfluoride anion [F₅]⁻ has been observed under cryogenic conditions in neon matrices at 850 cm⁻¹. In addition, a new band for the Cs⁺[F₃]⁻ complex in neon is reported.

Titel
Fluorine Rich Fluorides – New insights into the chemistry of polyfluoride anions
Verfasser
Thomas Vent-Schmidt, Felix Brosi, Jens Metzger, Tobias Schlöder, Xuefeng Wang, Lester Andrews, Carsten Müller, Helmut Beckers, Sebastian Riedel
Schlagwörter
Fluorine, Polyfluorides, Matrix-Isolation Spectroscopy, Coupled-Cluster Calculations
Datum
2015
Erschienen in
Angew. Chem. Int. Ed. 2015, 54, 8279–8283 (Angew. Chem. 2015, 127, 8397 – 8401. VIP Paper
Zitierweise
DOI: 10.1002/anie.201502624 (Int. Ed.); 10.1002/ange.201502624
Sprache
eng