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Structural Proof of Undecabromide [Br₁₁]⁻

Heike Haller, Jan Schröder, Sebastian Riedel – 2013

Besides iodine, few of the polyhalogen anions have been structurally characterized. Remarkably, the highest known ratio of elements‐to‐charge has now been found in the undecabromide [Br₁₁]⁻. This new polybromide monoanion has been prepared in pure halogen and was structurally characterized by single‐crystal X‐ray diffraction, Raman spectroscopy, and quantum‐chemical methods.

Titel
Structural Proof of Undecabromide [Br₁₁]⁻
Verfasser
Heike Haller, Jan Schröder, Sebastian Riedel
Datum
2013
Erschienen in
Angew. Chem. Int. Ed. 2013, 52, 4937–4940 (Angew. Chem. 2013, 125, 5037–5040)
Zitierweise
DOI: 10.1002/ange.201209928; 10.1002/anie.201209928 (Int. Ed.)
Sprache
eng
Art
Text