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Structural Evidence for Undecabromide [Br11]−

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Heike Haller, Jan Schröder, Sebastian Riedel – 2013

Besides iodine, few of the polyhalogen anions have been structurally characterized. Remarkably, the highest known ratio of elements‐to‐charge has now been found in the undecabromide [Br₁₁]⁻. This new polybromide monoanion has been prepared in pure halogen and was structurally characterized by single‐crystal X‐ray diffraction, Raman spectroscopy, and quantum‐chemical methods.

Titel
Structural Evidence for Undecabromide [Br11]−
Verfasser
Heike Haller, Jan Schröder, Sebastian Riedel
Datum
2013
Erschienen in
Angew. Chem. Int. Ed. 2013, 52, 18, 4937–4940 Angew. Chem. 2013, 125, 18, 5037–5040
Zitierweise
DOI: 10.1002/anie.201209928 DOI: 10.1002/ange.201209928
Sprache
eng