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Investigation of Gold Fluorides and Noble Gas Complexes by Matrix-Isolation Spectroscopy and Quantum-Chemical Calculations

Xuefeng Wang, Lester Andrews, Knut Willmann, Felix Brosi, Sebastian Riedel – 2012

Noble with a difference: Matrix-isolation experiments and quantum-chemical calculations have led to the characterization of two new compounds, namely first open-shell binary gold fluoride, AuF₂, and a NeAuF complex. Moreover, ArAuF, AuF₃, Au₂F₆, and monomeric AuF₅ have been produced and identified under cryogenic conditions in neon and argon matrices.

Titel
Investigation of Gold Fluorides and Noble Gas Complexes by Matrix-Isolation Spectroscopy and Quantum-Chemical Calculations
Verfasser
Xuefeng Wang, Lester Andrews, Knut Willmann, Felix Brosi, Sebastian Riedel
Datum
2012
Erschienen in
Angew. Chem. Int. Ed. 2012, 51, 10628–10632 (Angew. Chem. 2012, 124, 10780–10784)
Zitierweise
DOI: 10.1002/ange.201205072; 10.1002/anie.201205072 (Int. Ed.)
Sprache
eng
Art
Text