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Spectroscopic Observation of a Group 12 Oxyfluoride: A Matrix-Isolation and Quantum-Chemical Investigation of Mercury Oxyfluorides

Lester Andrews, Xuefeng Wang, Yu Gong, Tobias Schlöder, Sebastian Riedel, Marvin J. Franger – 2012

Experiments with amalgams as a source for laser‐ablated Hg atoms as reaction partners with OF₂ gave strong HgF₂ IR absorptions and new bands in the Hg-F stretching region for OHgF and FOHgF molecules trapped in solid neon and argon. Assignment of these new bands to the first oxyfluoride of mercury, OHgF, and to the FOHgF insertion product is supported by quantum‐chemical methods.

Titel
Spectroscopic Observation of a Group 12 Oxyfluoride: A Matrix-Isolation and Quantum-Chemical Investigation of Mercury Oxyfluorides
Verfasser
Lester Andrews, Xuefeng Wang, Yu Gong, Tobias Schlöder, Sebastian Riedel, Marvin J. Franger
Datum
2012
Erschienen in
Angew. Chem. Int. Ed. 2012, 51, 8235–8238 (Angew. Chem. 2012, 124, 8359–8363)
Zitierweise
DOI: 10.1002/ange.201204331; 10.1002/anie.201204331 (Int. Ed.)
Sprache
eng
Art
Text