Synthesis of the Smallest Axially Chiral Molecule by Asymmetric Carbon–Fluorine Bond Activation
031
Moritz F. Kuehnel, Tobias Schlöder, Sebastian Riedel, Belén Nieto-Ortega, Francisco J. Ramírez, Juan T. López Navarrete, Juan Casado, Dieter Lentz – 2012
Enantioselect‐DeFluor: Carbon–fluorine bond cleavage by a chiral zirconium complex allows the synthesis of optically active 1,3‐difluoroallene for the first time. Its absolute configuration was established by gas‐phase vibrational circular dichroism spectroscopy.
Titel
Synthesis of the Smallest Axially Chiral Molecule by Asymmetric Carbon–Fluorine Bond Activation
Verfasser
Moritz F. Kuehnel, Tobias Schlöder, Sebastian Riedel, Belén Nieto-Ortega, Francisco J. Ramírez, Juan T. López Navarrete, Juan Casado, Dieter Lentz
Datum
2012
Erschienen in
Angew. Chem. Int. Ed. 2012, 51, 9, 2218–2220
Angew. Chem. 2012, 124, 9, 2261–2263
Zitierweise
DOI: 10.1002/anie.201108105
DOI: 10.1002/ange.201108105
Sprache
eng