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Synthesis of the Smallest Axially Chiral Molecule by Asymmetric Carbon-Fluorine Bond Activation

Moritz F. Kuehnel, Tobias Schlöder, Sebastian Riedel, Belén Nieto-Ortega, Francisco J. Ramírez, Juan T. López Navarrete, Juan Casado, Dieter Lentz – 2012

Enantioselect‐DeFluor: Carbon–fluorine bond cleavage by a chiral zirconium complex allows the synthesis of optically active 1,3‐difluoroallene for the first time. Its absolute configuration was established by gas‐phase vibrational circular dichroism spectroscopy.

Titel
Synthesis of the Smallest Axially Chiral Molecule by Asymmetric Carbon-Fluorine Bond Activation
Verfasser
Moritz F. Kuehnel, Tobias Schlöder, Sebastian Riedel, Belén Nieto-Ortega, Francisco J. Ramírez, Juan T. López Navarrete, Juan Casado, Dieter Lentz
Datum
2012
Erschienen in
Angew. Chem. Int. Ed. 2012, 51, 2218–2220 (Angew. Chem. 2012, 124, 2261–2263)
Zitierweise
DOI: 10.1002/ange.201108105; 10.1002/anie.201108105 (Int. Ed.)
Sprache
eng
Art
Text