Structural proof for a higher polybromide monoanion. Investigation of [N(C₃H₇)₄][Br₉]

Heike Haller, Mathias Ellwanger, Alexander Higelin, Sebastian Riedel – 2011

Bromine's nine: The first crystal structure of a higher polybromide monoanion, [N(C₃H₇)₄][Br₉] is reported along with its IR and Raman spectra. Owing to its low melting point and vapor pressure, this substance can be classified as an ionic liquid. It shows surprisingly high conductivity which may enable its applications as electrolyte in batteries.

Titel
Structural proof for a higher polybromide monoanion. Investigation of [N(C₃H₇)₄][Br₉]
Verfasser
Heike Haller, Mathias Ellwanger, Alexander Higelin, Sebastian Riedel
Datum
2011
Erschienen in
Angew. Chem. Int. Ed. 2011, 50, 11528 (Angew. Chem. 2011, 123, 11732)
Zitierweise
DOI: 10.1002/ange.201105237; 10.1002/anie.201105237 (Int. Ed.)
Sprache
eng
Art
Text