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Oxidation of closo-[B₁₂Cl₁₂]²⁻ to the radical anion [B₁₂Cl₁₂]•⁻ and to neutral B₁₂Cl₁₂

René T. Boeré, Sylwia Kacprzak, Mathias Keßler, Carsten Knapp, Rainer Riebau, Sebastian Riedel, Tracey L. Roemmele, Monika Rühle, Harald Scherer, Stefan Weber – 2011

Strong as an ox: Oxidation of the perchlorinated dodecaborate [B₁₂Cl₁₂]²⁻ by AsF5 in liquid sulfur dioxide leads to the Jahn–Teller‐distorted radical anion [B₁₂Cl₁₂]‧⁻ and to neutral B₁₂Cl₁₂. The formation of both compounds has been verified by a combination of several theoretical and experimental methods (pictured: cyclic voltammogram of [B₁₂Cl₁₂]²⁻ in liquid SO₂).

Titel
Oxidation of closo-[B₁₂Cl₁₂]²⁻ to the radical anion [B₁₂Cl₁₂]•⁻ and to neutral B₁₂Cl₁₂
Verfasser
René T. Boeré, Sylwia Kacprzak, Mathias Keßler, Carsten Knapp, Rainer Riebau, Sebastian Riedel, Tracey L. Roemmele, Monika Rühle, Harald Scherer, Stefan Weber
Datum
2011
Erschienen in
Angew. Chem. Int. Ed. 2011, 50, 549–552 (Angew. Chem. 2011, 123, 572–575)
Zitierweise
DOI: 10.1002/ange.201004755; 10.1002/anie.201004755 (Int. Ed.)
Sprache
eng
Art
Text