Oxidation of closo-[B₁₂Cl₁₂]²⁻ to the radical anion [B₁₂Cl₁₂]•⁻ and to neutral B₁₂Cl₁₂
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René T. Boeré, Sylwia Kacprzak, Mathias Keßler, Carsten Knapp, Rainer Riebau, Sebastian Riedel, Tracey L. Roemmele, Monika Rühle, Harald Scherer, Stefan Weber – 2011
Strong as an ox: Oxidation of the perchlorinated dodecaborate [B₁₂Cl₁₂]²⁻ by AsF5 in liquid sulfur dioxide leads to the Jahn–Teller‐distorted radical anion [B₁₂Cl₁₂]‧⁻ and to neutral B₁₂Cl₁₂. The formation of both compounds has been verified by a combination of several theoretical and experimental methods (pictured: cyclic voltammogram of [B₁₂Cl₁₂]²⁻ in liquid SO₂).
Titel
Oxidation of closo-[B₁₂Cl₁₂]²⁻ to the radical anion [B₁₂Cl₁₂]•⁻ and to neutral B₁₂Cl₁₂
Verfasser
René T. Boeré, Sylwia Kacprzak, Mathias Keßler, Carsten Knapp, Rainer Riebau, Sebastian Riedel, Tracey L. Roemmele, Monika Rühle, Harald Scherer, Stefan Weber
Datum
2011
Quelle/n
Erschienen in
Angew. Chem. Int. Ed. 2011, 50, 549–552 (Angew. Chem. 2011, 123, 572–575)
Zitierweise
DOI: 10.1002/ange.201004755; 10.1002/anie.201004755 (Int. Ed.)
Sprache
eng
Art
Text