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The Reaction of White Phosphorus with NO⁺/NO₂⁺[Al(ORF)₄]⁻: The [P₄NO]⁺ Cluster Formed by an Unexpected Nitrosonium Insertion

Tobias Koechner, Sebastian Riedel, Anna J. Lehner, Harald Scherer, Ines Raabe, Tobias A. Engesser, Franziska W. Scholz, Urs Gellrich, Philipp Eiden, Roberto A. Paz Schmidt, Dietmar A. Plattner, Ingo Krossing – 2010

An appealing couple: The unprecedented insertion of the nitrosonium cation into a tetrahedral edge of white phosphorus forms the highly reactive [P₄NO]⁺ cation (see picture). The synthesis, characterization, and applications are discussed, and NO₂[Al(OC(CF₃)₃)₄] is presented as an easily synthesized oxidant.

Titel
The Reaction of White Phosphorus with NO⁺/NO₂⁺[Al(ORF)₄]⁻: The [P₄NO]⁺ Cluster Formed by an Unexpected Nitrosonium Insertion
Verfasser
Tobias Koechner, Sebastian Riedel, Anna J. Lehner, Harald Scherer, Ines Raabe, Tobias A. Engesser, Franziska W. Scholz, Urs Gellrich, Philipp Eiden, Roberto A. Paz Schmidt, Dietmar A. Plattner, Ingo Krossing
Datum
2010
Erschienen in
Angew. Chem. 2010, 44, 8316–8320 (Angew. Chem. Int. Ed. 2010, 49, 8139-8143)
Zitierweise
DOI: 10.1002/ange.201003031; 10.1002/anie.201003031 (Int. Ed.)
Sprache
eng
Art
Text