Springe direkt zu Inhalt

Revising the highest oxidation states of the 5d elements: The case of iridium(+VII)

Sebastian Riedel, Martin Kaupp – 2006

Our computational study suggests thus that the highest iridium oxidation state that has a realistic chance of experimental observation is Ir⁺ⱽᴵᴵ. The experimentally known highest 5d oxidation states for groups 9, 10, and 11 are Os⁺ⱽᴵᴵᴵ, Pt⁺ⱽᴵ, and Au⁺ⱽ, respectively. Adding the computational predicted Hg⁺ᴵⱽ and Ir⁺ⱽᴵᴵ states suggests that the trend for the later 5d metals should become a linear decrease. All in all there is a linear increase up to Os and after Os there is a linear decrease down to Hg. This trend is a new observation for the 5d transition metals.

Titel
Revising the highest oxidation states of the 5d elements: The case of iridium(+VII)
Verfasser
Sebastian Riedel, Martin Kaupp
Datum
2006
Erschienen in
Angew. Chem. 2006, 118, 3791-3794; Angew. Chem. Int. Ed. 2006, 45, 3708 - 3711
Zitierweise
DOI: 10.1002/ange.200600274; 10.1002/anie.200600274 (Int. Ed.)
Sprache
eng
Art
Text