[Pb₅{Mo(CO)₃}₂]⁴⁻: The first Complex Containing a Planar Pb₅ Unit

Li Yong, Stephan D. Hoffmann, Thomas F. Fässler, Sebastian Riedel, Martin Kaupp – 2005

Lead around: The cyclic [Pb₅]⁴⁻ ion can be stabilized as an organometallic complex with the {Mo(CO)₃} fragment. This complex is formed by the reaction of [Pb₉]⁴⁻ with [MesMo(CO)₃] (Mes=1,3,5‐trimethylbenzene). In the solid state this highly charged anion forms a linear chain with strong interactions between the potassium cations and the carbonyl oxygen.

Titel
[Pb₅{Mo(CO)₃}₂]⁴⁻: The first Complex Containing a Planar Pb₅ Unit
Verfasser
Li Yong, Stephan D. Hoffmann, Thomas F. Fässler, Sebastian Riedel, Martin Kaupp
Datum
2005
Erschienen in
Angew. Chem. 2005, 117, 2129 - 2133; Angew. Chem. Int. Ed. 2005, 44, 2092 - 2096
Zitierweise
DOI: 10.1002/ange.200462342; 10.1002/anie.200462342 (Int. Ed.)
Sprache
eng
Art
Text