Chemistry of the Elements Technetium and Rhenium
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The coordination chemistry and organometallic chemistry of technetium and rhenium was in the focus of our research for many years. This involved studies with the long-lived isotope 99Tc as well as with the short-lived nuclear isomer 99mTc.Many of our recent studies, particularly those with bulky terphenylisocyanides, were done in close collaboration with the group of Prof. Joshua Figueroa, University of California San Diego. |
Technetiumchemie
Moritz Johannes Ernst, Abdullah Abdulkader, Adelheid Hagenbach, Guilhem Claude, Maximilian Roca Jungfer and Ulrich Abram
"[Tc(NO)(Cp)(PPh3)Cl] and [Tc(NO)(Cp)(PPh3)(NCCH3)](PF6), and Their Reactions with Pyridine and Chalcogen Donors"
Technetium Chemistry
Guilhem Claude, Denis Puccio, Maximilian Roca Jungfer, Adelheid Hagenbach, Sarah Spreckelmeyer, Ulrich Abram
"Technetium complexes with an isocyano-alkyne ligand and its reaction products"
Rhenium Chemistry
Felipe Dornelles da Silva, Maximilian Roca Jungfer, Adelheid Hagenbach, Ernesto Schulz Lang and Ulrich Abram
" Stabilization of 2-pyridyltellurium(II) derivatives by oxidorhenium(V) complexes"
Rhenium Chemistry
Guilhem Claude, Erika Kulitzki, Adelheid Hagenbach, Joshua S. Figueroa, and Ulrich Abram
" Phenylimido Complexes of Rhenium: Fluorine Substituents Provide Protection, Reactivity and Solubility"
Technetium Chemistry
Federico Salsi, Adelheid Hagenbach, Joshua S. Figueroa and Ulrich Abram
" Na[Tc(CO)(CNp-F-ArDArF2)4]: an isocyanide analogue of the elusive Na[Tc(CO)5] "
Technetium and Rhenium Chemistry
Federico Salsi,Shuai Wang, Christian Teutloff, Marvin Busse, Michael Neville, Adelheid Hagenbach, Robert Bittl, Joshua S. Figueroa and Ulrich Abram
"A Complete Triad of Zero-Valent 17-Electron Monoradicals of Group 7 Elements Stabilized by m-Terphenyl Isocyanides"
Rhenium Chemistry
Bruno Noschang Cabral, Jessica Rodrigues Fonseca, Maximilian Roca Jungfer, Anke Krebs, Adelheid Hagenbach, Ernesto Schulz Lang and Ulrich Abram
"Oxidorhenium(V) and Rhenium(III) Complexes with Arylselenolato and -tellurolato Ligands"
Rhenium Chemistry
Maximilian Roca Jungfer, Ulrich Abram
"[ReH3(PPh3)4] - A Key Compound in the Rhenium Hydride Chemistry"
Rhenium Chemistry
Guilhem Claude, Dominik Weh, Adelheid Hagenbach, Joshua S. Figueroa, and Ulrich Abram
"Rhenium Complexes with p-Fluorophenylisocyanide"
Technetium Chemistry
Guilhem Claude, Laura Zeh, Maximilian Roca Jungfer, Adelheid Hagenbach, Joshua S. Figueroa, and Ulrich Abram
"The Chemistry of Phenylimidotechnetium(V) Complexes: Steric and Electronic Factors"
Technetium Chemistry
Augusto F. Oliveira, Agnieszka Kuc, Thomas Heine, Ulrich Abram, Andreas C. Scheinost
"Shedding Light on the Enigmatic TcO2·xH2O Structure with Density Functional Theory and EXAFS Spectroscopy"
Technetium Chemistry
Moritz Johannes Ernst, Maximilian Roca Jungfer, Ulrich Abram
Reactions of TcI(NO) and TcVN Complexes with Alkynes and Alkynides
Technetium Chemistry
Moritz Johannes Ernst, Maximilian Roca Jungfer, Adelheid Hagenbach, Ulrich Abram
Triaryltechnetium(III) and Related Complexes
Technetium Chemistry
Maximilian Roca Jungfer, Ulrich Abram
Unlocking air- and water-stable technetium acetylides and other organometallic complexes
Technetium Chemistry
Mamina Bhol, Guilhem Claude, Maximilian Roca Jungfer, Ulrich Abram, Malaichamy Sathiyendiran
Calix[4]arene-Analogous Technetium Supramolecules
Technetium Chemistry
Maximilian Roca Jungfer, Laura Elsholz, Ulrich Abram
Technetium(I) Carbonyl Chemistry with Small Inorganic Ligands
Technetium Chemistry
Maximilian Roca Jungfer, Moritz Johannes Ernst, Ulrich Abram
[{TcI(NO)(LOMe)(PPh3)Cl}Ag](PF6) and [TcII(NO)(LOMe)(PPh3)Cl](PF6): Two Unusual Technetium Complexes with the ‘Kläui Ligand’
Z. Anorg. Allg. Chem. 2022, 648, e202100316.
DOI: 10.1002/zaac.202100316
Technetium Chemistry
Markus Zegke, Dennis Grödler, Maximilian Roca Jungfer,Alexander Haseloer,Meike Kreuter, Jörg M. Neudörfl, Thomas Sittel, Christopher M. James, Jörg Rothe, Marcus Altmaier, Axel Klein,Martin Breugst, Ulrich Abram,Erik Strub, Mathias S. Wickleder
"Ammonium Pertechnetate in Mixtures of Trifluoromethane sulfonic Acid and Trifluoromethanesulfonic Anhydride"
Angew. Chem. Int. Ed. Engl. 2022, 61, e202113777.
DOI: 10.1002/anie.202113777
Technetium Chemistry
Maximilian Roca Jungfer, Ulrich Abram
[Tc(OH2)(CO)3(PPh3)2]+: A Synthon for Tc(I) Complexes and its Reactions with Neutral Ligands.
Technetium Chemistry
Abdullah Abdulkader, Adelheid Hagenbach, Ulrich Abram
[Tc(NO)Cl(Cp)(PPh3)] – A Technetium(I) Compound with an Unexpected Synthetic Potential
Selenium Ligands
Rodrigo Cervo, Thaísa R. R. Lopes, Adriana R. de Vasconcelos, Juliana F. Cargnelutti, Ricardo F. Schumacher, Bárbara Tirloni, Sailer S. dos Santos, Ulrich Abram, Ernesto S. Lang and Roberta Cargnelutti
Coordination compounds containing 2-pyridylselenium ligands: synthesis, structural characterization, and antibacterial evaluation
Technetium Chemistry
Maximilian Roca Jungfer, Laura Elsholz, Ulrich Abram
Technetium Hydrides Revisited: Syntheses, Structures and Reactions of [TcH3(PPh3)4] and [TcH(CO)3(PPh3)2]
Rhenium and Technetium Chemistry
Federico Salsi, Michael Neville, Myles Drance, Adelheid Hagenbach,Joshua S. Figueroa, Ulrich Abram
{MI(CO)X(CNArDArF2)4} (DArF = 3,5-(CF3)2C6H3; M = Re, Tc; X = Br, Cl) Complexes: Convenient Platforms for the Synthesis of Low-valent Rhenium and Technetium Compounds
Rhenium and Technetium Chemistry
Li Bo, Sarah Hildebrandt, Adelheid Hagenbach, Ulrich Abram
Tricarbonylrhenium(I) and -technetium(I) Complexes with Tris(1,2,3-triazolyl)phosphine Oxides
Rhenium Chemistry
Sarah Hildebrandt, Adelheid Hagenbach, Ulrich Abram
Tricarbonylrhenium(I) Complexes with Tridentate Schiff Base
Rhenium Chemistry
André G. de A. Fernandes, Rommel B. Viana, Rodolfo Moreno-Fuquen, Claudia C. Gatto, Ernesto S. Lang, Marcel Z. Modolo, Amandha K. Silva, Sebastião S. Lemos, Adelheid Hagenbach, Ulrich Abram, Victor M. Deflon
Oxorhenium(V) complexes with a benzyldithiocarbazate ligand: synthesis, crystal structure, spectroscopic and DFT analyses
Technetium Chemistry
Stephen Bauters, Andreas C. Scheinost, Katja Schmeide, Stephan Weiss, Kathy Dardenne,
Jörg Rothe, Natalia Mayordomo, Robin Steudtner, Thorsten Stumpf, Ulrich Abram, Sergei M.
Butorine, Kristina O. Kvashnina
Signatures of Technetium Oxidation States: A New Approach
Technetium Chemistry
Anna C. Grunwald, Clemens Scholtysik, Adelheid Hagenbach, Ulrich Abram
One Ligand, One Metal, Seven Oxidation States - Stable Technetium Complexes with the ‘Kläui Ligand’
Technetium Chemistry
Guilhem Claude, Federico Salsi, Adelheid Hagenbach, Milan Gembicky, Myles J. Drance, Michael Neville, Chinglin Chan, Joshua S. Figueroa, and Ulrich Abram
Structural and Redox Variations in Technetium Complexes Supported by m-Terphenyl Isocyanides
Rhenium Chemistry
Joshua S. Figueroa and Ulrich Abram
Oxidorhenium(V) and Rhenium(III) Complexes with m-Terphenyl Isocyanides
Rhenium Chemistry
Federico Salsi, Michael Neville, Myles Drance, Adelheid Hagenbach, Chinglin Chan, Joshua S. Figueroa, Ulrich Abram
A Closed-Shell Monomeric Rhenium(1-) Anion Provided by m-Terphenyl Isocyanide Ligation
