Archive of Paper Highlights

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July 2017

  • Broad substrate tolerance of tubulin tyrosine ligase enables one-step site-specific enzymatic protein labeling

    D. Schumacher, O. Lemke, J. Helma, L. Gerszonowicz, V. Waller, T. Stoschek, P. Durkin, N. Budisa, H. Leonhardt, B.G. Keller, C. Hackenberger, Chem. Sci. 2017, 8, 3471-3478 (DOI: 10.1039/C7SC00574A)

  • Thermal disproportionation of oxo-functionalized graphene

    Fabian Grote, Christoph Gruber, Felix Börrnert, Ute Kaiser, Siegfried Eigler, Angew. Chem. Int. Ed. 2017, Online Version

  • Illuminating Iron: Mesoionic Carbenes as Privileged Ligands in Photochemistry

    B. Sarkar, L. Suntrup, Angew. Chem. Int. Ed. 2017, Online Version

  • Tricyanomethane and Its Ketenimine Tautomer: Generation from Different Precursors and Analysis in Solution, Argon Matrix, and as a Single Crystal

    Klaus Banert, Madhu Chityala, Manfred Hagedorn, Helmut Beckers, Tony Stüker, Sebastian Riedel, Tobias Rüffer, and Heinrich Lang, Angew. Chem. Int. Ed. 2017, Online Version

June 2017

  • Palladium-Catalyzed Directed Halogenation of Bipyridine N-Oxides

    Sina P. Zucker, Friedrich Wossidlo, Manuela Weber, Dieter Lentz, and C. Christoph Tzschucke, J. Org. Chem. 2017, Article ASAP

  • Superacids Based on Pentafluoroorthotellurate Derivatives of Aluminum

    A. Wiesner, T. W. Gries, S. Steinhauer, H. Beckers, S. Riedel, Angew. Chem. Int. Ed. 2017, Online

May 2017

  • Data-based modeling of drug penetration relates human skin barrier function to the interplay of diffusivity and free-energy profiles

    Robert Schulz, Kenji Yamamoto, André Klossek, Roman Flesch, Stefan Hönzke, Fiorenza Rancan, Annika Vogt, Ulrike Blume-Peytavi, Sarah Hedtrich, Monika Schäfer-Korting, Eckart Rühl, and Roland R. Netz, Proc. Natl. Acad. Sci. USA 2017, 114(14), 3631-3636

April 2017

  • Internal Dynamics of the 3-Pyrroline-N-Oxide Ring in Spin-Labeled Proteins

    P. Consentius, B. Loll , U. Gohlke, C. Alings, C. Müller, R. Müller, C. Teutloff, U. Heinemann, M. Kaupp, M. C. Wahl, and T. Risse, J. Phys. Chem. Lett. 2017, 8(6), 1113-1117

March 2017

  • PolyWhips: Directional particle transport by gradient-directed growth and stiffening of supramolecular assemblies

    L. Cera, L. Chiappisi, C. Böttcher, A. Schulz, S. Schoder, M. Gradzielski, C.A. Schalley, Adv. Mater. 2017, 29(8), 1604430

February 2017

January 2017

  • Discovery and Investigation of Natural Editing Function against Artificial Amino Acids in Protein Translation

    J. Völler, M. Dulic, U. Gerling-Driessen, H. Biava, T. Baumann, N. Budisa, I. Gruic-Sovulj, B. Koksch, ACS Cent. Sci. 2016, advance publication on the web

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December 2016

  • Core-multishell nanocarriers: Transport and release of dexamethasone probed by soft X-ray spectromicroscopy

    K. Yamamoto, A. Klossek, R. Flesch, T. Ohigashi, E. Fleige, F. Rancan, J. Frombach, A. Vogt, U. Blume-Peytavi, P. Schrade, S. Bachmann, R. Haag, S. Hedtrich, M. Schäfer-Korting, N. Kosugi, E. Rühl, J. Control. Release 2016, 242, 64-70

November 2016

  • Tracking Transient Conformational States of T4 Lysozyme at Room Temperature Combining X-ray Crystallography and Site-Directed Spin Labeling

    P. Consentius, U. Gohlke, B. Loll, C. Alings, R. Müller, U. Heinemann, M. Kaupp, M. Wahl, and T. Risse, J. Am. Chem. Soc. 2016, 138(39), 12868.12875

October 2016

  • Intradomain Allosteric Network Modulates Calcium Affinity of the C-Type Lectin Receptor Langerin

    Jonas Hanske, Stevan Aleksic, Martin Ballaschk, Marcel Jurk, Elena Shanina, Monika Beerbaum, Peter Schmieder, Bettina G. Keller, Christoph Rademacher, J. Am. Chem. Soc. 2016, 138(37), 12176-12186

August/September 2016

  • Structural Proof for the First Dianion of a Polychloride: Investigation of [Cl8]2−

    Robin Brückner, Patrick Pröhm, Anja Wiesner, Simon Steinhauer, Carsten Müller, Sebastian Riedel, Angew. Chem. Int. Ed. 2016, 55(36), 10904-10908

  • Clicking the Arsenic–Carbon Triple Bond: An Entry into a New Class of Arsenic Heterocycles

    Gregor Pfeifer, Martin Papke, Daniel Frost, Julian A. W. Sklorz, Marija Habicht, Christian Müller, Angew. Chem. Int. Ed. 2016, Early View

  • Retention of Native Protein Structures in the Absence of Solvent: A Coupled Ion Mobility and Spectroscopic Study

    J. Seo, J., W. Hoffmann, S. Warnke, M. T. Bowers, K. Pagel, G. von Helden, Angew. Chem. Int. Ed. 2016, Early View

  • Synthesis of Strophasterol A Guided by a Proposed Biosynthesis and Innate Reactivity

    R. C. Heinze, D. Lentz, P. Heretsch, Angew. Chem. Int. Ed. 2016, Early View

July 2016

  • Significantly enhanced proteolytic activity of cyclen complexes by monoalkylation

    Chrischani Perera-Bobusch, Jan Hormann, Christoph Weise, Stefanie Wedepohl, Jens Dernedde and Nora Kulak, Dalton Trans. 2016, 45, 10500-10504

June 2016

  • A combined in-situ XAS-DRIFTS study unraveling adsorbate induced changes on the Pt nanoparticle structure

    C. Brieger, J. Melke, N. van der Bosch, U. Reinholz, H. Riesemeier, A. Guilherme Buzanich, M. Krishna Kayarkatte, I. Derr, A. Schökel, C. Roth, J. Catal. 2016, 339, 57-67

May 2016

  • Introducing Chirality into Nonionic Dendritic Amphiphiles and Studying Their Supramolecular Assembly

    Sumit Kumar, Kai Ludwig, Boris Schade, Hans von Berlepsch, Ilona Papp, Rahul Tyagi, Monika Gulia, Rainer Haag, and Christoph Böttcher, Chem. Eur. J. 2016, 22(16), 5629-5636

  • Expanding the phosphorus–carbon analogy: formation of an unprecedented 5-phosphasemibullvalene derivative

    Massimo Rigo, Manuela Weber and Christian Müller, Chem. Comm. 2016, Advance Article

April 2016

  • Catalysis of “outer-phase” oxygen atom exchange reactions by encapsulated “inner-phase” water in {V15Sb6}-type polyoxovanadates

    M. Wendt, U. Warzok, C. Näther, J. van Leusen, P. Kögerler, C.A. Schalley, W. Bensch, Chem. Sci. 2016, 7, 2684-2694

  • Polymeric near-infrared absorbing dendritic nanogels for efficient in vivo photothermal cancer therapy

    Maria Molina, Stefanie Wedepohl and Marcelo Calderón, Nanoscale 2016, 8, 5852-5856

March 2016

  • A four-coordinate cobalt(II) single-ion magnet with coercivity and a very high energy barrier

    Y. Rechkemmer, F. D. Breitgoff, M. van der Meer, M. Atanasov, M. Hakl, M. Orlita, P. Neugebauer, F. Neese, B. Sarkar, J. van Slageren, Nature Commun. 2016, 7, #10467

  • Controlling the Interaction and Non-Close-Packed Arrangement of Nanoparticles on Large Areas

    Madlen Schmudde, Christian Grunewald, Christian Goroncy, Christelle N. Noufele, Benjamin Stein, Thomas Risse, and Christina Graf, ACS Nano 2016, Article ASAP

  • Charge-Induced Unzipping of Isolated Proteins to a Defined Secondary Structure

    A. I. González Flórez, E. Mucha, D.-S. Ahn, S. Gewinner, W. Schöllkopf, K. Pagel, G. von Helden, Angew. Chem. Int. Ed. 2016, 55(10), 3295-3299

February 2016

January 2016

  • Quantitative study of ruthenium cross-over in direct methanol fuel cells during early operation hours

    A. Schoekel, J. Melke, M. Bruns, K. Wippermann, F. Kuppler, C. Roth, J. Power Sources 2016, 301, 210-218

  • A 2D Polychloride Network Held Together by Halogen–Halogen Interactions

    Robin Brückner, Heike Haller, Simon Steinhauer, Carsten Müller und Sebastian Riedel, Angew. Chem. Int. Ed. 2015, 54(51), 15579-15583

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December 2015

  • Quantum theory of concerted electronic and nuclear fluxes associated with adiabatic intramolecular processes

    Timm Bredtmann, Dennis J. Diestler, Si-Dian Li, Jörn Manz, Jhon Fredy Pérez-Torres, Wen-Juan Tian, Yan-Bo Wu, Yonggang Yang and Hua-Jin Zhai, Phys. Chem. Chem. Phys. 2015 17(44), 29421-29464

November 2015

  • Structural Insights into the Incorporation of the Mo Cofactor into Sulfite Oxidase from Site-Directed Spin Labeling

    Aaron Hahn, Christopher Engelhard, Stefan Reschke, Christian Teutloff, Robert Bittl, Silke Leimkühler, Thomas Risse, Angew. Chem. Int. Ed. 2015 54(40), 11865-11869

  • Experimental and Theoretical Investigations of the Existence of CuII, CuIII, and CuIV in Copper Corrolato Complexes

    Woormileela Sinha, Michael G. Sommer, Naina Deibel, Fabian Ehret, Matthias Bauer, Biprajit Sarkar, Sanjib Kar, Angew. Chem. Int. Ed. 2015 54(46), 13769-13774

October 2015

September 2015

  • Field propagation-induced directionality of carrier-envelope phase-controlled photoemission from nanospheres

    F. Süßmann, L. Seiffert, S. Zherebtsov, V. Mondes, J. Stierle, M. Arbeiter, J. Plenge, P. Rupp, C. Peltz, A. Kessel, S.A. Trushin, B. Ahn, D. Kim, C. Graf, E. Rühl, M. F. Kling, T. Fennel, Nature Communications 2015, 6, article no. 7944

  • [Fe19] "Super-Lindqvist" Aggregate and Large 3D Interpenetrating  Coordination Polymer from Solvothermal Reactions of [Fe2(OtBu)6] with Ethanol

    Olaf Nachtigall, Matthias Kusserow, Rodolphe Clérac, Wolfgang Wernsdorfer, Michael Menzel, Franz Renz, Jerzy Mrozinski and Johann Spandl, Angew. Chem. Int. Ed. 2015, 54(35), 10361-10364

  • Fluorine teams up with water to restore inhibitor activity to mutant BPTI

    S. Ye, B. Loll, A.A. Berger, U. Mülow, C. Alings, M. Wahl, B. Koksch, Chem. Sci. 2015, 6(X), 5246-5254

August 2015

  • Fluorine-Rich Fluorides: New Insights into the Chemistry of Polyfluoride Anions

    Thomas Vent-Schmidt, Felix Brosi, Jens Metzger, Tobias Schlöder, Xuefeng Wang, Lester Andrews, Carsten Müller, Helmut Beckers and Sebastian Riedel, Angew. Chem. Int. Ed. 2015, 54(28), 8279-8283

July 2015

  • Selective Probing of the Penetration of Dexamethasone into Human Skin by Soft X-ray Spectromicroscopy

    K. Yamamoto, R. Flesch, T. Ohigashi, S. Hedtrich, A. Klossek, P. Patoka, G. Ulrich, S. Ahlberg, F. Rancan, A. Vogt, U. Blume-Peytavi, P. Schrade, S. Bachmann, M. Schäfer-Korting, N. Kosugi, and E. Rühl, Anal. Chem. 2015, 87(12), 6173-6179

June 2015

May 2015

April 2015

  • (-)-Englerin A is a Potent and Selective Activator of TRPC4 and TRPC5 Calcium Channels

    Y. Akbulut, H. J. Gaunt, K. Muraki, M. J. Ludlow, M. S. Amer, A. Bruns, N. S. Vasudev, L. Radtke, M. Willot, S. Hahn, T. Seitz, S. Ziegler, M. Christmann, D. J. Beech, H. Waldmann, Angew. Chem. Int. Ed. 2015, 54(12), 3787-3791

  • Dendritic polymer imaging systems for the evaluation of conjugate uptake and cleavage

    H. R. Krüger, G. Nagel, S. Wedepohl, M. Calderón, Nanoscale 2015, 7(9), 3838-3844

  • The Ligand Field of the Azido Ligand: Insights into Bonding Parameters and Magnetic Anisotropy in a Co(II)-Azido Complex

    D. Schweinfurth, M. G. Sommer, M. Atanasov, S. Demeshko, S. Hohloch, F. Meyer, F. Neese, B. Sarkar, J. Am. Chem. Soc. 2015, 137(5), 1993-2005

  • Amphiphilic Perylene–Calix[4]arene Hybrids: Synthesis and Tunable Self-Assembly

    Fabian Rodler, Boris Schade, Christof M. Jäger, Susanne Backes, Frank Hampel, Christoph Böttcher, Timothy Clark, and Andreas Hirsch, J. Am. Chem. Soc. 2015, 137(9), 3308-3317

March 2015

  • Synthesis of Polycyclic Tertiary Carbinamines by Samarium Diiodide Mediated Cyclizations of Indolyl Sulfinyl Imines

    Chintada Nageswara Rao, Dieter Lentz, Hans-Ulrich Reissig, Angew. Chem. Int. Ed. 2015, 54(9), 2750-2753

  • Chemical Assembly Systems: Layered Control for Divergent, Continuous, Multistep Syntheses of Active Pharmaceutical Ingredients

    Diego Ghislieri, Kerry Gilmore, Peter H. Seeberger, Angew. Chem. Int. Ed. 2015, 54(2), 678-682

February 2015

  • Photoionization of the 3s2 3p4 3P and the 3s2 3p4 1D, 1S states of sulfur: Experiment and theory

    Mathias Barthel, Roman Flesch, Eckart Rühl, and Brendan M. McLaughlin, Phys. Rev. A 2015, 91, 013406

January 2015

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December 2014

  • Supramolecular Polymers as Surface Coatings: Rapid Fabrication of Healable Superhydrophobic and Slippery Surfaces

    Qiang Wei, Christoph Schlaich, Sylvain Prévost, Andrea Schulz, Christoph Böttcher, Michael Gradzielski, Zhenhui Qi, Rainer Haag and Christoph A. Schalley, Adv. Mater. 2014, 26(43), 7358-7364

November 2014 - Month of Publications

  • Sebastian Riedel in Nature:

    Identification of an iridium-containing compound with a formal oxidation state of IX

    G. Wang, M. Zhou, J.T. Goettel, J. Schrobilgen, J. Su, J. Li, T. Schlöder, S. Riedel, Nature 2014, 514(7523), 475-477

  • Rainer Haag in Angewandte Chemie:

    Mussel-Inspired Dendritic Polymers as Universal Multifunctional Coatings

    Q. Wei, K. Achazi, H. Liebe, A. Schulz, P.-L.M. Noeske, I. Grunwald, R. Haag, Angew. Chem. Int. Ed. 2014, 53(43), 11650–11655

  • again Rainer Haag in Angewandte Chemie:

    Photoresponsive Switches at Surfaces Based on Supramolecular Functionalization with Azobenzene–Oligoglycerol Conjugates

    O. Nachtigall, C. Kördel, L.H. Urner, R. Haag, Angew. Chem. Int. Ed. 2014, 53(36), 9669–9673

  • Eugen Illenberger in Angewandte Chemie:

    Reactions in Nitroimidazole Triggered by Low-Energy (0–2 eV) Electrons: Methylation at N1-H Completely Blocks Reactivity

    K. Tanzer, L. Feketeova, B. Puschnigg, P. Scheier, E. Illenberger, S. Denifl, Angew. Chem. Int. Ed. 2014, 53(45), 12240–12243

October 2014

September 2014

  • Oxygen Transfer from an Intramolecularly Coordinated Diaryltellurium Oxide to Acetonitrile. Formation and Combined AIM and ELI-D Analysis of a Novel Diaryltellurium Acetimidate

    Ole Mallow, Jens Bolsinger, Pamela Finke, Malte Hesse, Yu-Sheng Chen, Andrew Duthie, Simon Grabowsky, Peter Luger, Stefan Mebs, and Jens Beckmann, J. Am. Chem. Soc. 2014, 136(31), 10870-10873

  • Tuning the electronic effects of aromatic phosphorus heterocycles: an unprecedented phosphinine with significant P(π)-donor properties

    Antonia Loibl, Iris de Krom, Evgeny A. Pidko, Manuela Weber, Jelena Wiecko and Christian Müller, Chem. Commun. 2014, 50, 8842-8844

  • Cyclometalated Mono- and Dinuclear IrIII Complexes with “Click”-Derived Triazoles and Mesoionic Carbenes

    Ramananda Maity, Stephan Hohloch, Cheng-Yong Su, Margarethe van der Meer and Biprajit Sarkar, Chem. Eur. J. 2014, 20(32), 9952-9961

August 2014

  • Unprecedented Strong Lewis Bases - Synthesis and Methyl Cation Affinities of Dimethylamino-Substituted Terpyridines

    Paul Hommes, Christina Fischer, Christoph Lindner, Hendrik Zipse and Hans-Ulrich Reissig, Angew. Chem. 2014, 53(29), 7647-7651

  • Iron oxide nanoparticles stabilized with dendritic polyglycerols as selective MRI contrast agents

    Daniel Nordmeyer, Patrick Stumpf, Dominic Gröger, Andreas Hofmann, Sven Enders, Sebastian B. Riese, Jens Dernedde, Matthias Taupitz, Ursula Rauch, Rainer Haag, Eckart Rühl and Christina Graf, Nanoscale 2014, 6, 9646-9654

July 2014

  • Hierarchically Ordered Self-Assembly of Amphiphilic Bifullerenes

    L. Wasserthal, B. Schade, K. Ludwig, C. Böttcher, A. Hirsch, Chem. Eur. J. 2014, 20(20), 5961-5966

  • Following ORR intermediates adsorbed on a Pt cathode catalyst during break-in of a PEM fuel cell by in operando X-ray absorption spectroscopy

    D. E. Ramaker, A. Korovina, V. Croze, J. Melke, C. Roth, Phys. Chem. Chem. Phys. 2014, 16, 13645-13653

June 2014

  • A Universal Approach to Crosslinked Hierarchical Polymer Multilayers as Stable and Highly Effective Antifouling Coatings

    Q. Wei, T. Becherer, P.-L. M. Noeske, I. Grunwald, R. Haag, Adv. Mater. 2014, 26(17), 2688-2693

  • Stimuli-induced folding cascade of a linear oligomeric guest chain programmed through cucurbit[n]uril self-sorting (n = 6, 7, 8)

    L. Cera, C.A. Schalley, Chem. Sci. 2014, 5(6), 2560-2567

May 2014

April 2014

  • Redox-Induced Spin-State Switching and Mixed Valency in Quinonoid-Bridged Dicobalt Complexes

    David Schweinfurth, Yvonne Rechkemmer, Stephan Hohloch, Naina Deibel, Irina Peremykin, Jan Fiedler, Raphael Marx, Petr Neugebauer, Joris van Slageren, and Biprajit Sarkar, Chem. Eur. J. 2014, 20(12), 3475-3486

March 2014

  • Carbohydrate-Lectin Recognition of Sequence-Defined Heteromultivalent Glycooligomers

    D. Ponader, P. Maffre, J. Aretz, D. Pussak, N. M. Ninnemann, S. Schmidt, P. H.
    Seeberger, C. Rademacher, G. U. Nienhaus, L. Hartmann, J. Am. Chem. Soc. 2014, 136(5), 2008-2016

  • Ruthenium Complexes of Tripodal Ligands with Pyridine and Triazole Arms: Subtle Tuning of Thermal, Electrochemical, and Photochemical Reactivity

    F. Weisser, S. Hohloch, S. Plebst, D. Schweinfurth, B. Sarkar, Chem. Eur. J. 2014, 20(3), 781-793

February 2014

  • Porphyrin Assemblies and Their Scaffolds

    J.-H. Fuhrhop, Langmuir 2014, 30(1), 1-12

  • Partial side chain fluorination influencing amyloid formation: a symphony of size, hydrophobicity, and alpha-helix propensity

    U.I.M. Gerling, M. Salwiczek, C.D. Cadicamo, H. Erdbrink, S. Grage, P. Wadhwani, A. Ulrich, M. Behrens, G. Haufe, C. Czekelius, B. Koksch, Chem. Sci. 2014, 5(2), 819-830

January 2014

  • A Microgel Construction Kit for Bioorthogonal Encapsulation and pH-Controlled Release of Living Cells

    D. Steinhilber, T. Rossow, S. Wedepohl, F. Paulus, S. Seiffert, R. Haag, Angew. Chem. Int. Ed. 2013, 52(51), 13538-13543

  • NMR Studies of Protonation and Hydrogen Bond States of Internal Aldimines of Pyridoxal 5'-Phosphate Acid-Base in Alanine Racemase, Aspartate Aminotransferase and Poly-L-lysine

    Monique Chan-Huot, Alexandra Dos, Reinhard Zander, Shasad Sharif, Peter M. Tolstoy, Shara Compton, Emily Fogle, Michael D. Toney, Ilya Shenderovich, Gleb S. Denisov, and Hans-Heinrich Limbach, J. Am. Chem. Soc. 2013, 135(48), 18160-18175

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December 2013

November 2013

  • The role of statistics and microenvironment for the photoresponse in multi-switch architectures: The case of photo switchable oligoazobenzene foldamers

    Z. Yu, S. Weidner, T. Risse, S. Hecht, Chemical Science 2013, 4(11), 4156-4167

  • Nuclear Fluxes in Diatomic Molecules Deduced from Pump-Probe Spectra with Spatiotemporal Resolutions down to 5 pm and 200 asec

    J. Manz, J.F. Perez-Torres, Y. Yang, Phys. Rev. Lett. 2013, 111, 153004

  • Cyclometalation of Aryl-Substituted Phosphinines through C-H-Bond Activation: A Mechanistic Investigation

    L. E. E. Broeckx, S. Güven, F. J. L. Heutz, M. Lutz, D. Vogt, C. Müller, Chem. Eur. J. 2013, 19(39), 13087-13098

October 2013

  • Synthesis and Biological Evaluation of Radio and Dye Labeled Amino Functionalized Dendritic Polyglycerol Sulfates as Multivalent Anti-Inflammatory Compounds

    D. Gröger, F. Paulus, K. Licha, P. Welker, M. Weinhart, C. Holzhausen, L. Mundhenk, U. Abram, A. D. Gruber, and R. Haag, Bioconjugate Chemistry 2013, 24, 1507-1514

  • Structural motifs of pre-nucleation clusters

    Y. Zhang, I. R. Türkmen, B. Wassermann, A. Erko, and E. Rühl, J. Chem. Phys. 2013, 139, 134506

September 2013

August 2013 and Archive of Paper Highlights

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