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Investigation of Gold Fluorides and Noble Gas Complexes by Matrix-Isolation Spectroscopy and Quantum-Chemical Calculations

Xuefeng Wang, Lester Andrews, Knut Willmann, Felix Brosi, Sebastian Riedel— 2012

Noble with a difference: Matrix-isolation experiments and quantum-chemical calculations have led to the characterization of two new compounds, namely first open-shell binary gold fluoride, AuF₂, and a NeAuF complex. Moreover, ArAuF, AuF₃, Au₂F₆, and monomeric AuF5 have been produced and identified under cryogenic conditions in neon and argon matrices.

TitelInvestigation of Gold Fluorides and Noble Gas Complexes by Matrix-Isolation Spectroscopy and Quantum-Chemical Calculations
VerfasserXuefeng Wang, Lester Andrews, Knut Willmann, Felix Brosi, Sebastian Riedel
Datum2012
Kennung10.1002/anie.201205072
Quelle/n
Erschienen inAngew. Chem. Int. Ed. 2012, 51, 10628–10632 (Angew. Chem. 2012, 124, 10780–10784)
Spracheeng
ArtText