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Hans-Heinrich Limbach

hhl

Institut für Chemie und Biochemie

Physikalische und Theoretische Chemie

Professor Dr. emeritus

Adresse Takustraße 3
Raum ?
14195 Berlin
E-Mail limbach (at) chemie.fu-berlin.de

 

Curriculum vitae H.H.Limbach

  • Born 1943 in Brühl/Cologne
  • Studies of Chemistry at the Universities of Bonn and Freiburg. Diploma Freiburg 1969, Dr. rer. nat. Freiburg 1973, Habilitation Freiburg 1980
  • Visiting scientist IBM Research Laboratory, San Jose, USA 1983 and UC Berkeley 1984
  • Professor of Chemistry at the Free University of Berlin 1990
  • Coordinator of the bilingual master study programme chemistry at the Free University of Berlin 1997
  • Coordinator of the International PhD Programme Chemistry at the Free University of Berlin 2003
  • Coordinator of a European Network in the Human Capital & Mobility program on "Localization and Transfer of Hydrogen" 1995-1998
  • Member 1996 and Head 1997 of the program commitee of the Deutsche Bunsengesellschaft für Physikalische Chemie
  • Organization of the International Autumn Bunsen Discussion Meeting "Hydrogen Transfer: Experiment and Theory", Berlin, September 1997 (mit J.Manz).
  • Guest Editor March-Issue 1998 of Berichte der Bunsen-Gesellschaft - Physical Chemistry Chemical Physics on "Hydrogen Transfer: Experiment and Theory" (with J.Manz)
  • Vice Chair Isotopes Gordon Conference 2000; Chair of the Isotope Gordon Conference 2002.
  • Co-organization of the programme of the Annual Meeting of the Deutsche Bunsengesellschaft für Physikalische Chemie 2002 on "Kern- und Elektronenspins als dynamische und kinetische Sonden"
  • Member of Editorial Board Magn.Res.Chem., 1997 Member of Editorial Board Spect. Lett. 1996
  • Guest Editor 2001 Journal "Magnetic Resonance in Chemistry" Special Issue NMR and Hydrogen Bonds
  • Associate Editorial Board member of "Chemical Physics" 2001
  • Member Advisory Board of the International Conference on "Horizons in Hydrogen Bond Research" 1998
  • President Advisory Board of the Internationalen Conference on "Horizons in Hydrogen Bond Research" 2001-2003
  • Chair of this conference Berlin 2003
  • Heisenberg fellow of the Deutsche Forschungsgemeinschaft 1981
  • Lecture fellowship of the Fonds der Chemischen Industrie Frankfurt 1982
  • Hermanos Elhuyar-Hans Goldschmidt-Lecture award from the Gesellschaft Deutscher Chemiker and the Real Sociedad Española de Química 1999.
  • Honorary Professor of Physics at the Faculty of Physics, State University St. Petersburg, Russia
  • Walther-Nernst-Denkmünze Award of the Deutsche Bunsengesellschaft of Physical Chemistry

Frühere Forschungsgebiete der Arbeitsgruppe Limbach (Prof. Limbach ist im Ruhestand)

A. Kohen, H.H. Limbach "Isotope Effects in Chemistry and Biology"

KEYWORDS

Low temperature liquid and solid state NMR, hydrogen transfer and hydrogen bonding, catalysis, isotope effects and labels, crystalline and amorphous solids, surfaces.

ABSTRACT

The current research program is focused on the design and the study by NMR spectroscopy of the structure and dynamics of isotopically labeled molecular model systems for proton and hydride transfer.

The range between small organic molecules embedded in liquids, solids and surfaces, modified enzymes, oligonucleotides and transition metal hydrides is covered. All instruments of variable temperature liquid and solid state NMR spectroscopy are applied.

The aim is to measure kinetic, equilibrium and geometric isotope and tunnel effects of hydrogen transfer in high- and low-barrier hydrogen bonds and in the coordination sphere of transition metal catalysts, and to model the results theoretically.

A substantial part of the work is done in collaboration with other research groups specialized in the areas of spectroscopy, synthetic and theoretical chemistry, supramolecular, polymer and biochemistry, material and surface science.

H. H. Limbach: List of Publications

For reprints please send a mail to: limbach@chemie.fu-berlin.de

 

Journal Articles

 

20132012 2011 2010 2009 2008 2007 2006 2005 2004 2003 2002 2001 2000 1999 1998 1997 1996 1995 1994 19931992 1991 1990 1989 1988 1987 1986-1980 1979-1970

Reviews in Books and Monographs

Monographs and Special Issues

Journal Articles

 

2013

256.   Jochen Matthes, Stephan Gründemann, Gerd Buntkowsky, Bruno Chaudret, Hans-Heinrich Limbach,* Applied Magnetic Resonance, 2013, 44, 247–265. http://dx.doi.org/10.1007/s00723-012-0395-9. Special issue Prof. H. M. Vieth. NMR Studies of the Reaction Path of the catalyzed ortho-para-H2 Conversion in Solid Benzene.

255.   Bob Grünberg, Anna Grünberg, Hans-Heinrich Limbach, Gerd Buntkowsky. Applied Magnetic Resonance, 2013, 44, 189-201. http://dx.doi.org/10.1007/s00723-012-0393-y. Special issue Prof. H. M. Vieth. Melting of Naphthalene confined in mesoporous Silica MCM-41.

 

2012

254.   Veronica Torres, Juan-Miguel Lopez, Uwe Langer, Gerd Buntkowsky, Hans-Martin Vieth, Jose Elguero, Hans-Heinrich Limbach,* Z. Phys. Chem. 2012, 226, 1125–1147.http://dx.doi.org/10.1524/zpch.2012.0305. Special Issue Prof. H. W. Spiess. Kinetics of Coupled Double Proton and Deuteron Transfer in Hydrogen-bonded Ribjbons of Crystalline Pyrazole-4-carboxylic Acid.

253.   N. de Sousa Amadeu, B. Grünberg,J. Frydel, M. Werner, H.-H. Limbach, H. Breitzke, G. Buntkowsky*, Z. Phys. Chem. 2012, 226, 1169-1186. http://dx.doi.org/10.1524/zpch.2012.0304. Special Issue Prof. H. W. Spiess. Melting of low molecular weight compounds in confinement observed by 2H-Solid State NMR: biphenyl, a case study.

252.   Brenda C. K. Ip, Ilja G. Shenderovich, Peter M. Tolstoy, Jaroslaw Frydel, Gleb S. Denisov, Gerd Buntkowsky, Hans-Heinrich Limbach.* J. Phys. Chem. A. 2012, 116, 11370–11387. http://dx.doi.org/10.1021/jp305863n.Supporting information. Jörn Manz Festschrift. Geometric Hydrogen bond H/D Isotope Effects and Isotopic Polymorphism of Solid 4-Methylpyridine-Pentachlorophenol revealed by NMR: Implications for the Shapes of Hydrogen-bonded Protons in the Solid and the Liquid State

251.   Jing Guo, Peter M. Tolstoy,* Benjamin Koeppe, Nikolai S. Golubev, Gleb S. Denisov, Sergei N. Smirnov, Hans-Heinrich Limbach. J. Phys. Chem. A. 2012, 116, 11180–11188. Jörn Manz Festschrift. http://dx.doi.org/10.1021/jp304943h. Hydrogen Bond Geometries and Proton Tautomerism of Homo-Conjugated Anions of Carboxylic Acids Studied via H/D Isotope Effects on 13C NMR Chemical Shifts NMR.

250.   Natalia Pérez-Hernández, Trung Quan Luong, Martín Febles, Carlos Marco, Hans-Heinrich Limbach, Martina Havenith, Cirilo Pérez, María Victoria Roux, Ricardo Pérez, Julio D. Martín,* J. Phys. Chem. C, 2012, 116, 9616–9630. http://dx.doi.org/10.1021/jp301323c. The Mobility of Water Molecules through Hydrated Pores.

 

2011

249.   Iker del Rosal, Torsten Gutman, Bernadeta Walaszek, Iann C. Gerber, Bruno Chaudret, Hans-Heinrich Limbach, Gerd Buntkowsky, Romuald Poteau,* Phys. Chem. Chem. Phys. , 2011, 13, 20199-20207. http://dx.doi.org/10.1039/C1CP22081K. Electronic Supplementary Material. 2H NMR calculations on polynuclear transition metal complexes: on the influence of local symmetry.

248.   Jing Guo, Peter M. Tolstoy,* Benjamin Koeppe, Gleb S. Denisov, Hans-Heinrich Limbach, J. Phys. Chem. A , 2011, 115, 9828-9836. http://dx.doi.org/10.1021/jp201073j. Electronic Supplementary Material. NMR Study of Conformational Exchange and Geometries of Intramolecular Hydrogen Bonds in Monoanions of Succinic Acid and Derivatives.

247.   Hans-Heinrich Limbach,*Monique Chan-Huot, Shasad Sharif, Peter M. Tolstoy, Ilya G. Shenderovich, Gleb S. Denisov, Michael D. Toney. Biochemica Biophysica Acta, Proteins & Proteomics 2011, 1814, 1426-1437. http://dx.doi.org/10.1016/j.bbapap.2011.06.004. Critical hydrogen bonds and protonation states of pyridoxal 5′-phosphate revealed by NMR. Special thematic issue Pyridoxal Phosphate Enzymology.

246.   Stepan B. Lesnichin, Titin Muljati, Ilya G. Shenderovich,* Hans-Heinrich Limbach,* David N. Silverman, J. Am. Chem. Soc. 2011, 133, 11331–11338.http://pubs.acs.org/doi/abs/10.1021/ja203478j. Intrinsic Proton Donating Power of Zinc-bound Water in a Carbonic Anhydrase Active Site Model Estimated by NMR.

245.   Benjamin Koeppe, Peter M. Tolstoy*, Hans-Heinrich Limbach, J. Am. Chem. Soc. 2011, 133, 7897–7908. http://pubs.acs.org/doi/abs/10.1021/ja201113a. Supporting information. Proton transfer pathways in strong anionic H-bonds in aprotic solution. A low-temperature UVNMR study.

244.   Natalia Pérez-Hernández,* Martín Febles, Cirilo Pérez, Johann Spandl, Julio D. Martín, Hans-Heinrich Limbach,* J. Phys. Chem. C 2011, 115, 9393–9402. Supporting information. http://dx.doi.org/10.1021/jp112105j. IR Studies of H/D Exchange of Water, Hydroxyl, and Carboxylic Groups Reveal Slowly Diffusing Lattice Defects in Sub-Nanometer Pores

243.   J. A. Frydel, M. Krzystyniak, D. Pienkowski, M. Pietrzak, N. Amadeu de Sousa, T. Ratajczyk, K Idzik, T. Gutmann, D. Tietze, S. Voigt, A. Fenn, H.H. Limbach, G. Buntkowsky, Solid State Nuclear Magnetic Resonance 2011, 72-80. http://dx.doi.org/10.1016/j.ssnmr.2011.01.001.Efficient design of multituned transmission line NMR probes: The electrical engineering approach.

242a. Dariush Ajami, Peter M. Tolstoy, Henry Dube, Severin Odermatt, Benjamin Koeppe, Jing Guo, Hans-Heinrich Limbach,* Julius Rebek, Jr.* Ang. Chem. 2011, 123, 548–552. http://dx.doi.org/10.1002/ange.201002182. Supporting Information. Eingekapselte Carbons ure-Dimere mit verkürzten Wasserstoffbrücken.

242b. Dariush Ajami, Peter M. Tolstoy, Henry Dube, Severin Odermatt, Benjamin Koeppe, Jing Guo, Hans-Heinrich Limbach,* Julius Rebek, Jr.* Ang. Chem. Int. Ed. 2011, 50, 528–531. http://dx.doi.org/10.1002/anie.201002182. Supporting Information. Encapsulated Carboxylic Acid Dimers with Compressed Hydrogen Bonds.

 

2010

241.   Monique Chan-Huot, Shasad Sharif, Peter M. Tolstoy, Michael D. Toney, Hans-Heinrich Limbach,* Biochemistry, 2010, 49, 10818–10830. http://dx.doi.org/10.1021/bi101061m. NMR studies of the Stability, Protonation States and Tautomerism of 13C and 15N Labeled Aldimines of the Coenzyme Pyridoxal 5’-phosphate in Water.

240.   Peter M. Tolstoy,* Jing Guo, Benjamin Koeppe, Nikolai S. Golubev, Gleb S. Denisov, Sergei N. Smirnov, Hans-Heinrich Limbach, J. Phys. Chem. A. 2010,114,10775–10782. http://dx.doi.org/10.1021/jp1027146. Supporting Information. Geometries and Tautomerism of OHN Hydrogen Bonds in Polar Solution probed by H/D Isotope Effects on 13C NMR Chemical Shifts.

239.   Evgenia Vaganova, Ellen Wachtel, Gregory Leitus, David Danovich, Stepan Lesnichin, Ilja Shenderovich, Hans-Heinrich Limbach, Shlomo Yitzchaik, J. Phys. Chem. B. 2010, 114, 10728–10733. http://dx.doi.org/10.1021/jp104277r. Photoinduced Proton Transfer in a Pyridine Based Polymer Gel.

238.   Torsten Gutmann, Bernadeta Walaszek, Yeping Xu , Maria Wächtler, Anna Grünberg, Iker del Rosal, Romuald Poteau, Rosa Axet, Guy Lavigne, Bruno Chaudret, Hans-Heinrich Limbach and Gerd Buntkowsky,* J. Am. Chem. Soc. 2010, 132, 11759–11767. http://dx.doi.org/10.1021/ja104229a. Hydrido-ruthenium cluster complexes as models for reactive surface hydrogen species of ruthenium nanoparticles – Solid-state 2H NMR and quantum chemical calculations.

237.   Alexandra Dos, Volkmar Schimming, Monique Chan-Huot, Hans-Heinrich Limbach, Phys. Chem. Chem. Phys.,2010, 12, 10235-10245. http://dx.doi.org/10.1039/C002730H. Electronic Supplementary Information. Effects of Hydration on the Acid-Base Interactions and Secondary Structures of Poly-L-Lysine Probed by 15N and 13C Solid State NMR.

236.   Łukasz Szyc, Jing Guo, Ming Yang, Jens Dreyer, Peter M. Tolstoy, Erik T. J. Nibbering,* Bogusława Czarnik-Matusewicz, Thomas Elsaesser, Hans-Heinrich Limbach, J. Phys. Chem. B 2010, 114, 7749-7760.http://dx.doi.org/10.1021/jp103630w. The Hydrogen-Bonded 2-Pyridone Dimer Model System. I. Combined NMR and FT-IR Study.

235.   Stepan B. Lesnichin, Peter M. Tolstoy, Hans-Heinrich Limbach, Ilja G. Shenderovich*. Phys. Chem. Chem. Phys. 2010, 12, 10373-10379.http://dx.doi.org/10.1039/c004499g. Electronic Supplementary Information. Counteranion-dependent intra- vs. intermolecular hydrogen bonding and proton transfer of 2,2’-bipyridinium in CDF3Cl/CDF2Cl observed by low-temperature NMR.

234.   Monique Chan-Huot, Christiane Niether, Shasad Sharif, Peter M. Tolstoy, Michael D. Toney, Hans-Heinrich Limbach*. J. Mol. Struct. 2010, 976, 282-289. http://dx.doi.org/10.1016/j.molstruc.2010.03.032. NMR Studies of the Protonation States of Pyridoxal 5’-phosphate in Water.

233.   Hans-Heinrich Limbach, K. Barbara Schowen, Richard L. Schowen. J. Phys. Org. Chem. 2010, 23, 586–605. http://dx.doi.org/10.1002/poc.1663. Heavy atom motions and tunneling in hydrogen transfer reactions: the importance of the pre-tunneling state.

232.   Mariusz Pietrzak, Jens P. Wehling, Shushu Kong, Peter M. Tolstoy, Ilya G. Shenderovich, Concepción López, Rosa María Claramunt, José Elguero, Gleb S. Denisov,Hans-Heinrich Limbach*.Chem. Eur. J. 2010, 16, 1679-1690. http://dx.doi.org/10.1002/chem.200902259. Symmetrization of Cationic Hydrogen Bridges of Protonated Sponges Induced by Solvent and Counteranion Interactions as Revealed by NMR Spectroscopy.

 

2009

231.   Sven Macholl,* Jochen Matthes, Hans-HeinrichLimbach, SylvianeSabo-Etienne, BrunoChaudret, Gerd Buntkowsky*. Solid State NMR, 2009, 36,137-143. http://dx.doi.org/10.1016/j.ssnmr.2009.08.001. High-resolution 2H MAS NMR applied to deuterium analogs of hydrido h2-dihydrogencomplexes. Supporting Information.

230.   Hans-Heinrich Limbach,* Peter Tolstoy, Natalia Pérez-Hernández, Jing Guo, Ilya G. Shenderovich, Gleb S. Denisov, Israel J. Chem. 2009, 49, 199 - 216. http://dx.doi.org/10.1560/IJC.49.2.199. OHO Hydrogen Bond Geometries and NMR Chemical Shifts: From Equilibrium Structures to Geometric H/D Isotope Effects with Applications for Water, Protonated Water and Compressed Ice. Supplement: Israel J. Chem. 2009, 49, S1-S36. http://dx.doi.org/10.1560/IJC.49.2.S1

229.   Iker del Rosal, Torsten Gutmann, Laurent Maron, Franck Jolibois, Bruno Chaudret, Bernadeta Walaszek, Hans-Heinrich Limbach, Romuald Poteau*, Gerd Buntkowsky*, Phys. Chem. Chem. Phys. 2009,11, 5657-5663. http://dx.doi.org/10.1039/b822150b. DFT 2H quadrupolar coupling constants of ruthenium complexes: a good probe of the coordination of hydrides in conjuction with experiments.

228a. Peter M. Tolstoy*, Benjamin Koeppe, Gleb S. Denisov, Hans-Heinrich Limbach. Ang. Chem. 2009, 121, 5855–5858. http://dx.doi.org/10.1002/ange.200806181. Kombinierte Flüssigkeits-NMR- und UV/Vis-Spektroskopie: Untersuchung der Struktur starker OHO-Wasserstoffbrücken von Phenolen mit Carbonsäuren.

228b. Peter M. Tolstoy*, Benjamin Koeppe, Gleb S. Denisov, Hans-Heinrich Limbach. Ang. Chem. Int. Ed. 2009, 48, 5745-5747. http://dx.doi.org/10.1002/anie.200806181. Combined NMR/UV-Vis Spectroscopy in theLiquidState: Study of the Geometries of Strong OHO Hydrogen Bonds of Phenols with Carboxylic Acids.

227.   Nikolai S. Golubev, Carsten Detering, Sergei N. Smirnov, Ilja G. Shenderovich, Gleb S. Denisov, Hans-Heinrich Limbach, Peter M. Tolstoy*. Phys. Chem. Chem. Phys. 2009,11, 5154 – 5159.http://dx.doi.org/10.1039/b900152b.H/D isotope effects on NMR chemical shifts of nuclei involved in a hydrogen bridge of hydrogen isocyanide complexes with fluoride anion.

226.   Alexandra Dos, Volkmar Schimming, Monique Chan Huot, Hans-Heinrich Limbach*, J. Am. Chem. Soc. 2009, 131, 7641–7653. http://dx.doi.org/10.1021/ja901082a. Supporting Information. Acid induced Amino Side Chain Interactions and Secondary Structure of Solid Poly-L-Lysine Probed by 15N and 13C Solid State NMR and Ab initio Model Calculations.

225.   Ibon Alkorta,* José Elguero, Hans-Heinrich Limbach, Ilja G. Shenderovich, Tammo Winkler. Mag. Res. Chem. 2009, 47, 585–592.http://dx.doi.org/10.1002/mrc.2433. A DFT and AIM analysis of the spin–spin couplings across the hydrogen bond in the 2-fluorobenzamide and related compounds.

224.   Bernadeta Walaszek, Yeping Xu; Anna Adamczyk; Hergen Breitzke, Katrin Pelzer, Hans-Heinrich Limbach, Jianlin Huang; Hexing Li, Gerd Buntkowsky. Solid State Nuclear Magnetic Resonance, 2009, 35, 164–171 . http://dx.doi.org/10.1016/j.ssnmr.2009.02.006. 2H-Solid-State-NMR Study of Hydrogen adsorbed on catalytically active Ruthenium coated Mesoporous Silica Materials.

223.   Juan Miguel Lopez del Amo, Uwe Langer, Verónica Torres, Mariusz Pietrzak, Gerd Buntkowsky, Hans-Martin Vieth, Mohamed F. Shibl, Oliver Kühn, Martin Broering, Hans-Heinrich Limbach,* J. Phys. Chem. A, 2009, 113, 2193–2206. http://dx.doi.org/10.1021/jp8079414.Isotope and Phase Effects on the Proton Tautomerism in Polycrystalline Porphycene Revealed by NMR.

222.   Ricardo Manríquez, Fernando A. López-Dellamary,Jaroslaw Frydel, Thomas Emmler, Hergen Breitzke, Gerd Buntkowsky, Hans-Heinrich Limbach, Ilja G. Shenderovich*, J. Phys. Chem. B, 2009, 113, 934–940. http://dx.doi.org/10.1021/jp8081968.SolidState NMR Studies of Aminocarboxylic Salt Bridges in L-Lysine Modified Cellulose.

221.   Rafael Fernández, Abdessamad Grirrane, Irene Resa, Amor Rodríguez, Ernesto Carmona,* Eleuterio Álvarez, Enrique Gutiérrez-Puebla, Ángeles Monge, Juan Miguel López del Amo, Hans-Heinrich Limbach, Agustí Lledós, Feliu Maseras, Diego del Río, Chemistry Eur. Journal, 2009, 15, 924-935. http://dx.doi.org/10.1002/chem.200801917. Structural Analysis of Zincocenes with Substituted Cyclopentadienyl Rings.

 

2008

220.   Bernadeta Walaszek, Anna Adamczyk, Tal Pery, Xu Yeping, Torsten Gutmann, Nader Amadeu de Sousa, Stefan Ulrich, Hergen Breitzke, Hans Martin Vieth, Sylviane Sabo-Etienne, Bruno Chaudret, Hans-Heinrich Limbach, Gerd Buntkowsky*, J. Am. Chem. Soc., 2008, 130, 17502–17508. http://dx.doi.org/10.1021/ja806344y. 2H Solid-State NMR of Ruthenium Complexes.

219.   Alexandra Dos, Volkmar Schimming, Sergio Tosoni, Hans-Heinrich Limbach, J. Phys. Chem. B 2008, 112, 15604-15615. http://dx.doi.org/10.1021/jp806551u. Acid-Base Interactions and Secondary Structures of Poly-L-Lysine Probed by 15N and 13C Solid State NMR and Ab initio Model Calculations.

218.   Gerhard Findenegg, Dilek Akcakayiran, Daniel Mauder; Christian Hess, Torsten Sievers, Dirk Kurth, Ilja Shenderovich, Hans-Heinrich Limbach, J. Phys. Chem. B 2008, 112, 14637-14647. http://dx.doi.org/10.1021/jp804712w. Carboxylic acid doped SBA-15 silica as a host for metallo-supramolecular coordination polymers.

217.   Gerd Buntkowsky, Hans-Heinrich Limbach, Bernadeta Walaszek, Anna Adamczyk, Yeping Xu, Hergen Breitzke, A. Schweitzer, Torsten Gutmann, M. Wächtler, Nader Amadeu, D. Tietze, Bruno Chaudret, Z. Phys. Chem. 2008, 222, 1049-1064. http://dx.doi.org/10.1524/zpch.2008.5359. Mechanisms of dipolar ortho/para-H2O conversion in Ice.

216.   Juan Miguel Lopez del Amo, Uwe Langer, Verónica Torres, Gerd Buntkowsky, Hans-Martin Vieth, Marta Pérez-Torralba, Dionísia Sanz, Rosa María Claramunt, José Elguero,Hans-Heinrich Limbach, J. Am. Chem. Soc. 2008, 130, 8620-8632. http://dx.doi.org/10.1021/ja801506n. Supporting Information. NMR Studies of Ultrafast Intramolecular Proton Tautomerism in Crystalline and Amorphous N, N’-Diphenyl-6-aminofulvene-1-aldimine:SolidState, Kinetic Isotope and Tunnel Effects.

215.   Felicitas Schröder, Daniel Esken, Mirza Cokoja, Maurits W. E. van den Berg, Oleg Lebedev, Gustaaf Van Tendeloo, Bernadeta Walaszek, Gerd Buntkowsky, Hans-Heinrich-Limbach, Bruno Chaudret, Roland A. Fischer, J. Am. Chem. Soc. 2008, 130, 6119-6130. http://dx.doi.org/10.1021/ja078231u. Supporting Information. Ruthenium Nanoparticles Inside Porous [Zn4O(bdc)3] by Hydrogenolysis of Adsorbed [Ru(cod)(cot)]: A Solid State Reference System for Surfactant Stabilized Ruthenium Colloids.

214.   Juan Miguel Lopez del Amo, Gerd Buntkowsky, Hans-Heinrich Limbach,* Irene Resa, Rafael Fernández, Ernesto Carmona,, J. Phys. Chem. A. 2008, 112, 3557-3565. http://dx.doi.org/10.1021/jp711504g. Supporting Information. Low-Temperature NMR Studies of Zn Tautomerism and Hindered Rotations in Solid Zincocene Derivatives.

213.   Anna Adamczyk, Yeping Xu, Bernadeta Walaszek, Frank Roelofs, Tal Pery, Karin Pelzer, Karine Philippot, Bruno Chaudret, Hans-Heinrich Limbach, Hergen Breitzke, Gerd Buntkowsky, Topics in Catalysis, 2008, 48, 75–83. http://dx.doi.org/10.1007/s11244-008-9054-7SolidState and Gas Phase NMR Studies of immobilized Catalysts and catalytic active Nanoparticles.

212a. Jordi García-Antón, M. Rosa Axet, Susana Jansat, Karine Philippot, Bruno Chaudret, Tal Pery, Gerd Buntkowsky, Hans-Heinrich Limbach. Ang. Chem. 2008, 120, 2104-2108.Reactions of olefins with novel ruthenium hydride nanoparticles: NMR characterization, hydride titration and room temperature C-C activation.

212b. Jordi García-Antón, M. Rosa Axet, Susana Jansat, Karine Philippot, Bruno Chaudret, Tal Pery, Gerd Buntkowsky, Hans-Heinrich Limbach. Ang. Chem. Int. Ed. 2008, 47, 2074-2078. DOI: 10.1002/anie.200704763. Reactions of olefins with novel ruthenium hydride nanoparticles: NMR characterization, hydride titration and room temperature C-C activation.

211a. Mariusz Pietrzak, Andrew Try, Bruno Andrioletti, Jonathan Sessler, Pavel Anzenbacher, Hans-Heinrich Limbach, Ang. Chem. 2008, 120, 1139 –1142. http://dx.doi.org/10.1002/ange.200704411. The largest 15N...15N coupling constant across an NHN-hydrogen bond. Supporting Information.

211b. Mariusz Pietrzak, Andrew Try, Bruno Andrioletti, Jonathan Sessler, Pavel Anzenbacher, Hans-Heinrich Limbach, Ang. Chem. Int. Ed. 2008, 47, 1123 – 1126. http://dx.doi.org/10.1002/ange.200704411. The largest 15N...15N coupling constant across an NHN-hydrogen bond. Supporting Information.

 

2007

210.   Ilya G. Shenderovich, Daniel Mauder, Dilek Akcakayiran, Gerd Buntkowsky, Hans-Heinrich Limbach, Gerhard H. Findenegg, J. Phys. Chem. B. 2007, 111, 12088-12096. http://dx.doi.org/10.1021/jp073682m. NMR Provides Checklist of Generic Properties for Atomic-Scale Models of Periodic Mesoporous Silicas

209.   Gerd Buntkowsky, Hergen Breitzke, Anna Adamczyk, Frank Roelofs, Thomas Emmler, Egbert Gedat, Bob Grünberg, Yeping Xu, Hans-Heinrich Limbach, Ilja Shenderovich, Anastasia Vyalikh, Gerhard H. Findenegg, Phys. Chem. Chem. Phys., 2007, 9, 4843–4853. http://dx.doi.org/10.1039/b707322d. Invited Article. Structural and dynamical properties of guest molecules confined in mesoporous silica materials revealed by NMR.

208.   Shasad Sharif, Emily Fogle, Michael D. Toney, Gleb S. Denisov, Ilya G. Shenderovich, Peter M. Tolstoy, Monique Chan Huot, Gerd Buntkowsky, Hans-Heinrich Limbach, J. Am. Chem. Soc. 2007,129, 9558-9559. http://dx.doi.org/10.1021/ja0728223. Supporting Information. NMR Localization of Protons in Critical Enzyme Hydrogen Bonds.

207.   Juan Miguel Lopez, Ferdinand Männle, Iwona Wawer, Gerd Buntkowsky, Hans-Heinrich Limbach, Phys. Chem. Chem. Phys. 2007, 9, 4498-4513. http://dx.doi.org/10.1039/b704384h. NMR Studies of Double Proton Transfer in Hydrogen Bonded Cyclic N,N’-Bisarylformamidine Dimers: Conformational Control, Kinetic HH/HD/DD Isotope Effects and Tunneling

206.   Shasad Sharif, Ilja G. Shenderovich, Leticia González, Gleb S. Denisov, David N. Silverman, Hans-Heinrich Limbach, J. Phys. Chem. B2007, 111, 6084-6093. http://dx.doi.org/10.1021/jp071725t. Supporting Information. NMR and Ab initio Studies of Small Complexes Formed between Water and Pyridine Derivatives in Solid and Liquid Phase

205.   Nikolai S. Golubev, Sergei N. Smirnov, Peter M. Tolstoy,* Shasad Sharif, Michael D. Toney, Gleb S. Denisov, Hans Heinrich Limbach, J. Mol. Struct 2007, 844-845,319-327. http://dx.doi.org/10.1016/j.molstruc.2007.04.015. Observation by NMR of the tautomerism of an intramolecular OHOHN-charge relay chain in a model Schiff base.

204.   Mariusz Pietrzak, Claudia Benedict, Holger Gehring, Ewald Daltrozzo, Hans-Heinrich Limbach, J. Mol. Struct 2007, 844-845,222-231. http://dx.doi.org/10.1016/j.molstruc.2007.04.023. NMR Studies and DFT Calculations of the Symmetric Intramolecular NHN-Hydrogen Bond of Bis-(2-Pyridyl)-Acetonitrile: Isotope Labeling Strategy for the Indirect 13C-Detection of 15N15N Couplings.

203.   Shasad Sharif, Gleb S. Denisov, Michael D. Toney, Hans-Heinrich Limbach, J. Am. Chem. Soc. 2007, 129, 6313-6327. http://dx.doi.org/10.1021/ja070296+. Supporting Information. NMR Studies of Coupled Low- and High-Barrier Hydrogen Bonds in Pyridoxal-5’-phosphate Model Systems in Polar Solution.

202.   Andrew Toner, J. Matthes, S. Gründemann, H. H. Limbach, B. Chaudret, Eric Clot, S. Sabo-Etienne. Proc. Nat. Acad. Sci. 2007, 104, 6945-6950. http://dx.doi.org/10.1073/pnas.0608979104. Protonation of Dihydrogen Ortho-Metalated Ruthenium Complexes: Agostic Interactions and Intramolecular Proton Transfer

201.   Shasad Sharif, Monique Chan Huot, Peter M. Tolstoy, Michael D. Toney, K. Hanna M. Jonsson, Hans-Heinrich Limbach, J. Phys. Chem. B 2007, 111, 3869 – 3876. http://dx.doi.org/10.1021/jp067334g.15N NMR Studies of Acid-Base Properties of Pyridoxal 5'-phosphate Aldimines in Aqueous Solution. Supporting information.

200.   Shasad Sharif, David Schagen, Michael D. Toney, Hans-Heinrich Limbach, J. Am. Chem. Soc. 2007,129, 4440-4455.http://dx.doi.org/10.1021/ja066240h. Coupling of Functional Hydrogen Bonds in Pyridoxal-5’-phosphate-Enzyme Model Systems Observed by Solid State NMR Spectroscopy. Supporting Information.

199.   A. Vyalikh, Th. Emmier, B. Grünberg, Y. Xu, I. Shenderovich, Gerhard H. Findenegg, H. H. Limbach, G. Buntkowsky. Z. Phys. Chem. 2007, 221, 155 - 168. http://dx.doi.org/10.1524/zpch.2007.221.l.155. Hydrogen Bonding of Water Conlined in Controlled-Pore Glass 10-75 Studied by 1H-Solid State NMR.

198.   Mohamed F. Shibl, Mariusz Pietrzak, Hans-Heinrich Limbach, and Oliver Kühn, Chem. Phys. Chem. 2007,8. 315 - 321. http://dx.doi.org/10.1002/cphc.200600511. Geometric H/D Isotope Effects and Cooperativity of the Double Hydrogen Bonds in Porphycene.

197.   Mariusz Pietrzak, Mohamed F. Shibl, Martin Bröring, Oliver Kühn, Hans-Heinrich Limbach, J. Am. Chem. Soc. 2007,129. 296-304.http://dx.doi.org/10.1021/ja065170b. 1H/2H NMR Studies of Geometric H/D Isotope Effects on the Coupled Hydrogen Bonds in Porphycene Derivatives

 

2006

196.   D. V. Andreeva, B. Ip, A. Gurinov, P. M. Tolstoy, G. S. Denisov, I. G. Shenderovich, H. H. Limbach, J. Phys. Chem. A 2006,110, 10872-10879. http://dx.doi.org/10.1021/jp0616821. Geometrical features of hydrogen bonded complexes involving sterically hindered pyridines

195.   M. Febles, N. Pérez-Hernández, C. Pérez, M. L. Rodríguez, C. Foces-Foces, M. V. Roux, E. Q. Morales, G. Buntkowsky, H. H. Limbach, J. D. Martín, J. Am. Chem. Soc. 2006, 128, 10008-10009. http://dx.doi.org/10.1021/ja063223j. Distinct Dynamic Behaviors of Water Molecules in Hydrated Pores. Supporting information.

194.   H. H. Limbach, J. M. Lopez, A. Kohen, Phil. Trans. B (London). 2006, 361, 1399–1415. http://dx.doi.org/10.1098/rstb.2006.1872. Arrhenius Curves of Hydrogen Transfers: Tunnel Effects, Isotope Effects and Effects of Pre-Equilibria.

193.   G. Buntkowsky, B. Walaszek, A. Adamczyk, Y. Xu, H. H. Limbach, B. Chaudret, Phys. Chem. Chem.Phys. 2006, 8, 1929-1935. http://dx.doi.org/10.1039/b601594h. Mechanism of Nuclear Spin initiated para-H2/ortho-H2 Conversion. HOT ARTICLE

192.   S. Sharif, D. R. Powell, D. Schagen, T. Steiner, M. D. Toney, E. Fogle, H. H. Limbach, Acta Cryst. 2006, B62, 480 - 487. http://dx.doi.org/10.1107/S0108768105040590. X-Ray Crystallographic Structures of Enamine and Amine Schiff bases of Pyridoxal and its 1:1 Hydrogen Bonded Complexes with Benzoic Acid Derivatives: Evidence for Coupled Inter- and Intramolecular Proton Transfer.

191.   H. H. Limbach, G. Buntkowsky, J. Matthes, S. Gründemann, T. Pery, B. Walaszek, B. Chaudret, Chem. Phys. Chem. 2006, 7, 551-554. http://dx.doi.org/10.1002/cphc.200500559. Novel Insights into the Mechanism of the ortho/para Spin Conversion of Hydrogen Pairs: Implications for Catalysis and Interstellar Water. Supporting information.

190.   S. Sharif, G. S. Denisov, M. D. Toney, H. H. Limbach, J. Am. Chem. Soc. 2006, 128, 3375-3387. http://dx.doi.org/10.1021/ja056251v. NMR Studies of Solvent-assisted Proton Transfer in a Biologically Relevant Schiff base: Towards a Distinction of Geometric and Equilibrium H-Bond Isotope Effects. Supporting information.

 

2005

189.   A. Vyalikh, T. Emmler, E. Gedat, I. Shenderovich, Gerhard H. Findenegg, H. H. Limbach, G. Buntkowsky, Solid State NMR, 2005, 28, 117-124. http://dx.doi.org/10.1016/j.ssnmr.2005.07.001. Evidence of Microphase Separation in Controlled Pore Glasses.

188.   H. H. Limbach, F. Männle, G. S. Denisov, C. Detering, Chem. Phys. 2005, 319, 69-92. http://dx.doi.org/10.1016/j.chemphys.2005.05.021. Base Catalyzed Intramolecular Single vs. Intermolecular Double Proton Transfer: A Dynamic NMR Study of 1,3-Di-(4-fluorphenyl)-triazene.

187.   T. Pery, Katrin Pelzer, G. Buntkowsky, K. Philippot, H. H. Limbach, B. Chaudret, Chem.Phys.Chem. 2005, 6, 605-607. http://dx.doi.org/10.1002/cphc.200400621. Direct NMR Evidence for the Presence of Mobile Surface Hydrides on Ruthenium Nanoparticles. Supporting information.

 

2004

186.   H. Zimmermann, P. Tolstoy, H. H. Limbach, R. Poupko, Z. Luz, J. Phys. Chem. B. 2004, 108, 18772-18778. http://dx.doi.org/10.1021/jp040482r. The Saddle Form of Cyclotriveratrylene

185.   B. Grünberg, T. Emmler, E. Gedat, I. Shenderovich, Gerhard H. Findenegg, H. H. Limbach, G. Buntkowsky, Chemistry Eur. J. 2004, 10, 5689 - 5696. http://dx.doi.org/10.1002/chem.200400351. Hydrogen Bonding of Water confined in mesoporous Silica MCM-41 and SBA-15 studied by 1H-Solid State NMR.

184.   H. H. Limbach, M. Pietrzak, S. Sharif, P. M. Tolstoy, I. G. Shenderovich, S. N. Smirnov, N. S. Golubev, G. S. Denisov, Chemistry Eur. J. 2004, 10, 5195-5204. http://dx.doi.org/10.1002/chem.200400212. NMR-Parameters and Geometries of OHN- and ODN Hydrogen Bonds of Pyridine-Acid Complexes.

183.   O. Klein, F. Aguilar-Parrilla, J. M. Lopez del Amo, N. Jagerovic, J. Elguero, H. H. Limbach, J. Am. Chem. Soc. 2004, 126, 11718-11732. http://dx.doi.org/10.1021/ja0493650. Dynamic NMR Study of the Mechanisms of Double, Triple and Quadruple Proton and Deuteron Transfer in Cyclic Hydrogen Bonded Solids of Pyrazole Derivatives.

182.   H. H. Limbach, M. Pietrzak, H. Benedict, P. M. Tolstoy, N. S. Golubev, G. S. Denisov, J. Mol. Structure,2004, 706, 115-119. http://dx.doi.org/10.1016/j.molstruc.2004.03.006. Empirical Corrections for Quantum Effects in Geometric Hydrogen Bond Correlations.

181.   T. Emmler, S. Gieschler, H. H. Limbach, G. Buntkowsky, J. Mol. Structure,2004, 700, 29-38. Special Issue Horizons in Hydrogen Bond Research, Guest Ed. A.J. Barnes and H. H. Limbach. http://dx.doi.org/10.1016/j.molstruc.2004.01.045. A Simple Method for the Characterization of OHO-Hydrogen-Bonds by 1H-Solid State NMR Spectroscopy. 180.   P. M. Tolstoy, S. N. Smirnov, I. G. Shenderovich, N. S. Golubev, G. S. Denisov, H. H. Limbach, J. Mol. Structure,2004,700, 19-27. http://dx.doi.org/10.1016/j.molstruc.2004.02.023. Special Issue Horizons in Hydrogen Bond Research, Guest Ed. A.J. Barnes and H. H. Limbach. NMR Studies ofSolidState - Solvent and H/D Isotope Effects on Hydrogen Bond Geometries of 1:1 Complexes of Collidine with Carboxylic Acids

179.   N. S.Golubev, P. M.Tolstoy, S. N.Smirnov, G. S.Denisov, H. H. Limbach, J. Mol. Structure,2004, 700, 3-12. http://dx.doi.org/10.1016/j.molstruc.2004.01.024. Special Issue Horizons in Hydrogen Bond Research, Guest Ed. A.J. Barnes and H. H. Limbach, Low-Temperature NMR Spectra of Fluoride - Acetic Acid Hydrogen-Bonded Complexes in Aprotic Polar Environment.

178.   J. Matthes, T. Pery, S. Gründemann, G. Buntkowsky, S. Sabo-Etienne, B. Chaudret, H. H. Limbach, J. Am. Chem. Soc. 2004, 126, 8366-8367. Bridging the Gap between Homogeneous and Heterogeneous Catalysis: ortho/para-H2 Conversion, Hydrogen Isotope Scrambling and Hydrogenation of Olefins by Ir(CO)Cl(PPh3)2

177.   P. M. Tolstoy, P. Schah-Mohammedi, S. N. Smirnov, N. S. Golubev, G. S. Denisov, H. H. Limbach, J. Am. Chem. Soc. 2004, 126, 5621-5634. http://dx.doi.org/10.1021/ja039280j. Characterization of Fluxional Hydrogen Bonded Complexes of Acetic Acid and Acetate by NMR: Geometries, Isotope and Solvent Effects.

176.   J. Matthes, S. Gründemann, A. Toner, Y. Guari, B. Donnadieu, S. Sabo-Etienne, E. Clot, H. H. Limbach, B. Chaudret, Organometallics, 2004, 23; 1424-1433. Orthometallated Hydrido Dihydrogen Ruthenium Complexes: Dynamics, Exchange Couplings and Reactivity.

175.   S. Milosavljević, I. Juranić, V. Bulatović, S. Macura, N. Juranić, H. H. Limbach, K. Weisz, V. Vajs, N. Todorović, Structural Chemistry, 2004, 15, 237-245. Conformational Analysis of Guaianolide-Type Sesquiterpene Lactones by Low-Temperature NMR Spectroscopy and Semiempirical Calculations. (http://www.kluweronline.com/issn/1040-0400)

174.   N. Pérez-Hernandez, C. Pérez, M. L. Rodríguez, C. Foces-Foces, P. M. Tolstoy, H. H. Limbach, E. Q. Morales, Ricardo Pérez and J. D. Martín, Bioorganic & Medicinal Chemistry, 2004, 12, 1305­1314. Water molecules in hydroxy/acid networks as a competition between dynamics and bonding. Synthesis of a wet hydrophobic pore.

173.   E. M. Basílio Janke, H. H. Limbach, K. Weisz, J. Am. Chem. Soc. 2004, 126, 2135-2141. http://dx.doi.org/10.1021/ja038630z. Binding of an Acetic Acid Ligand to Adenosine: A Low Temperature NMR Study.

172.   H. H. Limbach, O. Klein, J. M. Lopez Del Amo, J. Elguero, Z. Phys. Chem., 2004, 217, 17 - 49. http://dx.doi.org/10.1524/zpch.218.1.17.25386. Special issue for Prof. H. W. Zimmermann, Kinetic Hydrogen/Deuterium Isotope Effects in Multiple Proton Transfer Reactions.

 

2003

171.   I. G. Shenderovich, G. Buntkowsky, A. Schreiber, E. Gedat, S. Sharif, Judith Albrecht, Nikolaj S. Golubev, Gerhard H. Findenegg, H. H. Limbach, J. Phys. Chem. B. 2003, 107, 11924-11939. http://dx.doi.org/10.1021/jp0349740. Pyridine-15N - a Mobile NMR Sensor for Surface Acidity and Surface Defects of Mesoporous Silica.

170.   I. G. Shenderovich, P. Tolstoy, N. S. Golubev, S. N. Smirnov, G. S. Denisov, H. H. Limbach, J. Am. Chem. Soc. 2003, 125, 11710 - 11720. http://dx.doi.org/10.1021/ja029183a. Low-Temperature NMR Studies of the Structure and Dynamics of a Novel Series of Acid-Base Complexes of HF with Collidine exhibiting Scalar Couplings across Hydrogen Bonds.

 

2002

169.   A. Bismarck, I. Aranberri-Askargorta, J. Springer, T. Lampke, B. Wielage, A. Stamboulis , I. Shenderovich, H. H. Limbach, Polymer Composites , 2002, 23 (5): 872-894. Surface characterization of flax, hemp and cellulose fibers; Surface properties and the water uptake behavior.

168.   I. G. Shenderovich, H. H. Limbach, S. N. Smirnov, P. M. Tolstoy, G. S. Denisov, N. S. Golubev. Phys. Chem. Chem. Phys. 2002, 4, 5488 - 5497. H/D Isotope Effects on the Low-Temperature NMR Parameters and Hydrogen Bond Geometries of (FH)2F- and (FH)3F- Anions in CDF3/CDF2Cl Liquid Solution.

167.   H. Komber, H. H. Limbach, F. Böhme, C Kunert. J. Am. Chem. Soc. 2002, 124, 119567 - 11963. Symmetric and Asymmetric Tautomers of Cyclo-tris(4-X-2,6-pyridylformamidine)s - NMR Studies in Solution and in theSolidState.

166.   F. Wehrmann, J. Albrecht, E. Gedat, G. J. Kubas, H. H. Limbach, G. Buntkowsky. J. Phys. Chem., A; 2002, 106; 2855-2861. Hydrogen Deuterium Isotope Effect on Exchange Rates in h2 - bond Transition Metal Dihydrogen Complexes revealed by 2H Solid State NMR Spectroscopy.

165.   E. Gedat, A. Schreiber, Gerhard H. Findenegg, H.-H. Limbach, G. Buntkowsky, J. Phys. Chem., B; 2002, 106; 1977-1984. DOI: http://dx.doi.org/10.1021/jp012391p. Evidence for surface and core phases of benzene-d6 confined in mesoporous silica SBA-15 as studied with 2H-NMR.

 

2001

164.   E. M. Basilio Janke, A. Dunger, H. H. Limbach, K. Weisz, Magn. Reson. Chem. 2001, 39, S177-S182. Special Issue NMR Spectroscopy of Hydrogen Bonded Systems. Guest Editor H. H..Limbach. Hydrogen-Bonding in Complexes of Adenosine and 4-Thiouridine: A Low Temperature NMR Study.

163.   E. Gedat, A. Schreiber, Gerhard H. Findenegg, H. H. Limbach, G. Buntkowsky, Magn. Reson. Chem. 2001, 39, S149-S157. Special Issue NMR Spectroscopy of Hydrogen Bonded Systems. Guest Editor H. H..Limbach. Stray Field Gradient NMR reveals Effects of Hydrogen Bonding on Diffusion Constants of Pyridine in Mesoporous Silica.

162.   M. Pietrzak, H. H. Limbach, M. Pérez-Torralba, D. Sanz, R. M. Claramunt, J. Elguero, Magn. Reson. Chem. 2001, 39, S100-S108. Special Issue NMR Spectroscopy of Hydrogen Bonded Systems. Guest Editor H. H..Limbach. Scalar Coupling Constants Across the Intramolecular NHN-Hydrogen Bond of Symmetrically and Non-symmetrically substituted 6-Aminofulvene-1-aldimines.

161.   I. G. Shenderovich, A. P. Burtsev, G. S. Denisov, N. S. Golubev, H. H. Limbach, Magn. Reson. Chem. 2001, 39, S91-S99. Special Issue NMR Spectroscopy of Hydrogen Bonded Systems. Guest Editor H. H. Limbach. Influence of the temperature-dependent dielectric constant on the H/D isotope effects on the NMR chemical shifts and the hydrogen bond geometry of the collidine-HF complex in CDF3/CDClF2 solution.

160.   M. Rospenk, L. Sobczyk, P. Schah-Mohammedi, H. H. Limbach, N. S. Golubev, S. M. Melikova, Magn. Reson. Chem. 2001, 39, S81-S90. Special Issue NMR Spectroscopy of Hydrogen Bonded Systems. Guest Editor H. H..Limbach. Dimerization and Solvent Assisted Proton Dislocation in the Low-Barrier Hydrogen Bond of a Mannich Base. A Low-Temperature NMR Study.

159.   P. Lorente, I. G. Shenderovich, G. Buntkowsky, N. S. Golubev, G. S. Denisov, H. H. Limbach, Magn. Reson. Chem. 2001, 39, S18-S29. http://dx.doi.org/10.1002/mrc.946. Special Issue NMR Spectroscopy of Hydrogen Bonded Systems. Guest Editor H. H. Limbach. 1H/15N NMR chemical shielding, dipolar 15N,2H coupling and hydrogen bond geometry correlations in a novel series of hydrogen bonded acid-base complexes of collidine with carboxylic acids.

158r. C. Detering, P. M. Tolstoy, N. S. Golubev, H. H. Limbach, G. S. Denisov, Doklady Akademic Nauk, 2001, 379, 1-4.

158e. Doklady Phys.Chem. (Engl.Transl), 2001, 379, 191-193.Vicinal H/D Isotope Effects in NMR Spectra of Complexes with Coupled Hydrogen Bonds. Phosphoric acids.

157.   C. Foces-Foces, Aurea Echevarría, N. Jagerovic, Ibon Alkorta, Jose Elguero, Uwe Langer, O. Klein, Maria Minguet-Bonvehí, H. H. Limbach. J. Am. Chem. Soc. 2001, 123, 7898-7906. A Solid State NMR, X-Ray Diffraction and Ab initio Computational Study of Hydrogen Bond Structure and Dynamics of Pyrazole-4-Carboxylic Acid Chains.

156.   V. P. Bulychev, G. S.Denisov, H. H. Limbach, R. M. Shukailov, Optics and Spectroscopy, 2001, 90, 356-361. Translated from Optika i Spektroskopiya, 2001, 90, 412-418. Calculation of Vibrations of the H-bonds and Electrooptical Parameters of the [F(HF)2]- Complex.

155.   N. V. Belkova, A. V. Ionidis, L. M. Epstein, E. S. Shubina, S. Gruendemann, N. S. Golubev, H. H. Limbach, Eur. J. Inorg. Chem. 2001, 1753-1761. Proton transfer to CpRuH(CO)(PCy3) studied by low temperature IR and NMR Spectroscopy.

154.   M. Pietrzak, J. Wehling, H. H. Limbach, N. S. Golubev, C. López, R. M. Claramunt, J. Elguero, J. Am. Chem. Soc. 2001, 123, 4338-4339. 13C detected Scalar Nitrogen - Nitrogen Couplings across the Intramolecular Symmetric NHN-Hydrogen Bond of Proton Sponge.

153.   U. Langer, L. Latanowicz, C. Hoelger, G. Buntkowsky, H. M. Vieth, H. H. Limbach. Phys. Chem. Chem. Phys. 2001, 3, 1446-1458. http://dx.doi.org/10.1039/B007564g. 15N and 2H NMR Relaxation and Kinetics of Stepwise Double Proton and Deuteron Transfer in Polycrystalline Tetraaza[14]annulene.

152.   R. M. Claramunt, D. Sanz, S. H. Alarcón, M. Pérez-Torralba, J. Elguero, C. Foces-Foces, M. Pietrzak, U. Langer, H. H. Limbach. Ang. Chem. 2001, 113, 434-437. Ang. Chem. Int. Ed. 2001, 40, 420-423. 6-Aminofulvene-1-aldimine: a Model Molecule for the Study of Intramolecular Hydrogen Bonds.

151.   S. Sabo-Etienne, V. Rodriguez, B. Donnadieu, B. Chaudret, H. Abou el Makarim, J. C. Barthelat, S. Ulrich, H. H. Limbach, C. Moïse. New J. Chem. 2001, 25, 55-62. Synthesis, X-ray crystal structure, NMR characterization, Theoretical Calculations on [Cp2Ta(h2-H2)(CO)]+, the First Thermally Stable Group 5 Dihydrogen Complex.

2000

150.   P. Schah-Mohammedi, I. G. Shenderovich, C. Detering,H. H. Limbach, P. M. Tolstoy, S. N. Smirnov, G. S. Denisov, N. S. Golubev. J. Am. Chem. Soc., 2000, 122, 12878-12879. http://dx.doi.org/10.1021/ja0017615. Hydrogen/Deuterium-Isotope Effects on NMR Chemical Shifts and Symmetry of Homoconjugated Hydrogen Bonded Ions in Polar Solution.

149.   A. Dunger, H. H. Limbach, K. Weisz. . J. Am. Chem. Soc. 2000; 122, 10109-10114. http://dx.doi.org/10.1021/ja000718e. Geometry and Strength of Hydrogen Bonds in Complexes of 2'-Deoxyadenosine with 2'-Deoxyuridine.

148.   A. J. Toner, S. Gründemann, E. Clot, H. H. Limbach, B. Donnadieu, S. Sabo-Etienne, B. Chaudret. J. Am. Chem. Soc. 2000; 122, 6777-6778. Ruthenium assisted reversibly Proton Transfer from an Aromatic Carbon to a Hydride.

147.   S. Macholl, I. Sack, H. H. Limbach, J. Pauli, M. Kelly, G. Buntkowsky. Magn. Reson. Chem. 2000, 38, 596–603. Solid state NMR study of the SH3 domain of a–spectrin – application of 13C-15N TEDOR and REDOR.

146.   M. Angeles García, C. López, O. Peters,R. M. Claramunt, O. Klein, D. Schagen, H. H. Limbach, C. Foces-Foces, J. Elguero, Magn. Reson. Chem. 2000, 38, 604–614. Solid state behaviour of 3,5-dibromo-1H-1,2,4-triazole and 3,5-dichloro-1H-1,2,4-triazole

145.   S. H. Alarcón, J. A. Jiménez, R. M. Claramunt, J. Elguero, Magn. Res. Chem. 2000, 39, 305-310. Combined Variable Temperature and Variable Field 15N MAS NMR Study of (15N- 14N) Residual Dipolar Coupling in Pyrazole Derivatives.

144.   K. B. Schowen, H. H. Limbach, G. S. Denisov, R. L. Schowen, Biochemica Biophysica Acta, 2000, 1458, 43-62. Hydrogen Bonds and Proton Transfer in General-Catalytic Transition-State Stabilization in Enzyme Catalysis. Special thematic issue on Proton-Transfer Reactions in Bioenergetics, Edited by P. Brzezinski.

143.   H. Benedict, I. G. Shenderovich, O. L. Malkina, V. G. Malkin, G. S. Denisov, N. S. Golubev, H. H. Limbach. J. Am. Chem. Soc., 2000, 122, 1979-1988. Nuclear Scalar Spin-Spin Couplings and Geometries of Hydrogen Bonds.

142.   I. Sack, S. Macholl, F. Wehrmann, J. Albrecht, H. H. Limbach, F. Fillaux, M. H. Baron, G. Buntkowsky, Appl. Magn. Reson. 2000, 17, 413-431. A 15N-1H Dipolar CSA Solid State NMR Study of Polyglycine(-CO-CD2-15NH-)nModifications.

141.   U. Langer, Ch. Hoelger, B. Wehrle, L. Latanowicz, E. Vogel, H. H. Limbach, J. Phys. Org. Chem., 2000, 13, 23-34. A 15N NMR Study of Proton Localization and Proton Transfer Thermodynamics and Kinetics in Polycrystalline Porphycene.

1999

140.   O. Klein, M. M. Bonvehi, F. Aguilar-Parrilla, J. Elguero, H. H. Limbach. Israel Journal of Chemistry, 1999, 34, 291-299. Evidence for Hydrogen Bond Compression during Triple Proton Transfer in Crystalline Pyrazoles. A Dynamic 15N NMR Study.

139.   I. Alkorta,J. Elguero, B. Donnadieu, M. Etienne, J. Jaffart, D. Schagen, H. H. Limbach, New J. Chem., 1999, 23, 1231-1237. The structure of 3,5-bis(trifluoromethyl)pyrazole in the gas phase and in the solid state.

138.   J. A. Jiménez, R. M. Claramunt, O. Mó,, F. Wehrmann, G. Buntkowsky, H. H. Limbach, R. Goddard, J. Elguero., Phys. Chem. Chem. Phys., 1999, 1, 5113 - 5120. The Structure of 1-Aminopyrazole in theSolidState and in Solution: An Experimental and Computational Study.

137.   F. Wehrmann, T. P. Fong, R. H. Morris, H. H. Limbach, G. Buntkowsky, Phys. Chem. Chem. Phys., 1999, 1, 4033 - 4041. Coherent D2 Rotational Tunneling and Incoherent D2 Dynamics in a Solid Non-classical RuD2 Complex studied by 2H Solid State NMR Spectroscopy.

136.   S. N. Smirnov, H. Benedict, N. S. Golubev, G. S. Denisov, M. M. Kreevoy, R. L. Schowen, H. H. Limbach, Can J. Chem., 1999, 77, 943 - 949. Exploring Zero-point Energies and Hydrogen Bond Geometries along Proton Transfer Pathways by Low-temperature NMR.

135.   S. Gründemann, S. Ulrich, H. H. Limbach,N. S. Golubev, G. S. Denisov, L. M. Epstein, S. Sabo-Etienne, B. Chaudret, Inorg.Chem.1999, 38, 2550-2551. Solvent-assisted Reversible Proton Transfer within an Intermolecular Dihydrogen Bond and Characterization of an Unstable Dihydrogen Complex.

134.   S. Gründemann, H. H. Limbach, G. Buntkowsky, S. Sabo-Etienne, B. Chaudret, J. Phys. Chem. A., 1999, 103, 4752-4754.Distance and Scalar HD-Coupling Correlations in Transition Metal Dihydrides - Dihydrogen Complexes

133.   V. Schimming, Ch. G. Hoelger, G. Buntkowsky, I. Sack, J. H. Fuhrhop, S. Rocchetti, H. H. Limbach, J. Am. Chem. Soc., 1999, 121; 4892-4893. Evidence by 15N CPMAS and 15N-13C REDOR NMR for reversible binding of atmospheric CO2 to amino groups in the solid state.

132.   C. Foces-Foces, C. A. L. Llamas-Saiz, P. Lorente, N. S. Golubev, H. H. Limbach, Acta Cryst. 1999, C55, 377 - 381. http://dx.doi.org/10.1107/S0108270198013766. Three 2,4,6-Trimethylpyridine-benzoic acid complexes at 150K.

131.   N. S. Golubev, I. G. Shenderovich, S. N. Smirnov, G. S. Denisov, H. H. Limbach, Chemistry- A European Journal, 1999, 5, 492-497. http://dx.doi.org/10.1002/(SICI)1521-3765(19990201)5:2<492::AID-CHEM492>3.0.CO;2-I. Nuclear Scalar Spin-Spin Coupling Reveals Novel Properties of Low-Barrier Hydrogen-Bonds in a Polar Environment.

1998

130.   H. Quast, M. Heubes, A. Dunger, H. H. Limbach, J. Magn. Res. A., 1998, 134, 236-244. A High-precision Carbon-13 Shift Thermometer for the Temperature range of 100-300 K.

129.   S. Takeda, T. Inabe, C. Benedict, U. Langer, H. H. Limbach, Ber. Bunsenges. Phys. Chem. 1998, 102, 1358–1369. Proton Dynamics in Interacting Hydrogen Bonds in the Solid State: Proton Tunneling in the NHO hydrogen bonds of N,N’-di(2-hydroxy-1-naphthylmethylene)-p-phenylenediamine

128.   V. Rodriguez, S. Sabo-Etienne, B. Chaudret, J. Thoburn, S. Ulrich, H. H. Limbach, J. Eckert, J. C. Barthelat, K. Hussein, C. J. Marsden, Fluxionality and Isomerism of the bis(Dihydrogen) Complex RuH2(H2)2(Pcy3)2; INS, NMR and Theoretical Studies. Inorg. Chem. 1998, 37, 3475-3485.

127.   A. Dunger, H. H. Limbach, K. Weisz, Chemistry Eur. J., 1998, 4, 621 - 628. NMR Studies on the Self-Association of Uridine and Uridine Analogues

126.   I. Shenderovich, S. Smirnov, G. S. Denisov, V. Gindin, N. S. Golubev, A. Dunger, R. Reibke, S. Kirpekar, O. L. Malkina, H. H. Limbach, Ber. Bunsenges. Phys. Chem. 1998, 102, 422 - 428. http://dx.doi.org/10.1002/bbpc.19981020322. Nuclear Magnetic Resonance of Hydrogen Bonded Clusters between F- and (HF)n: Experiment and Theory.

125.   S. Gründemann, H. H. Limbach, V. Rodriguez, B. Donnadieu, S. Sabo-Etienne, B. Chaudret, Ber. Bunsenges. Phys. Chem. 1998, 102, 344 - 353. Coherent and Incoherent Dihydrogen Dynamics in a Ruthenium Trihydride Complex with the Tris(pyrollyl)phosphine Ligand.

124.   C. Benedict, U. Langer, H. H. Limbach, H. Ogata, S. Takeda, Ber. Bunsenges. Phys. Chem. 1998, 102, 335 - 339. Observation of Thermal Tautomerism of Thermochromic Salicylideneaniline Derivatives in the Solid State by Ultra Low Temperature 15N-CP/MAS NMR

123.   C. López, P. Lorente, R. M. Claramunt, J. Marín, C. Foces-Foces, A. L. Llamas-Saiz, J. Elguero, H. H. Limbach, Ber. Bunsenges. Phys. Chem. 1998, 102, 414 - 418. http://dx.doi.org/10.1002/bbpc.19981020320. Localization of Hydrogen Bond Deuterons in Proton Sponges by Dipolar Solid State 15N NMR Spectroscopy. Special Issue on Hydrogen Transfer: Experiment and Theory.

122.   O. Brackhagen, Ch. Scheurer, R. Meyer, H. H. Limbach, Ber. Bunsenges. Phys. Chem. 1998, 102, 303 - 316. Hydrogen Transfer in the porphin anion: A quantum dynamical study of vibrational effects. Special Issue on Hydrogen Transfer: Experiment and Theory.

121.   H. H. Limbach,S. Ulrich, G. Buntkowsky, S. Gründemann, S. Sabo-Etienne, B. Chaudret, G. J. Kubas, J. Eckert, J. Am. Chem. Soc. 1998, 120, 7929-7943. NMR and INS Line Shapes of Transition Metal Hydrides in the Presence of Coherent and Incoherent Dihydrogen Exchange.

120.   H. Benedict, H. H. Limbach, M. Wehlan, W. P. Fehlhammer, N. S. Golubev, R. Janoschek, J. Am. Chem. Soc. 1998, 120, 2939-2950. Solid State 15N NMR and Theoretical Studies of Primary and Secondary Geometric H/D Isotope Effects on Low-Barrier NHN-Hydrogen Bonds.

 

1997

119.   G. Buntkowsky, I. Sack, H. H. Limbach, B. Kling, J. Fuhrhop, J. Phys. Chem. B. 1997, 101, 11265-11272. Structure Elucidation of Amide Bonds with Dipolar Chemical Shift NMR Spectroscopy

118.   R. Anulewicz, I. Wawer, T. M. Krygowski, F. Männle and H.-H. Limbach, J. Am. Chem. Soc. 1997, 119, 12223-12230. A combined X-ray Diffraction and 15N CPMAS NMR Study of Molecular Structure induced Proton Order and Disorder in Cyclic N,N’Bisarylformamidine Dimers. Supplementary Information

117.   N. S. Golubev, S. N. Smirnov, P.Schah-Mohammedi, I. Shenderovich, G. S. Denisov, V. Gindin, H. H. Limbach, Russ. J. Gen.Chem. 1997, 67, 1082-1087. Study of Acid-Base Interaction by Means of Low-Temperature NMR Spectra. Structure of Salicilic Acid Complexes.

116.   M. Edgar, M. Schubert, H. H. Limbach, C.G.Göltner, Ber. Bunsenges. Phys. Chem. 1997, 101, 1769-1772. http://dx.doi.org/10.1002/bbpc.19971011147. NMR Investigations of Nanostructured Ceramics.

115.   M. Ramos, I. Alkorta, J. Elguero, N. S. Golubev, G. S. Denisov, H. Benedict, H. H. Limbach J. Phys. Chem. , 1997, A101, 9791-9800. http://dx.doi.org/10.1021/jp972586q. Theoretical Study of the Influence of Electric Fields on Hydrogen-Bonded Acid-Base Complexes.

114.   B. Manzano, F. Jalon, J. Matthes, S.Sabo-Etienne, B.Chaudret, S. Ulrich, H. H. Limbach, J. Chem. Soc. Dalton Trans, 1997, 3153-3159. Exchange Couplings and hydrogen dynamics in ruthenium trihydride adducts with coinage-metal cations.

113.   J. Ayllon, S. Sabo-Etienne, B. Chaudret, S. Ulrich, H. H. Limbach. Inorganica Chimica Acta, 1997, 259, 1-4. Modulation of quantum mechanical exchange couplings in transition metal hydrides through hydrogen bonding.

112.   G. Buntkowsky, H. H. Limbach, F. Wehrmann, I. Sack, H. M. Vieth, R. H. Morris, J. Phys. Chem. A. 1997, 101, 4679-4689. 2HNMR Theory of Transition Metal Dihydrides: Coherent and Incoherent Quantum Dynamics.

111.   K. Weisz, J. Jähnchen, H. H. Limbach, J. Am. Chem. Soc. 1997, 119, 6436-6437. Low Temperature NMR Studies on the Structure of Uridine Dimers.

110.   F. Aguilar-Parrilla, O. Klein, J. Elguero, H. H. Limbach, Ber. Bunsenges. Phys. Chem. 1997, 101, 889 - 901. A Dynamic 15N NMR Study of Kinetic Hydrogen/ Deuterium Isotope and Tunnel Effects on the Triple Proton Transfer in Crystalline 3,5-Dimethylpyrazole.

109.   R. M. Claramunt, M. D. Santa Maria, I. Forfar, F. Aguilar-Parrilla, M. Minguet-Bonvehi, O. Klein, H. H. Limbach, C. Foces-Foces, A. L. Llamas-Saiz, J. Elguero, J. Chem. Soc., Perkin Trans. 2, 1997, 1867-1875. Molecular structure and dynamics of C-1-adamantyl substituted N-unsubstitute pyrazoles studied by solid state NMR spectroscopy and X-ray crystallography.

108.   J. L. G. de Paz, J. Elguero, C. Foces-Foces, A. L. Llamas-Saiz, F. Aguilar-Parrilla, O. Klein, H. H. Limbach, J. Chem. Soc. Perkin 2, 1997, 101-109. Theoretical Study of the Structure and Tautomerism of NH-Pyrazoles in theSolidState.

 

1996

107.   J. Bodurka, G. Buntkowsky, R. Olechnowicz, A. Gutsze, H. H. Limbach. Coll. Surf, A., 1996, 115, 55-62. Investigations of water in normal and dehydrated rabbit lenses with 1H NMR and calorimetric measurements.

106.   J. Bodurka, G. Buntkowsky, A. Gutsze, H. H. Limbach, Applied Spectroscopy, 1996, 50, 1421-1427. Analysis of the 1H NMR line shape found in animal lenses.

105.   A. Antinolo, F. Carillo, B. Chaudret, M. Fajardo J. Fernande-Baeza, M. Lanfranchi, H. H. Limbach, M. Maurer, A. Otero, M. A. Pellinghelli. Inorg. Chem.1996, 35, 7873-7881. Exchange couplings in niobiocene trihydrides, Nb(C5H3RR’)2H3 and their adducts with copper triad cations {[Nb(C5H3RR’)2H3]2M}+ (R=R’=H; R=H. R’=SiMe3, R=R’=SiMe3).

104.   J. Braun,R. Schwesinger,P. G. Williams,H. Morimoto, D. E. Wemmer, H. H. Limbach, J. Am. Chem. Soc., 1996, 118, 11101-11110. Kinetic H/D/T Isotope andSolidState Effects on the Tautomerism of the Conjugated Porphyrin Monoanion.

103.   J. D. Thoburn, W. Lüttke, C. Iber, H. H. Limbach, J. Am. Chem. Soc., 1996,118, 12459-12460. Indigodiimine: A Highly Fluxional Molecule that Tautomerizes via Double Proton Transfers.

102.   N. S. Golubev, G. S. Denisov, S. N. Smirnov, D. N. Shchepkin, H. H. Limbach, Z. f. Phys. Chem., 1996, 196, 73-84, Sonderheft für Prof. H. Baumgärtel. Evidence by NMR of Temperature-dependent Solvent Electric Field Effects on Proton Transfer and Hydrogen Bond Geometries.

101.   G. Buntkowsky, J. Bargon, H. H. Limbach, J. Am. Chem. Soc., 1996, 118, 8677-8683. A Dynamic Model of Reaction Pathway Effects on Para-Hydrogen Induced Nuclear Spin Polarization.

100.   F. Männle, I. Wawer, H. H. Limbach. Chem. Phys. Letters, 1996, 256, 657-662. Observation and Characterization by 15N CPMAS NMR of a Double Proton Transfer in Cyclic Dimers of 15N,15N,-Di-(4-bromophenyl)-formamidine in the Solid State.

99.     J. Braun, H. H. Limbach, P. Williams, H. Morimoto, D. Wemmer, J. Am. Chem. Soc., 1996, 118, 7231-7232. Observation of Kinetic Tritium Isotope Effects by Dynamic NMR. Example: The Tautomerism of Porphyrin.

98.     C. Lopez, R.M. Claramunt, A. Llamas-Saiz, C. Foces-Foces, J. Elguero, I. Sobrados, F. Aguilar-Parrilla, H. H. Limbach, New J. Chem., 1996, 20, 523-536. X-ray diffraction and solid state NMR studies of 1,8-bis(dimethylamino)naphtalene and its complexes with picric and hexafluorophosphoric acids.

97.     J. Bodurka, G. Buntkowsky, A. Gutsze, H. H. Limbach, Z. f. Naturforschung, 1996, 51c, 81-90. Evidence of Surface Diffusion of Water Molecules on Proteins in the Rabbit Lenses from 1H-NMR Measurements.

96.     H. Benedict, C. Hoelger, F. Aguilar-Parrilla, W. P. Fehlhammer, M. Wehlan, R. Janoschek, H. H. Limbach, J. Mol. Struct., 1996, 378, 11-16 (Special Issue Isotope Effects). Hydrogen/Deuterium Isotope Effects on 15N NMR Chemical Shifts and Geometries of Low-Barrier Hydrogen Bonds in theSolidState.

95.     C. G. Hoelger, H. H. Limbach, F. Aguilar-Parrilla, J. Elguéro, O. Weintraub, S. Vega, J. Magn. Res., 1996,A120, 46 - 55. 15N Chemical Shift Tensors and Hydrogen Bond Geometries of 3,5-Substituted Pyrazoles and Their Orientation in the Molecular Frame.

94.     S. N. Smirnov, N. S. Golubev, G. S. Denisov, H. Benedict, P. Schah-Mohammedi, H. H. Limbach, J. Am. Chem. Soc., 1996, 118, 4094 - 4101.Hydrogen/Deuterium Isotope Effects on the NMR Chemical Shifts and Geometries of Intermolecular Low-Barrier Hydrogen Bonded Complexes.

93.     C. Foces-Foces, L. Infantes, J. Elguero, F. Aguilar-Parrilla, N. S. Golubev, H. H. Limbach, J. Chem. Soc. Perkin Trans 2, 1996, 349 - 353. MixedCrystals of Pyrazoles and Benzoic Acids. 1. The Molecular Structure of 3,5-Dimethylpyrazole/2,4,6-Trimethylbenzoic Acid Co-crystals.

92.     F. Männle, H. H. Limbach, Ang. Chem., 1996,108, 477-479; Ang. Chem. Int. Ed. , 1996,35, 441-442. Observation of an intramolecular base-catalyzed proton transfer in 1,3-Di-(4-fluorphenyl)-triazene.

1995

91.     J. Bodurka, A. Gutsze, G. Buntkowsky, H. H. Limbach, Z. f. Phys. Chem. 1995, 190, 99 - 109. Evidence of Anisotropic Reorientations of Water Molecules in the Cortex of the Rabbit Eye Lens Detected by 1H-NMR-Spectroscopy.

90.     A. Gutsze, J. Bodurka, R. Olechnowicz, G. Buntkowsky, H. H. Limbach, Z. f. Naturforschung, 1995, 50c, 410 - 418. 1H NMR and Calorimetric Measurements on Rabbit Eye Lenses.

89.     S. Sabo-Etienne, B. Chaudret, H. A. El Makarim, J. C. Barthelat, J. P. Daudey, S. Ulrich, H. H. Limbach, C. Moise, J. Am. Chem. Soc. 1995,117, 11602-11604. Upon the chemical origin of exchange couplings in d2 systems.

88.     C. G. Hoelger, E. Rössler, B. Wehrle, F. Aguilar-Parrilla and H. H. Limbach, J. Phys. Chem., 1995,99, 14271 - 14276. http://dx.doi.org/10.1021/j100039a013. Self-decoupling of 15N-14N Dipole-Quadrupole Couplings in 15N CPMAS NMR Spectra and Molecular Motions in Crystalline Hydrazine Sulfate, p-Diethylaminobenzaldehyde, Diphenylhydrazone and its Solid Solution in Polycarbonate.

87.     J. Elguero, N. Jagerovic, C. Foces-Foces, F. H. Cano, M. V. Roux, F. Aguilar-Parrilla, H. H. Limbach, J. Heterocyclic Chem., 1995,32, 451-456. Solid State Structure of NH-Pyrazoles not easily Amenable to Crystal Structure Determinations: The Case of 3(5)-Phenyl-5(3)-methylpyrazole and 3,5-Diphenyl-4-methylpyrazole.

86.     W. Hoffmann, H. Breitzke, C. T. Simmons, K. Lüders, G. Buntkowsky, H. H. Limbach, E. V. Antipov, A. A. Gippius, O. Loebich, H. R. Khan, M. Paranthaman, J. R. Thompson, Appl. Magn. Reson., 1995,8, 57-65. 199Hg and 63,65Cu NMR Studies of Mercury Based High-TC Superconductors.

85.     F. Aguilar-Parrilla, H. H. Limbach, C. Foces-Foces, F. H. Cano, N. Jagerovic, J. Elguero, J. Org. Chem., 1995,60, 1965-1970. Structure and Dynamics of 3,5-Di-tert-butylpyrazole Probed by Combined X-Ray Crystallography and 15N Solid State NMR.

84.     W. Kozminski, F. Aguilar-Parrilla, I. Wawer, H. H. Limbach, L. Stefaniak. Solid State Magn. Res., 1995,4, 121-124. 15N and 13C solid-state nuclear magnetic resonance study of 5-thiomethyltetrazole .

1994

83.     G. Scherer, H. H. Limbach. Croat. Chem. Acta, 1994,67, 431-440. Sonderheft zu Ehren von Prof. T. Skerlak, auf Einladung Proton and Heavy Atom Motions during the Stepwise Proton Tautomerism of Various. Oxalamidines, A semiempirical PM3-MNDO Study.

82.     A. L. Lamas-Saiz, C. Foces-Foces, F. H. Cano, P. Jimenez, J. Laynez, W. Meutermans, J. Elguero, H. H. Limbach, F. Aguilar-Parrilla, Acta Cryst., 1994,B50, 746-762. The Influence of the Nitro Group on the Solid State Structure of 4-Nitropyrazoles: the Cases of Pyrazole, 3,5-Dimethylpyrazole, 3,5-Di-tert-butylpyrazole and 3,5-Diphenylpyrazole.PartI. Static Aspects (Crystallograpbhy and Thermodynamics).

81.     A. Antinolo, F. Carrillo, B. Chaudret, M. Fajardo, J. Fernandez-Baeza, M. Lanfranchi, H. H. Limbach, M. Maurer, A. Otero, M. A. Pellinghelli. Inorg. Chem., 1994,33, 5163-5164. Synthesis, Spectroscopic Properties, X-rax Crystal Structure of {[Nb(C5H3[SiMe3]2)2H3]2 Au}+, a Complex Showing Large Quantum Mechanical Exchange Couplings.

80.     F. Aguilar-Parrilla, F. Männle, H. H. Limbach, J. Elguero, N. Jagerovic. Magn. Reson. Chem., 1994,32, 699-702. 15N NMR Chemical Shifts of NH-Pyrazoles in theSolidState and in Solution at Low Temperature.

79.     N. S. Golubev, G. S. Denisov, V. A. Gindin, S. S. Ligay, H. H. Limbach, S. N. Smirnow, J. Mol. Struct., 1994,322, 83-91. The role of short hydrogen bonds in mechanisms of enzymatic action.

78.     H. C. Dorn, C. S. Yannoni, H. H. Limbach, E. Vogel, J. Phys. Chem., 1994,98, 11628-11629. Evidence for a Non-classical Structure of a 1,6-Methano[10]annulene: A Cryogenic 13C CPMAS NMR Study of the 11,11-Dimethyl Derivative.

77.     N. S. Golubev, S. N. Smirnov, V. A. Gindin, G. S. Denisov, H. Benedict, H. H. Limbach, J. Am. Chem. Soc., 1994,116, 12055-12056. Formation of Charge Relay Chains between Acetic Acid and Pyridine observed by Low Temperature NMR.

76.     W. Hoffmann, H. Breitzke, M. Baenitz, M. Heinze, K. Lüders, G. Buntkowsky, H. H. Limbach, E. V. Antipov, A. A. Gippius, O. Loebich, H. R. Khan, M. Paranthaman, J. R. Thompson. Physica, 1994,C227, 225-229. Application of 199Hg solid-state NMR to Hg-based HTSC.

75.     J. Braun, C. Hasenfratz, R. Schwesinger, H. H. Limbach, Ang. Chem., 1994,106, 2302-2304; Ang. Chem. Int. Ed. , 1994,33, 2215-2217. Free Acid Porphyrin and its Conjugated Monoanion.

74.     C. G. Hoelger, H. H. Limbach, J. Phys. Chem., 1994,98, 11803-11810. http://dx.doi.org/10.1021/j100096a028. Localization of Hydrons in Hydrogen Bonds using Dipolar Solid State NMR Spectroscopy.

73.     J. Braun, M. Schlabach, B. Wehrle, M. Köcher, E. Vogel, H. H. Limbach, J. Am. Chem. Soc., 1994,116, 6593 - 6604. NMR Study of the Tautomerism of Porphyrin Including the Kinetic HH/HD/DD Isotope Effects in the Liquid and theSolidState.

72.     J. Elguero, F. H. Cano, C. Foces-Foces, A. L. Llamas-Saiz, H. H. Limbach, F. Aguilar-Parrilla, R. M. Claramunt, C. Lopez, J. Heterocycl. Chem., 1994,31, 695-700. Proton Transfer in Solid Heterocycles: an X-Ray and CPMAS NMR Study.

71.     O. Weintraub, S. Vega, Ch. Hoelger, H. H. Limbach, J. Magn. Reson., 1994,A110, 12-18. Coherence Transfer in dipolar coupled homonuclear spin systems in solids rotating at the magic angle .

70.     O. Weintraub, S. Vega, Ch. Hoelger, H. H. Limbach, J. Magn. Reson., 1994,A109, 14-25. Distance measurements between homonuclear spins in rotating solids.

69.     F. Aguilar-Parrilla, R. M. Claramunt, C. Lopez, D. Sanz, H. H. Limbach, J. Elguero, J. Phys. Chem., 1994,98, 8752-8760. High Resolution Solid State 13C and 15N NMR Spectroscopy of Pyrazole and 3,5-Dimethylpyrazole Adsorbed on Alumina and Silica.

68.     D. Carmona, J. Ferrer, M. P. Lamata, L. A. Oro, H. H. Limbach, G. Scherer, J. Elguero, M. L. Jimeno, J. Organometallic Chem., 1994,470, 272-274. Determination of the free activation energy for the breaking of the 31P-107(109)Ag bond in [(h6-p-cymene)Ru(m-pz)3Ag(PPH3)].

67.     A. L. Llamas-Saiz, C. Foces-Foces, J. Elguero, F. Aguilar-Parrilla, H. H. Limbach, P. Molina, M. Alajarin, A. Vidal, R. M. Claramunt, C. Lopez, J. Chem. Soc. Perkin 2, 1994, 209-212. Iminophosphorane-substituted Proton Sponges. Part 5: Structures in the Solid State. Correlation between Solid State 31P MAS NMR Spectra andCrystal Structures. Supplementary Material

66.     G. Scherer, H. H. Limbach, J. Am. Chem. Soc., 1994,116, 1230-1239. Dynamic NMR Study of the Tautomerism of Bicyclic Oxalamidines: Kinetic HH/HD/DD Isotope and Solvent Effects.

65.     C. G. Hoelger, B. Wehrle, H. Benedict, H. H. Limbach, J. Phys. Chem., 1994,98, 843 - 851. http://dx.doi.org/10.1021/j100054a020. High-Resolution Solid-State NMR Relaxometry as a Kinetic Tool for the Study of Ultrafast Proton Transfers in Crystalline Powders. Example: Dimethyldibenzotetraaza[14]annulene.

1993

64.     F. Toda, K. Tanaka, C. Foces-Foces, A. L. Llamas-Saiz, H. H. Limbach, F. Aguilar-Parrilla, R. M. Claramunt, C. Lopez, J. Elguero, J. Chem. Soc. Chem. Comm. 1993,1139 - 1142. Intermolecular Proton Transfer in Host-Guest Crystals: the Case of Pyrazole Included in 1,1-Di(2,4-dimethylphenyl)but-2-yn-1-ol, an X-Ray and Solid State 13C/15N NMR Study.

63.     M. Schlabach, H. H. Limbach, E. Bunnenberg, A. Shu, B. R. Tolf and C. Djerassi, J. Am. Chem. Soc., 1993,115, 4554-4565. NMR Study of Kinetic HH/HD/DH/DD Isotope Effects on the Acetylporphyrin. Evidence for a Stepwise Double Proton Transfer.

1992

62.     B. Chaudret, H. H. Limbach, C. Moise. C. R. Acad. Sci. Paris, Ser. II. 1992,315, 533 - 536. Premières observations par RMN de couplages quantiques dans un complexe dihydrure: . (Cp2TaH2L)PF6(Cp = h5-C5H5; L = P(OMe3, PMe2Ph).

61.     F. Aguilar-Parrilla, G. Scherer. H. H. Limbach, M. C. Foces-Foces, F. H. Cano, J. A. S. Smith, C. Toiron, J. Elguero, J. Am. Chem. Soc., 1992,114, 9657 - 9659. Observation of a Series of Degenerate Cyclic Double, Triple and Quadruple Proton Transfers in Solid Pyrazoles. Supplementary Material

60.     F. Aguilar-Parrilla, C. Cativiela, M. D. Diaz de Villegas, J. Elguero, C. Foces-Foces, J. I. G. Laureiro, F. H. Cano, H. H. Limbach, J. A. S. Smith, C. Toiron, J. Chem. Soc. Perkin 2, 1992,1737 - 1742. The Tautomerism of 3(5)-Phenylpyrazoles: An Experimental (1H,13C, 15N NMR and X-Ray Crystallography) and Theoretical (STO-3G) Study.

59.     H. H. Limbach, G. Scherer, M. Maurer, B. Chaudret, Ang. Chem., 1992,104, 1414 - 1417; Ang. Chem. Int. Ed. , 1992,31, 1369 - 1372. On the Mechanism of Coherent Dihydrogen Tunneling in Transition Metal Trihydrides.

58.     M. Schlabach, B. Wehrle, H. Rumpel, J. Braun, G. Scherer, H. H. Limbach, Ber. Bunsenges. Phys. Chem., 1992,96, 821 - 833. NMR and NIR Studies of the Tautomerism of 5,10,15,20-Tetraphenylporphyrin, including Kinetic HH/HD/DD Isotope and Solid State Effects.

1991

57.     L. Meschede, H. H. Limbach, J. Phys. Chem., 1991,95, 10267 - 10280. Sonderheft zu Ehren von Prof. M. Kasha. Dynamic NMR Study of Kinetic HH/HD/DD Isotope Effects of Double Proton Transfer in Cyclic Bis(p-fluorophenyl)formamidine Dimers.

56.     R. Schwesinger, R. Link, G. Thiele, H. Rotter, D. Honert, H. H. Limbach, F. Männle, Ang. Chem., 1991,103, 1376 -1378; Ang. Chem. Int. Ed. , 1991,30, 1372 - 1375. Stabile Phosphazenium-Ionen in der Synthese - ein leicht zugängliches, extrem reaktives “nacktes” Fluoridsalz.

55.     M. Schlabach, G. Scherer, H. H. Limbach, J. Am. Chem. Soc., 1991,113, 3550 - 3558. Kinetic HH/HD/DH/DD Isotope Effects on Nondegenerate Stepwise Double Proton Transfer Reactions. NMR Study of the Tautomerism of meso-Tetraphenylchlorin.

54.     E. Bär, J. Fuchs, D. Rieger, F. Aguilar-Parrilla, H. H. Limbach, W. P. Fehlhammer, Ang. Chem., 1991,103, 88 - 90; Ang. Chem. Int. Ed. , 1991,30, 88 - 90. Molecular and Ionic Hydrogen Isocyanide (CNH) Adducts with N-H-0- and “Super-Short” N-H...N-Hydrogen Bridges: Metal-Stabilized Hydrogen Bisisocyanides.

53.     B. Wehrle, H. H. Limbach, H. Bräunling. Synth. Met., 1991, 39, 319 -325. 15N CPMAS NMR study of the structure and reactions of polypyrrylenemethine and polyfurylenepyrrylene­methine.

52.     J. J. Wolff, H. H. Limbach. Liebigs Ann. Chem., 1991,691 - 693. Synthesis and Spectroscopic Characterization of 15N-Labeled Hexaaminobenzene Derivatives.

 

1990

51.     B. Wehrle, H. H. Limbach, J. Mortensen, J. Heinze. Synthetic Metals, 1990,38, 293 - 298. Solid-State 15N CPMAS NMR Study of the Structure of Polypyrrole.

50.     T. J. Butenhoff, R. S. Chuck, H. H. Limbach, C. B. Moore, J. Phys. Chem., 1990,94, 7847 - 7851. Vibrational Photochemistry of Porphine Imbedded in a n-Hexane-d14 Shpol’skii Matrix.

49.     T. J. Butenhoff, H. H. Limbach, C. B. Moore. Spectrochimica Acta, 1990,46A. 519 - 522. The Near-Infrared Photochemistry of Porphine imbedded in an n-Hexane Matrix.

48.     F. Aguilar-Parrilla, B. Wehrle, H. Bräunling, H. H. Limbach, J. Magn. Reson., 1990,87, 592 - 597. Temperature Gradients and Sample Heating in Variable Temperature High Speed MAS NMR Spectroscopy.

47.     B. Wehrle, F. Aguilar-Parrilla, H. H. Limbach, J. Magn. Reson., 1990,87, 584 - 591. A Novel 15N Chemical-Shift NMR Thermometer for Magic Angle Spinning Experiments.

1989

46.     B. Wehrle, H. H. Limbach, G. Zipplies, M. Hanack, Ang. Chem, Adv. Mat., 1989,101, 443 - 445. 15N CPMAS NMR Study of the Structure and Reactions of Phthalocyaninatopolysiloxane and its Precursors in theSolidState.

45.     B. Wehrle, H. H. Limbach, J. Mortensen, J. Heinze, Ang. Chem, Adv. Mat., 1989,101, 441 - 443. 15N CPMAS NMR Study of the Structure of Polyaniline.

44.     B. Wehrle, H. H. Limbach. Chem. Phys., 1989,136, 223 - 247. Special Issue: “Spectroscopy and dynamics of elementary proton transfers in polyatomic Molecules”. NMR Study of Environment modulated Proton Tautomerism in Crystalline and amorphous Phthalocyanine.

43.     G. Scherer, H. H. Limbach, J. Am. Chem. Soc., 1989,111, 5946 - 5947. Observation of a Stepwise Double Proton Transfer in Oxalamidine Which Involves Matched Kinetic HH/HD/DD Isotope and Solvent Effects.

42.     J. A. S. Smith, B. Wehrle, F. Aguilar-Parrilla, H. H. Limbach, M. C. Foces-Foces, F. H. Cano, J. Elguero, A. Baldy, M. Pierrot, M. M. T. Khurshid, J. B. Larcombe-McDouall, J. Am. Chem. Soc., 1989,111, 7304 - 7312. Intermolecular Triple Proton and Deuteron Transfer in Crystalline 3,5-Dimethylpyrazole studied by NMR. NQR. and X-ray Methods.

41.     H. Rumpel, H. H. Limbach, J. Am. Chem. Soc., 1989,111, 5429 - 5441. NMR Study of Kinetic HH/HD/DD Isotope, Solvent, Solid-State Effects on Double Proton Transfer in Azophenine.

40.     H. H. Limbach, L. Meschede, G. Scherer, Z. Naturforsch., 1989, 44a, 459 - 471. Festschrift zum 70. Geburtstag von Jakob Bigeleisen, auf Einladung. NMR Stratagems for the Study of Multiple Kinetic Hydrogen/Deuterium Isotope Effects of Proton Exchange. Example: Di-p-fluorphenylformamidine/THF.

39.     M. Schlabach, H. Rumpel, H. H. Limbach, Ang. Chem., 1989,101, 84 - 87; Ang. Chem. Int. Ed. , 1989,28, 76 - 79. Investigation of the Tautomerism of 15N-labeled Hydroporphyrins by. Dynamic NMR Spectroscopy.

38.     H. Rumpel, H. H. Limbach, G. Zachmann , J. Phys. Chem., 1989,93, 1812 - 1818. ttp://dx.doi.org/10.1021/j100342a025. Liquid- and Solid-State Infrared and Near-Infrared Study of the Proton Dynamics in Azophenine.

1988

37.     B. Wehrle, H. Zimmermann and H. H. Limbach, J. Am. Chem. Soc., 1988,110, 7014 - 7024. http://dx.doi.org/10.1021/ja00229a013. A Solid State 15N CPMAS NMR Study of Dye Tautomerism in Glassy Polystyrene: Site Dependence of Double Minimum Potentials and Their Motional Averaging.

36.     L. Meschede, D. Gerritzen, H. H. Limbach, Ber. Bunsenges. Phys. Chem., 1988,92, 469 - 485. Dynamic NMR Study of the Interference between Cyclic Proton Exchange, Selfassociation and Hindered Rotation of Diphenylformamidine in Tetrahydrofuran.

35.     H. H. Limbach, B. Wehrle, M. Schlabach, R. Kendrick, C. S. Yannoni, J. Magn. Reson., 1988,77, 84 - 100. CPMAS Polarization Transfer Methods for Superposed Chemical Exchange and Spin Diffusion in Organic Solids.

 

1987

34.     B. Wehrle, H. H. Limbach, H. Zimmermann, Ber. Bunsenges. Phys. Chem., 1987,91, 941 - 950. Variable Temperature 15N CPMAS NMR Studies of Dye Tautomerism in Crystalline and Amorphous Environments.

33.     B. Wehrle, H. H. Limbach, M. Köcher, O. Ermer, E. Vogel, Ang. Chem., 1987, 99, 914 - 917; Ang. Chem. Int. Ed. 1987, 26, 934 - 936. 15N -CPMAS-NMR Study of the Problem of NH Tautomerism in Crystalline Porphin and Porphycene.

32.     H. H. Limbach, B. Wehrle, H. Zimmermann, R. Kendrick, C. S. Yannoni, Ang. Chem.,1987, 99, 241 - 243; Ang. Chem. Int. Ed. Engl,. 1987, 26, 247 - 248. Kinetic 15N -CPMAS-NMR Study of a Double Proton Transfer in a Crystalline Malonaldehyde Diimine Derivative.

31.     H. H. Limbach, B. Wehrle, H. Zimmermann, R. Kendrick, C. S. Yannoni, J. Am. Chem. Soc.,1987, 109, 929 - 930. Observation of a Nonconcerted Double Proton Transfer in the Solid State by 15N CPMAS NMR.

30.     H. Rumpel, H. H. Limbach, J. Labelled Comp., 1987, 24, 235 - 238. Synthesis of 4-13C and 3,5-13C Labeled Aniline as Precursor of 13C-Labeled Monosubstituted Benzenes.

1986-1980

29.     G. Otting, H. Rumpel, L. Meschede, G. Scherer. H. H. Limbach, Ber. Bunsenges. Phys. Chem., 1986, 90, 1122 - 1129. Dynamic Liquid State NMR and IR Study of Tautomerism and Conformations of Tetraphenyloxalamidine, a Novel Small Intramolecular Double Hydrogen Transfer System.

28.     M. Schlabach, B. Wehrle, H. H. Limbach, E. Bunnenberg, A. Knierzinger, A. Shu, B. R. Tolf, C. Djerassi, J. Am. Chem. Soc., 1986, 108, 3856 - 3858. Evidence of Tautomerism in a Triply 15N labeled Monoacetylporphyrine by NMR: Kinetic HH/HD Isotope Effects and Thermodynamics in CD2Cl2.

27.     R. D. Kendrick, S. Friedrich, B. Wehrle, H. H. Limbach, C. S. Yannoni, J. Magn. Reson., 1985, 65, 159 - 161. http://dx.doi.org/10.1016/0022-2364(85)90387-7. A Stratagem for Low-Temperature Magic-Angle Spinning Using Nitrogen Spinning Gas.

26.     P. C. Myrhe, J. D. Krueger, B. L. Hammond, S. M. Lok, C. S. Yannoni, V. Macho, H. H. Limbach, H. M. Vieth, J. Am. Chem. Soc., 1984, 106, 6079 - 6080. Solid-State 13C CPMAS Spectra of Rapidly Equilibrating Carbocations.

25.     H. H. Limbach, J. Hennig, R. Kendrick, C. S. Yannoni, J. Am. Chem. Soc., 1984, 106, 4059- 4060. Proton-Transfer Kinetics in Solids: Tautomerism in Free Base Porphines by 15N CPMAS NMR.

24.     H. H. Limbach, J. Chem. Phys., 1984, 80, 5343 - 5345. Reply to a “Comment on IR-spectroscopic study of isotope effects on the NH/ND stretching bands of meso-tetraphenylporphine and vibrational hydrogen tunneling”.

23.     J. Hennig, H. H. Limbach, J. Am. Chem. Soc., 1984, 106, 292- 298. Localization and Transfer of Protons between 15N atoms of meso-tetraphenylporphine probed by Nuclear Overhauser Effects and Dipole-Dipole Relaxation Times.

22.     D. Gerritzen, H. H. Limbach, J. Am. Chem. Soc., 1984, 106, 869 - 879. Kinetic Isotope Effects and Tunneling in Cyclic Double and Triple Proton Transfer between Acetic Acid and Methanol in Tetrahydrofuran studied by Dynamic1H and 2H NMR Spectroscopy.

21.     H. H. Limbach, J. Hennig, J. Stulz, J. Chem. Phys., 1983, 78, 5432 - 5436. http://dx.doi.org/10.1063/1.445471. IR-spectroscopic study of isotope effects on the NH/ND-stretching bands of meso-tetraphenylporphine and vibrational hydrogen tunneling.

20.     H. Rüterjans, E. Kaun, W. Hull, H. H. Limbach, Nucleic Acids Res., 1982, 10, 7027 - 7039. Evidence for tautomerism in nucleic acid base pairs. 1H NMR study of 15N labeled t-RNA.

19a.   H. H. Limbach, J. Hennig, D. Gerritzen, H. Rumpel, Faraday Discuss. Chem. Soc., 1982, 74, 229 - 243; 279 - 296. Primary Kinetic HH/HD/DH/DD Isotope Effects and Proton Tunnelling in Double Proton-transfer Reactions.

19b.   H. H. Limbach, Faraday Discuss. Chem. Soc., 1982, 74, 279 - 296. General Discussion

18.     J. Hennig, H. H. Limbach, J. Magn. Reson., 1982, 49, 322 - 328. Magnetization Transfer in the Rotating Frame: A New Simple Kinetic Tool for the Determination of Rate Constants in the SlowChemicalExchangeRange.

17.     W. Gronski, A. Hasenhindl, H. H. Limbach, M. Möller, H. H. Cantow, Polymer Bulletin, 1981, 6, 93 - 100. Micro- and Macroconformation of Macromolecules. 10. Conformational Analysis of Amorphous Polymers in the Glassy State by Macig Angle Spinning 13C-NMR.

16.     D. Gerritzen, H. H. Limbach, Ber. Bunsenges. Phys. Chem., 1981, 85, 527 - 535. Kinetic and Equilibrium Isotope Effects of Proton Exchange and Autoprotolysis of Pure Methanol Studied by Dynamic NMR Spectroscopy.

15.     D. Gerritzen, H. H. Limbach, J. Phys. Chem., 1980, 84, 799 - 805. Proton Chemical Shifts and Termodynamics of the Formation of Hydrogen-Bonded Dimers and Mixed 1:1 Associates in the Ternary System Acetic Acid/Methanol/Tetrahydrofuran-d8.

14.     H. H. Limbach, W. Seiffert, J. Am. Chem. Soc., 1980, 102, 538 - 542. 1H NMR Spectroscopic Study of Cyclic Proton Exchange between Acetic Acid and Methanol in Tetrahydrofuran-d8.

 

1970-1979

13.     H. H. Limbach, J. Hennig, J. Chem. Phys., 1979, 71, 3120 - 3124. Quasiclassical calculations of one-dimensional potential parameters of the hydrogen migration in meso-tetraphenylporphine from experimental tunnel rates.

12.     H. H. Limbach, J. Magn. Reson., 1979, 36, 287 - 300. NMR Lineshape Theory of Superimposed Intermolecular Spin Exchange Reactions and Its Application to the System Acetic Acid/Methanol/Tetrahydrofuran-d8.

11.     J. Hennig, H. H. Limbach, J. Chem. Soc. Faraday Trans.2, 1979, 75, 752 - 766. Kinetic Study of Hydrogen Tunnelling in meso-Tetraphenylporphine by Nuclear Magnetic Resonance Lineshape Analysis and Selective T1r-Relaxation Time Measurements.

10.     H. Prinzbach, H. Sauter, H. G. Hörster, H. H. Limbach, L. Knothe, Liebigs Ann. Chem., 1977, 869 - 894. Cyclic cross-conjugated bond systems. 32. Syntheses and cycloaddition reactions of 1,2,3,4-tetraphenyl-, 1,2:3,4-dibenzo-, 2,3-diphenylpentafulvalene

9.       H. Prinzbach, D. Stusche, J. Markert, H. H. Limbach, Chem, Ber., 1976, 109, 3505 - 3526. Cis-Aza-bis- and cis-aza-tris-s-homobenzenes; cis-aza-tris-s-homotropilidenes. Syntheses and s®p isomerizations.

8.       H. H. Limbach, W. Seiffert, Ber. Bunsenges. Phys. Chem., 1974, 78, 641 - 647. Dynamic processes in systems with hydrogen bonds. II. 1H-NMR study of the direct and indirect intermolecular proton exchange of N,N-bis(pentadeuterophenyl)-1-amino-3-iminopropene in carbon disulfide. Dynamic processes in hydrogen bond systems.

7.       H. H. Limbach, W. Seiffert, Ber. Bunsenges. Phys. Chem., 1974, 78, 532 - 537. Dynamic processes in systems with hydrogen bonds. I. 1H-NMR spectroscopic study of the cis-trans equilibrium and the hydrogen bond association of N,N'-bis(pentadeuterophenyl)-1-amino-3-iminopropene in carbon disulfide.

6.       H. H. Limbach, W. Seiffert, Tetrahedron Letters, 1972, 371 - 374. Cis-trans rearrangement and NH-exchange in malondialdehyde di(pentadeuteroanil).

5.       W. Seiffert, H. H. Mants ch, V. Zanker, H. H. Limbach, J. Mol. Struct., 1970, 5, 227 - 235. NMR and UV spectroscopic investigations of the structure of acridine-N-oxide photoproducts.

4.       W. Seiffert, H. H. Limbach, V. Zanker, H. H. Mantsch, Histochemie, 1970, 23, 220 - 243. Ultraviolet spectra and S-electronic structures of monaminoacridinium cations.

3.       W. Seiffert, H. H. Limbach, V. Zanker, H. H. Mantsch, Tetrahedron, 1970, 26, 2663 - 2675. SCF calculations on monohydroxy-acridinium cations

2.       H. H. Limbach, W. Seiffert, E. Ohmes, H. Zimmermann, Ber. Bunsenges. Phys. Chem., 1970, 74, 966 - 977. Proton NMR spectra of linear diazaacenes and their N-oxides.

1.       H. H. Limbach, F. Strohbusch, H. Zimmermann, Ber. Bunsenges. Phys. Chem., 1970, 74, 3 - 7. http://onlinelibrary.wiley.com/doi/10.1002/bbpc.19700741005/pdf. N.M.R. Spectroscopic determination of association constants of hydrogen bonded complexes. Mixed associations between 2-tert-butylphenol and tetrahydrofuran in carbon tetrachloride.

 

Reviews in Books and Monographs

 

R13.  G. Buntkowsky, H. H. Limbach, in Hydrogen Transfer Reactions, J. T. Hynes, J. Klinman, H. H. Limbach, R. L. Schowen, Eds. Chapter Wiley-VCH, Weinheim 2006. Chapter 21, p. 639 – 682. Dihydrogen Transfer and Symmetry: The Role of Symmetry on the Chemistry of Dihydrogen Transfer in the Light of NMR Spectroscopy.

R12.  H. H. Limbach, in Hydrogen Transfer Reactions, J. T. Hynes, J. Klinman, H. H. Limbach, R. L. Schowen, Eds. Chapter Wiley-VCH, Weinheim 2007. Chapter 6, p. 135-221. http://dx.doi.org/10.1002/9783527611546.ch6. Single and multiple hydrogen/deuterium transfer reactions in liquids and solids.

R11.  G. Buntkowsky, H. H. Limbach, J. Low. Temp. Phys., 2006, 143, 55-114. 2H-Solid State NMR Studies of Tunneling Phenomena and Isotope Effects in Transition Metal Dihydrides. http://dx.doi.org/10.1007/s10909-006-9211-y

R10.  H. H. Limbach, G. S. Denisov, N. S. Golubev, in Isotope Effects In Chemistry and Biology , A. Kohen, H. H. Limbach, Eds.; Taylor & Francis, Boca Raton FL, 2005; Chapter 7, pp 193-230. Hydrogen Bond Isotope Effects Studied by NMR.

R09.  H. H. Limbach, in Encyclopedia of Nuclear Magnetic Resonance: Supplementary Volume 9,: Advances in NMR. Eds, D. M. Grant, R. K. Harris, John Wiley & Sons, Ltd, Chichester, 2002, pp. 520-531. http://dx.doi.org/10.1002/9780470034590.emrstm0142. Dynamics of Hydrogen Transfer in Liquids and Solids.

R08.  J. Elguero, H. H. Limbach, F. Aguilar-Parrilla, R. M. Claramunt, C. Lopez, in F. H. Cano, C. Foces-Foces, M. Martinez-Ripoll., Eds., Cristallografía, Madrid, 1995, Kapitel 17, .287-309. Resonancia magnética nuclear de alta resolución en estado sólido: un auxiliar de la cristallografía.

R07.  H. H. Limbach, G. Scherer, L. Meschede, F. Aguilar-Parrilla, B. Wehrle, J. Braun, C. Hoelger, H. Benedict, G. Buntkowsky, W. P. Fehlhammer, J. Elguero, J. A. S. Smith, B. Chaudret. in Y. Gauduel and P. J. Rossky, Eds.Ultrafast Reaction Dynamics and Solvent Effects, American Institute of Physics, AIP Conference Proceedings 298, 1994, Part III. p.225-239. NMR Studies of Elementary Steps of Hydrogen Transfer in Condensed Phases.

R06.  H. H. Limbach. in Intermolecular Forces, Eds. P. L. Huyskens, W. A. P. Luck, t. Zeegers-Huyskens, Springer-Verlag, Heidelberg 1991, Chapter XI. p. 158 - 167. NMR Studies of Elementary Steps of Multiple Proton and Deuteron Transfers in Liquids, Crystals and Organic Glasses.

R05.  H. H. Limbach, in NMR Basic Principles and Progress, Vol. 23: Deuterium and Shift Calculation, p. 66-167, Springer-Verlag, Heidelberg 1991, Review. Dynamic NMR Spectroscopy in the Presence of Kinetic Hydrogen/Deuterium Isotope Effects.

R04.  H. H. Limbach. in 35 Jahre Fonds der Chemischen Industrie 1950-1985, 1985, S.89 - 97. Multiple Wasserstoffwanderungen: Eine Herausforderung an die NMR Spektroskopie.

R03.  H. H. Limbach, D. Gerritzen, H. Rumpel, B. Wehrle, G. Otting, H. Zimmermann, R. Kendrick, C. S. Yannoni. in H. Sixl, Photoreaktive Festkörper, M. Wahl Verlag, Karlsruhe 1985, Kapitel 2, S. 19 - 42. NMR and IR Studies of Kinetic Isotope and Solution-Solid State Effects on Double Hydrogen Transfers in Organic compounds.

R02.  H. H. Limbach, in E. Wyn-Jones and J. Gormally, Eds., Aggregation Processes in Solution, Elsevier, Amsterdam 1983, Chapter 16, S. 410-461. The Use of NMR Spectroscopy in the Study of Hydrogen Bonding in Solution.

R01.  H. H. Limbach, Nach. Chem. Tech. Lab., 1980, 28, 860 - 865. NMR Spektroskopie am Menschen.

 

Editor of Monographs and Special Issues

 

5.       J. T. Hynes, J. Klinman, H. H. Limbach, R. L. Schowen, Eds.; Handbook of Hydrogen Transfer, Vols. 1 - 4, Wiley-VCH 2007.

4.       A. Kohen, H. H. Limbach, Eds., Isotope Effects In Chemistry and Biology; Taylor & Francis: Boca Raton, FL, 2005; pp 1-1128. Order Information ISBN 0824724496.

3.       A.J. Barnes and H. H. Limbach, Eds., J. Mol. Structure,2004, 700, 1-254. Special Issue Horizons in Hydrogen Bond Research.

2.       H. H. Limbach, Ed., Magn. Reson. Chem. 2001, 39, S1-S213. Special Issue NMR Spectroscopy of Hydrogen Bonded Systems.

1.       H. H. Limbach, J. Manz, Eds., Ber. Bunsenges. Phys. Chem. 1998, 102, 289-586. Special Issue on "Hydrogen Transfer: Experiment and Theory."