Springe direkt zu Inhalt

Dual Photoredox and Gold Catalysis: Intermolecular Multicomponent Oxyarylation of Alkenes

M. N. Hopkinson, B. Sahoo, F. Glorius* – 2014

Intermolecular three-component oxyarylation reactions of simple alkenes have been developed using a dual gold and photoredox catalytic system. Inexpensive organic dyes could be employed as the photocatalyst using aryldiazonium salts, while the combination of gold and iridium catalysts allowed for diaryliodonium compounds to be employed as the source of the arene coupling partner. In both cases, α-arylated ether products were generated under remarkably mild conditions using readily accessible visible light sources.

Title
17. Dual Photoredox and Gold Catalysis: Intermolecular Multicomponent Oxyarylation of Alkenes
Author
M. N. Hopkinson, B. Sahoo, F. Glorius*
Publisher
Advanced Synthesis and Catalysis
Date
2014
Identifier
DOI: 10.1002/adsc.201400580
Source(s)
Citation
Adv. Synth. Catal. 2014, 356, 2794-2800