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Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)

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G. Thiele, C. Donsbach, I. Nußbruch, S. Dehnen – 2016

The synthesis of chalcogenidoplumbates(II,IV) via the in situ reduction of nominal "PbCh2" (Ch = Chalcogen) and via a solid-state reaction and subsequent solvothermal reactions is presented. Additionally, reactivities of plumbate(II) solutions are portrayed, which yield the heaviest-known CO homolog known to date: the µ-PbSe ligand.

Title
Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of Chalcogenidoplumbates(II or IV)
Author
G. Thiele, C. Donsbach, I. Nußbruch, S. Dehnen
Date
2016
Citation
J. Vis. Exp. 2016, 118, e54789.
Type
Text