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Heterobimetallic Chalcogenidometallate Strands: Synthesis, Structure, Magnetism, and Conductivity

IC12

G. Thiele, S. Peter, M. Schwarzer, E. Ruzin, R. Clérac, H. Staesche, C. Rößler, B. Roling, S. Dehnen – 2012

The reactions of [SnTe]4− anions with Hg2+ or Mn2+ ions in protic solution yielded two solvent-free salts with one-dimensional, SiS2-type telluridostannate chain anions {[MSnTe4]2−}n: Rb2[HgSnTe4] (2) and (NMe4)2[MnSnTe4] (3). Besides their crystal structures, we present the physical properties of the previously reported Cs+ analogue Cs2[MnSnTe4] (1), indicating antiferromagnetic coupling of the Mn ions and charge transport due to polaron hopping.

Title
Heterobimetallic Chalcogenidometallate Strands: Synthesis, Structure, Magnetism, and Conductivity
Author
G. Thiele, S. Peter, M. Schwarzer, E. Ruzin, R. Clérac, H. Staesche, C. Rößler, B. Roling, S. Dehnen
Date
2012
Citation
Inorg. Chem. 2012, 51, 3349-3351.
Type
Text