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A photoswitchable rotaxane operating in monolayers on solid support

F.B. Schwarz, T. Heinrich, A. Lippitz, W.E.S. Unger, C.A. Schalley— 2016

A novel photoswitchable rotaxane was synthesised and its switching behaviour in solution was analysed with NMR and UV-VIS. A monolayer of rotaxanes was deposited on glass surfaces and the on-surface photoswitching was investigated. Angle-resolved NEXAFS spectra revealed a preferential orientation that reversibly changes upon switching.

Title225
A photoswitchable rotaxane operating in monolayers on solid support
AuthorF.B. Schwarz, T. Heinrich, A. Lippitz, W.E.S. Unger, C.A. Schalley
Date20161125
IdentifierDOI: 10.1039/C6CC08586E
Source(s)
CitationChem. Commun. 2016, 52, 14458-14461
TypeText