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Lower critical solution temperature (LCST) phase behaviour of an ionic liquid and its control by supramolecular host-guest interactions

S. Dong, J. Heyda, J. Yuan, C.A. Schalley— 2016

Lower critical solution temperature (LCST) phase behaviour of an imidazolium-based ionic liquid is reported, which can be controlled by concentration, the choice of cation, anion and solvent, and by supramolecular host-guest complex formation. Molecular dynamics simulations provide insight into the molecular basis of this LCST phenomenon. This thermo-responsive system has potential applications in cloud point extraction processes.

Title219
Lower critical solution temperature (LCST) phase behaviour of an ionic liquid and its control by supramolecular host-guest interactions
AuthorS. Dong, J. Heyda, J. Yuan, C.A. Schalley
Date20160526
IdentifierDOI: 10.1039/C6CC02838A
Source(s)
CitationChem. Commun. 2016, 52, 7970-7973
TypeText