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183
Generation of a Dynamic System of Three-Dimensional Tetrahedral Polycatenanes

S. P. Black, A. R. Stefankiewicz, M. M. J. Smulders, D. Sattler, C. A. Schalley, J. R. Nitschke, J. K. M. Sanders— 2013

Seven of the best: A dynamic combinatorial library of polycatenated tetrahedra was prepared by complexation between a dynamic Fe4L6 tetrahedral cage, constructed from ligands containing an electron-deficient naphthalenediimide core, and an electron-rich aromatic crown ether, 1,5-dinaphtho[38]crown-10. The highest order species in the library is the tetrahedral [7]catenane.

Title183
Generation of a Dynamic System of Three-Dimensional Tetrahedral Polycatenanes
AuthorS. P. Black, A. R. Stefankiewicz, M. M. J. Smulders, D. Sattler, C. A. Schalley, J. R. Nitschke, J. K. M. Sanders
Date20130418
IdentifierDOI 10.1002/anie.201209708, 10.1002/ange.201209708
Source(s)
CitationAngew. Chem. Int. Ed. 2013, 52, 5749-5752; Angew. Chem. 2013, 125, 5861-5864