Takudrei

153
A neutral Pt3 stack unsupported by any bridging ligand

L. Holland, W.-Z. Shen, P. von Grebe, D. Gupta, P. J. Sanz Miguel, Y. Huang, F. Pichierri, A. Springer, C. A. Schalley, B. Lippert— 2011

Pt...Pt...Pt interactions via their d8 orbitals, combined with π–π stacking of deprotonated, chelating 2-(3′-pyrazolyl)pyridine (pyzpy) ligands, are responsible for trans-Pt(pyzpy)2 (2) crystallization in a stack of three molecules unsupported by any bridging ligand.

Title153
A neutral Pt3 stack unsupported by any bridging ligand
AuthorL. Holland, W.-Z. Shen, P. von Grebe, D. Gupta, P. J. Sanz Miguel, Y. Huang, F. Pichierri, A. Springer, C. A. Schalley, B. Lippert
Date20110405
IdentifierDOI 10.1039/C0DT01408G
Source(s)
CitationDalton Trans. 2011, 40, 5159-5161