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A double intramolecular cage contraction within a self-assembled metallo-supramolecular bowl

B. Brusilowskij, S. Neubacher, C. A. Schalley— 2009

When isolated in the high vacuum of an ESI-FTICR mass spectrometer, bowl-shaped metallo-supramolecular M6L4 assemblies undergo a surprising and mechanistically interesting intramolecular double cage contraction to yield smaller M3L2 cages.

Title121
A double intramolecular cage contraction within a self-assembled metallo-supramolecular bowl
AuthorB. Brusilowskij, S. Neubacher, C. A. Schalley
Date20090114
IdentifierDOI 10.1039/B819412B
Source(s)
CitationChem. Commun. 2009, 785-787