M. N. Hopkinson, C. Richter, M. Schedler, F. Glorius*— 2014
The successful isolation and characterization of an N-heterocyclic carbene in 1991 opened up a new class of organic compounds for investigation. From these beginnings as academic curiosities, N-heterocyclic carbenes today rank among the most powerful tools in organic chemistry, with numerous applications in commercially important processes. Here we provide a concise overview of N-heterocyclic carbenes in modern chemistry, summarizing their general properties and uses and highlighting how these features are being exploited in a selection of pioneering recent studies.
16. An Overview of N-Heterocyclic Carbenes
M. N. Hopkinson, C. Richter, M. Schedler, F. Glorius*