34. Transforming Terpene-Derived Aldehydes into 1,2-Epoxides via Asymmetric α-Chlorination: Subsequent Epoxide Opening with Carbon Nucleophiles

P. Winter, J. Swatschek, M. Willot, L. Radtke, T. Olbrisch, A. Schäfer, M. Christmann

Merging Jørgensen's and MacMillan's organocatalytic aldehyde chlorinations enables the synthesis of chiral vinylcyclopropanes and (−)-cis-aerangis lactone via terpene-derived 1,2-epoxides.

Title34. Transforming Terpene-Derived Aldehydes into 1,2-Epoxides via Asymmetric α-Chlorination: Subsequent Epoxide Opening with Carbon Nucleophiles
AuthorP. Winter, J. Swatschek, M. Willot, L. Radtke, T. Olbrisch, A. Schäfer, M. Christmann
IdentifierDOI: 10.1039/C1CC15173H
Source(s)
CitationChem. Commun. 2011, 47, 12200-12202