Beyond Iron Trifluoride: A Matrix-Isolation and Quantum-Chemical Investigation of FeF₄

Tobias Schlöder, Thomas Vent-Schmidt, Sebastian Riedel— 2012

Beyond iron trifluoride: Matrix-isolation IR spectroscopy and state-of-the-art quantum-chemical calculations have led to the characterization of iron tetrafluoride, a previously unknown species. FeF4 has been prepared by co-deposition of laser-ablated iron atoms with fluorine under excess of noble gases (neon and argon) at cryogenic temperatures.

TitleBeyond Iron Trifluoride: A Matrix-Isolation and Quantum-Chemical Investigation of FeF₄
AuthorTobias Schlöder, Thomas Vent-Schmidt, Sebastian Riedel
Date2012
Identifier10.1002/anie.201206464
Source(s)
Appeared InAngew. Chem. Int. Ed. 2012, 51, 12063–12067 (Angew. Chem. 2012, 124, 12229–12233)
Languageeng
TypeText