Formation and Characterization of [BrC(NMe2)2)][Br3] and [BrC(NMe2)2)]2[Br8] in Ionic Liquids
069
Karsten Sonnenberg, Patrick Pröhm, Simon Steinhauer, Anja Wiesner, Carsten Müller, Sebastian Riedel – 2017
The polybromide salts [BrC(NMe₂)₂)]₂[Br₈] and [BrC(NMe₂)₂)][Br₃]were synthesized in the ionic liquid [BMP][OTf] (1‐butyl‐1‐methyl‐pyrrolidinium triflate). The compounds were characterized by Raman, NMR, and X‐ray single crystal structure determination as well as quantum‐chemical calculations. The polybromide dianion [Br₈]²⁻ structure shows similarities to the very recently reported structure of the first octachloride [Cl₈]²⁻.
Titel
Formation and Characterization of [BrC(NMe2)2)][Br3] and [BrC(NMe2)2)]2[Br8] in Ionic Liquids
Verfasser
Karsten Sonnenberg, Patrick Pröhm, Simon Steinhauer, Anja Wiesner, Carsten Müller, Sebastian Riedel
Datum
2017
Quelle/n
Erschienen in
Z. Anorg. Allg. Chem. 2017, 643, 1, 101–105
Zitierweise
DOI: 10.1002/zaac.201600337
Sprache
eng