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Structural Proof for the First Dianion of a Polychloride: Investigation of [Cl8]2−

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Robin Brückner, Patrick Pröhm, Anja Wiesner, Simon Steinhauer, Carsten Müller, Sebastian Riedel – 2016

The polychloride salt [CCl(NMe₂)₂]⁺₂ [Cl₈]²⁻ was synthesized and crystallized in the ionic liquid [BMP]OTf. The compound was fully characterized by Raman spectroscopy as well as X‐ray single‐crystal structure determination, and represents the first example of a polychloride dianion to be described. Detailed gas‐phase and solid‐state calculations concerning the nature of the bonding situation were also performed.

Titel
Structural Proof for the First Dianion of a Polychloride: Investigation of [Cl8]2−
Verfasser
Robin Brückner, Patrick Pröhm, Anja Wiesner, Simon Steinhauer, Carsten Müller, Sebastian Riedel
Datum
2016
Erschienen in
Angew. Chem. Int. Ed. 2016, 55, 36, 10904–10908 Angew. Chem. 2016, 128, 36, 11064-11068
Zitierweise
DOI: 10.1002/anie.201604348 DOI: 10.1002/ange.201604348
Sprache
eng